1. ChemInform Abstract: METHYLATION OF THE PHOSPHORYL GROUP WITH METHYL IODIDE
- Author
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Alexandr M. Pinchuk, A. P. Marchenko, and Georgyi Koidan
- Subjects
chemistry.chemical_classification ,Tris ,Hexamethyldisiloxane ,Inorganic chemistry ,Iodide ,General Medicine ,Methylation ,Medicinal chemistry ,NMR spectra database ,chemistry.chemical_compound ,chemistry ,Phosphorus-31 NMR spectroscopy ,Phosphoric acid ,Methyl iodide - Abstract
The authors have established that hexaalkyltriamidophosphazo groups are unusually strong electron-donor substituents at P /SUP III/ , causing the extremely high basicity of such compounds. This paper performs methylation of tris (tris (N,N-dimethylamido) phosphazo) phosphate and tris (tris (N,N-dimethylamido) phosphazo) methoxyphosphonium iodide (I) using methyl oxide. The NMR spectra were recorded on a Bruker WP-20 spectrometer, and hexamethyldisiloxane and 85% H/sub 3/PO/sub 4/ were used as the standard.
- Published
- 1985
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