1. Dysprosium Single-Molecule Magnets with Bulky Schiff Base Ligands: Modification of the Slow Relaxation of the Magnetization by Substituent Change
- Author
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Liviu F. Chibotaru, Ekaterina Mamontova, Yannick Guari, Anton V. Cherkasov, Konstantin A. Lyssenko, Jérôme Long, Natalia V. Forosenko, Alexander A. Trifonov, Joulia Larionova, Marko Damjanović, Ivan V. Basalov, Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC), G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences [Moscow] (RAS), A. N. Nesmeyanov Institute of Organoelement Compounds (INEOS), Institute for Nanoscale Physics and Chemistry (INPAC), Université Catholique de Louvain = Catholic University of Louvain (UCL), Chimie moléculaire et organisation du solide (CMOS), and Université Montpellier 2 - Sciences et Techniques (UM2)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
Lanthanide ,Schiff base ,010405 organic chemistry ,Organic Chemistry ,Relaxation (NMR) ,Substituent ,chemistry.chemical_element ,General Chemistry ,010402 general chemistry ,01 natural sciences ,Catalysis ,0104 chemical sciences ,3. Good health ,chemistry.chemical_compound ,Magnetization ,Crystallography ,chemistry ,Dysprosium ,Molecule ,[CHIM.COOR]Chemical Sciences/Coordination chemistry ,Bifunctional - Abstract
International audience; We report the synthesis, magnetic and photoluminescence investigations of two bifunctional dysprosium complexes based on tridentate Schiff base ligands. Magnetic investigations reveal a genuine Single-Molecule Magnet (SMM) behavior with out-of-phase signals up to 60 K, and the tunable emission arising from the Schiff base ligands.
- Published
- 2018
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