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Start Over Author "Akihiro Kozakai" Journal chemistry - an asian journal
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1. Asymmetric Henry Reaction of Trifluoromethyl Enones with Nitromethane Using a N,N-Dibenzyl Diaminomethylenemalononitrile Organocatalyst.

Author

Masahiro Kawada, Ryo Tsuyusaki, Kosuke Nakashima, Misaki Yamada, Akihiro Kozakai, Yasuyuki Matsushima, Shin-ichi Hirashima, and Tsuyoshi Miura

Subjects
NITROALDOL reactions, NITROMETHANE, CARBONYL compounds
Abstract

A novel N,N-dibenzyl diaminomethylenemalononitrile organocatalyst efficiently promoted asymmetric Henry reactions of trifluoromethyl enones with nitromethane, affording corresponding highly functionalized products in high yields with excellent enantioselectivities (up to 90% ee). This study is the first to report the successful example of the asymmetric 1,2-additions of nitromethane to trifluoromethyl enones. [ABSTRACT FROM AUTHOR]

Published
2022
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