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1. Ligand Substitution of Ru II -Alkylidenes to Ru(bpy) 3 2+ : Sequential Olefin Metathesis/Photoredox Catalysis.

Author

Gallhof M, Kell L, and Brasholz M

Abstract

Ruthenium(II) alkylidene complexes such as the Grubbs' 1st and 2nd generation catalysts undergo a ligand substitution with 2,2'-bipyridine, which readily leads to the common photoredox catalyst Ru(bpy) 3 2+ . The application of this catalyst transformation in sequential olefin metathesis/photoredox catalysis is demonstrated by way of ring-closing metathesis (RCM)/photoredox ATRA reactions., (© 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.)

Published
2020
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