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A wide variety of biaryls is synthesized through Suzuki--Miyaura cross-coupling of aryl bromides or aryl triflates with (het)aryl boronic acids. A palladacycle complex is used as an highly active catalyst which exhibits excellent stability toward air and moisture. The procedure features high efficiency, mild reaction conditions and high yields. Somewhat lower yields are achieved under air atmosphere. [ABSTRACT FROM AUTHOR]

A novel method using phosphinamides as directing groups for the direct ortho-arylation with arylboronic acids to produce mixtures of mono- and diarylated products is presented. [ABSTRACT FROM AUTHOR]

The article presents chemical equations related to the article "Mild-Condition Synthesis of Allenes from Alkynes and Aldehydes Mediated by Tetrahydroisoquinoline (THIQ)" by M. Dou and others, published in the "Journal of Organic Chemistry" in 2013.

The new protocol for the construction of C-P bonds in amenable to various phenol derivatives and different types of phosphorus nucleophiles such as phosphine oxides and phosphites. [ABSTRACT FROM AUTHOR]

Optimized conditions are elaborated which include a protected tyrosine as the optimized optically active ligand. [ABSTRACT FROM AUTHOR]

It is proposed, that the reaction of tetrahydroisoquinoline with aromatic aldehydes provide exo-iminium ions, which isomerize to endo-iminium ions. [ABSTRACT FROM AUTHOR]

Michael addition of α-cyanoketones and acrylates in the presence of chiral cinchonidine catalyst (CJN) produces the corresponding Michael adducts in high yields with moderate to good enantioselectivities. [ABSTRACT FROM AUTHOR]