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1. ChemInform Abstract: Microbial Asymmetric Reduction of α-Hydroxyketones in the anti-Prelog Selectivity

Author

Takeshi Sugai, Toshikuni Tsujigami, and Hiromichi Ohta

Subjects
chemistry.chemical_compound, Enzyme system, Chemistry, Stereochemistry, Reactivity (chemistry), General Medicine, Optically active, Yamadazyma farinosa, Selectivity, Ring (chemistry), Carbonyl group
Abstract

Yamadazyma farinosa IFO 10896 was found to reduce α-hydroxyketones bearing a phenyl ring to give optically active diols with anti-Prelog selectivity. The distance between the carbonyl group and the phenyl ring was shown to have an interesting effect on the reactivity and selectivity of the enzyme system.

Published
2010
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