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The method is substrate‐selective and specific for the oxidation of benzylic alcohols. [ABSTRACT FROM AUTHOR]

An abstract of an article about N-heterocyclic carbene-catalyzed radical reactions is presented.

An abstract of the article "Synthesis of 2,2'-Biphenols Through Direct C(sp 2)-H Hydroxylation of (1,1'-Biphenyl)-2-ols." by S. Duan, Y. Xu,a nd X. Zhang is presented.

An abstract of the article "Photocatalytic Decarboxylative Hydroxylation of Carboxylic Acids Driven by Visible Light and Using Molecular Oxygen" by D. Homolka is presented.

An abstract of the article "Photocatalytic Decarboxylative Hydroxylation of Carboxylic Acids Driven by Visible Light and Using Molecular Oxygen" by Hai-Tao Song and colleagues is presented.

An abstract of the article "Synthesis of 2,2'-Biphenols Through Direct C(sp2)-H Hydroxylation of [1,1'-Biphenyl]-2-ols" by Shitao Duan and colleagues is presented.

The catalyst used in the convenient procedure is recycled and reused in five additional catalytic cycles without loss of its activity. [ABSTRACT FROM AUTHOR]

Chemical equations are presented for the article "Medium-Ring Stereocontrol in the Temporary Silicon-Tethered Ring-Closing Metathesis Approach to the Synthesis of Polyketide Fragments" by P.A. Evans and colleagues, published in the periodical "Synthesis."

Review: [146 refs. [ABSTRACT FROM AUTHOR]

The radical carbohydroxylation of styrenes with a broad range of aryldiazonium salts is achieved under mild thermal conditions. [ABSTRACT FROM AUTHOR]

In view of suitable long-term waste forms for depleted U, metal uranates(VI) are solubility limiting U(VI) phases under high pH conditions. [ABSTRACT FROM AUTHOR]

A broad spectrum of 1,2-amino alcohols and 1,2-diamines is synthesized as is demonstrated for a series of selected examples. [ABSTRACT FROM AUTHOR]

All yields are based on recovered starting material. [ABSTRACT FROM AUTHOR]

The article presents chemical equations for the article "Cu(II)-Catalyzed Enantioselective α-Hydroxylation and α-Chlorination of β-Ketoesters with N,N,O-Tridentate Chiral Phenanthroline Ligand" by Y. Naganawa and others published in "ChemistrySelect" in 2016.

Protected α-hydroxy carbonyls or free α-hydroxy ketones are prepared by an efficient and green method including the in situ conversion of various ketones into the corresponding silyl enol ethers and their oxidation to the corresponding α-hydroxy ketones. [ABSTRACT FROM AUTHOR]

An abstract of the article "Aerobic α-Hydroxylation of β-Keto Esters and Amides by Co-Catalysis of SmI

A graphical abstract of the study "Acid-Catalyzed C-O Coupling of Styrenes with N-Hydroxyphthalimide: Trapping Alkenyl Radicals by TEMPO" by X.-F. Xia and colleagues is presented.

Conditions for either dimerization or 2-hydroxylation of variously functionalized benzamides are elaborated. [ABSTRACT FROM AUTHOR]

The article presents chemical equation for the article "IPSO-Hydroxylation of Boronic Acid via Ozonolysis: A Metal-, Ligand-, and Base-Free Method" by Y. K. Bommegowda and others, in journal "Chemistry Letters" in 2016.

A copper-catalyzed thiophenol C-H activation is described. [ABSTRACT FROM AUTHOR]

An abstract on stereoselective hydroxylation of amides using Oppolzer's Sultam as chiral auxilliary is presented.

A new hydrazone-based exo-directing group (DG) strategy is developed for the functionalization of unactivated primary β C-H bonds of aliphatic amines. [ABSTRACT FROM AUTHOR]

The first template assisted meta-hydroxylation reaction is disclosed. [ABSTRACT FROM AUTHOR]

Aroyl groups in substrates (I) are essential for the chlorohydroxylation reaction. [ABSTRACT FROM AUTHOR]

The reaction is proposed to involve intermediary 1,2-bonded diboron-complexes ((dioxadiborinino)dioxadiborinine-type). [ABSTRACT FROM AUTHOR]

The first synthesis of formosusin A (I), with Sharpless asymmetric dihydroxylation of a vinyliodide being the key step, is described. [ABSTRACT FROM AUTHOR]

Review: [89 refs. [ABSTRACT FROM AUTHOR]

In the presented approach DMF plays a dual role both as a hydroxyl source and as a solvent. [ABSTRACT FROM AUTHOR]

A detailed experimental and computational study on the title reaction is presented. [ABSTRACT FROM AUTHOR]

Review: [hydration, hydroxylation, and hydroamination as key reations for various cascae transformations, also in total synthesis] [ABSTRACT FROM AUTHOR]

A new method for the ortho-directed hydroxylation of both symmetrical and unsymmetrical azobenzenes is developed. [ABSTRACT FROM AUTHOR]

A novel method for selective generation of aryl radicals from diaryliodonium salts and iodanylidene malonates with TEMPO-Na as a single-electron transfer (SET) reducing reagent is described. [ABSTRACT FROM AUTHOR]

Both enantiomers are accessible using the same cupreidine-derived organocatalyst by simply changing the oxidant. [ABSTRACT FROM AUTHOR]

A practical method for the ortho C-H hydroxylation of benzamides with inexpensive copper(II) acetate monohydrate and a pyridine ligand is presented. [ABSTRACT FROM AUTHOR]

A graphical abstract of the article "A Versatile Approach for the Synthesis of para-Substituted Arene via Palladium-Catalyzed C-H Functionalization and Protodecarboxylation of Benzoic Acids" is presented.

An abstract of the article "Temperature-Controlled Acyloxylations and Hydroxylations of Bromoarene by a Silver Salt" by K. Yoo and colleagues is presented.

The article presents chemical equations for the article "Synthesis of Hydroxypyrrolone Carboxamides Employing Selectfluor" by T. C. Allmann and others, published in the journal "Chemistry - A European Journal" in 2016.

A nitrogen complexation strategy using a strong Broensted acid (HBF4) or an azaphilic Lewis acid (BF3, not shown) enables remote, non-directed C(sp3)-H oxidations of tertiary, secondary, and primary amine- and pyridine-containing molecules with tunable iron catalysts. [ABSTRACT FROM AUTHOR]

A silver-promoted radical mechanism is proposed for this reaction. [ABSTRACT FROM AUTHOR]

An abstract of the article "Copper-Catalyzed Intermolecular Oxyamination of Olefins Using Carboxylic Acids and O-Benzoylhydroxylamines" by Hemric, B.N., Wang, Q., and Beilstein J. is presented.

Chemical reactions are presented for the article "Palladium-Catalyzed Regioselective C-H Bond Acetoxylation-Alkoxylation of Azoxybenzenes" by M Sun and colleagues, published in the journal "Synlett" in 2015.

A novel and rapid Mn-mediated method for aliphatic C-H hydroxylation is described. [ABSTRACT FROM AUTHOR]

Chemical equations are presented for the article 2-Hydroxylation of 1,3-Diketones with Atmospheric Oxygen" by T. Li and colleagues, published in the journal "Synlett" in 2015.

An abstract of the article "Copper-Catalyzed Aerobic Decarboxylation/Ketooxygenation of Electron-Deficient Alkenes" is presented.

The cross-coupling reaction between N-hydroxyphthalimide and various benzylic and allylic hydrocarbons is realized through an organocatalytic radical-mediated process involving C(sp3)-O bond formation using tert-butyl hydroperoxide as an oxidant and tetra-n-butylammonium iodide as a catalyst, during which the phthalimide N-oxyl radical and benzylic and allylic radicals are generated in situ and react selectively by a radical/radical cross-coupling reaction. [ABSTRACT FROM AUTHOR]

Review: review on hydroxylation reactions where dissociative non-rebound mechanism is shown to dominate; 50 refs. [ABSTRACT FROM AUTHOR]

Two regiochemical pathways of aziridine ring opening are described, providing access to two classes of compounds from a common intermediate. [ABSTRACT FROM AUTHOR]

Thorough reinvestigation of the title reactions reveals that in contrast to previously published results the reactions do not deliver the products in very high yields and with high to very high enantiomeric excesses, but in often significantly lower yields and with no enantioselectivity at all. [ABSTRACT FROM AUTHOR]

An asymmetric oxygen atom transfer of oxindole derivatives using Davis′ oxaziridine gives the corresponding 3-aryl-3-hydroxy-2-oxindole derivatives with excellent enantioselectivity. [ABSTRACT FROM AUTHOR]

An abstract of the article "Iron-Catalyzed Dioxygenation of Alkenes and Terminal Alkynes by Using (Diacetoxyiodo)benzene as Oxidant" by B. T. V. Srinivas, Vikas S. Rawat and Bojja Sreedhar is presented.