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The contamination of microplastics in aquatic environment is regarded as a serious threat to ecosystem especially to aquatic environment. Microplastic pollution associated problems including their bioaccumulation and ecological risks have become a major concern of the public and scientific community. The removal of microplastics from their discharge points is an effective way to mitigate the adverse effects of microplastic pollution, hence has been the central of the research in this realm. Presently, most of the commonly used water or wastewater treatment technologies are capable of removing microplastic to certain extent, although they are not intentionally installed for this reason. Nevertheless, recognizing the adverse effects posed by microplastic pollution, more efforts are still desired to enhance the current microplastic removal technologies. With their structural multifunctionalities and flexibility, nanomaterials have been increasingly used for water and wastewater treatment to improve the treatment efficiency. Particularly, the unique features of nanomaterials have been harnessed in synthesizing high performance adsorbent and photocatalyst for microplastic removal from aqueous environment. This review looks into the potentials of nanomaterials in offering constructive solutions to resolve the bottlenecks and enhance the efficiencies of the existing materials used for microplastic removal. The current efforts and research direction of which studies can dedicate to improve microplastic removal from water environment with the augmentation of nanomaterial-enabled strategies are discussed. The progresses made to date have witnessed the benefits of harnessing the structural and dimensional advantages of nanomaterials to enhance the efficiency of existing microplastic treatment processes to achieve a more sustainable microplastic cleanup. [Display omitted] • The potentials of nanomaterials for microplastic remediation are reviewed. • Various nanomaterial-enabled removal techniques are discussed. • Nanomaterials overcome the limitations of bulk materials in microplastic remediation. • The challenges and way forward are presented. [ABSTRACT FROM AUTHOR]

Herbicides such as atrazine and humus substances such as fulvic acid are widely used in agricultural sector. They can be traced in surface and groundwater around the agriculture field at concentrations beyond the approved limit due to their mobility and persistence. Bismuth-based photocatalysts activated by visible light are potential materials for removing various organic pollutants from water bodies. These photocatalysts can also be suitable candidates for developing a hybrid membrane with anti-fouling properties. In this study, Bi 2 WO 6 nanoparticles were synthesized via the hydrothermal method and integrated into the cellulose acetate (CA), polyetherimide (PEI), polysulfone (PSF) and polyvinylidene fluoride (PVDF) polymers via physical blending approach. The hybrid membranes were then characterized by FTIR, XPS and FESEM to confirm the chemical bonding, chemical composition and surface morphology of Bi 2 WO 6. Thus, the pure water flux of CA (35.6 L m−2 h−1), PEI (46.56 L m−2 h−1), PSF (6.84 L m−2 h−1), and PVDF (68.47 L m−2 h−1) hybrid membranes has significantly enhanced than the pristine CA, PEI, PSF and PVDF membranes. The significant rejection of atrazine-fulvic acid was observed with hybrid membranes in the order of CA (84.1%) > PVDF (72.7%) > PEI (47.8%) > PSF (37.2%), and these membranes have shown an excellent flux recovery ratio than pristine membranes. Further, electrochemical quantification studies were performed to analyze the removal efficiency of atrazine-fulvic acid from water. In this present work, GO-modified SPE was employed for electrochemical sensing studies. The resultant CA hybrid membrane achieved removal efficiency of 84.08% for atrazine. It was observed that the Bi 2 WO 6 established strong bonding with CA, and PVDF membranes, thus showing a significant removal efficiency and FRR than other hybrid and pristine membranes. [Display omitted] • Bi 2 WO 6 nanoparticles were synthesized by the hydrothermal method. • Hybrid Bi 2 WO 6 incorporated membranes were fabricated using CA, PSF, PEI and PVDF polymers. • The better binding energy of Bi 2 WO 6 was noted with various hybrid membranes via. XPS analysis. • CA, PVDF hybrid membranes showed better rejection towards Atrazine-fulvic acid solution. • Validate the rejection results observed from UV spectroscopy with electrochemical studies. [ABSTRACT FROM AUTHOR]

The noxious side effects of pesticides on human health and environment have prompted the search of effective and reliable treatment techniques for pesticide removal. The removal of pesticides can be accomplished through physical, chemical and biologicals. Physical approaches such as filtration and adsorption are prevailing pesticide removal strategies on account of their effectiveness and ease of operation. Membrane-based filtration technology has been recognized as a promising water and wastewater treatment approach that can be used for a wide range of organic micropollutants including pesticides. Nanofiltration (NF), reverse osmosis (RO) and forward osmosis (FO) have been increasingly explored for pesticide removal from aquatic environment owing to their versatility and high treatment efficiencies. This review looks into the remedial strategies of pesticides from aqueous environment using membrane-based processes. The potentials and applications of three prevailing membrane processes, namely NF, RO and FO for the treatment of pesticide-containing wastewater are discussed in terms of the development of advanced membranes, separation mechanisms and system design. The challenges in regards to the practical implementation of membrane-based processes for pesticide remediation are identified. The corresponding research directions and way forward are highlighted. An in depth understanding of the pesticide nature, water chemistry and the pesticide-membrane interactions is the key to achieving high pesticide removal efficiency. The integration of membrane technology and conventional removal technologies represents a new dimension and the future direction for the treatment of wastewater containing recalcitrant pesticides. [Display omitted] • The potentials of membrane technology for pesticides removal are reviewed • The rejection is governed by pesticide nature, water chemistry and membrane properties • NF, RO and FO are the key membrane processes for pesticide removal • Integrated membrane processes offer the most efficient pesticide removal [ABSTRACT FROM AUTHOR]