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2 results on '"Yannick Escudié"'

1. ChemInform Abstract: Synthesis of Original Phosphine-Sulfoxide Ligands for Asymmetric Allylic Alkylation

Author

Mariana Lozano González, Eddy Maerten, Isabelle Fabing, Antoine Baceiredo, Yannick Escudié, Isabel Alvarado-Beltrán, Cecilio Alvarez Toledano, and Nathalie Saffon-Merceron

Subjects
chemistry.chemical_compound, Tsuji–Trost reaction, chemistry, chemistry.chemical_element, Sulfoxide, General Medicine, Combinatorial chemistry, Phosphine, Palladium
Abstract

New phosphine-sulfide and phosphine-sulfoxide ligands were synthesized and tested in allylic alkylation. Their coordination mode with Palladium have been studied by analysis of the corresponding X-ray crystallographic structures. The most efficient ligands were prepared in enantiomerically pure form and were applied to the Pd-catalyzed asymmetric allylic alkylation providing enantioselectivities up to 74%. more...

Published
2016
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2. ChemInform Abstract: Iron-Catalyzed Reduction of CO2into Methylene: Formation of C-N, C-O, and C-C Bonds

Author

Guanghua Jin, C. Gunnar Werncke, Sylviane Sabo-Etienne, Sébastien Bontemps, and Yannick Escudié

Subjects
Reduction (complexity), chemistry.chemical_compound, Chemistry, Iron catalyzed, Acetal, Iron complex, General Medicine, Methylene, Medicinal chemistry, Catalysis
Abstract

Based on the use of a (dihydrido)iron complex as catalyst the conversion of hydroboranes to bis(boryl)acetal (III) using CO2 as one-carbon source is optimized.

Published
2016
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