1. A Solution‐based Method for Synthesizing Pyrite‐type Ferrous Metal Sulfide Microspheres with Efficient OER Activity.
- Author
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Xiang, Wendi, Tian, Qianqiu, Zhong, Cheng, Deng, Yida, Han, Xiaopeng, and Hu, Wenbin
- Subjects
METAL sulfides ,MICROSPHERES ,OXYGEN evolution reactions ,METAL-air batteries ,TRANSITION metals ,PRECIOUS metals - Abstract
Simple and stable synthesis of transition metal sulfides and clarification of their growth mechanisms are of great importance for developing catalysts, metal‐air batteries and other technologies. In this work, we developed a one‐step facile hydrothermal approach to successfully synthesize NiS2 microspheres. By changing the experimental parameters, the reason that affects the formation of nanostructured spheres is investigated and discussed in detail, and the formation mechanism of microspheres is proposed innovatively. Furthermore, electrochemical testing results show that the 7 h‐NiS2 catalyst exhibits a remarkable oxygen evolution reaction (OER) activity with an overpotential of 311 mV at 10 mA cm−2 in 1.0 M KOH, superior to precious metal RuO2. The NiS2 catalyst also exhibits a robust durability. This work will contributes to the rational design and the understanding of growth mechanism of transition metal chalcogenide electrocatalysts for diverse energy conversion technologies. [ABSTRACT FROM AUTHOR]
- Published
- 2020
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