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The combustion of polyamide 6 (PA6) fabrics releases toxic smoke, which will pollute the environment and threaten human life and health. Herein, a novel eco-friendly flame-retardant coating was constructed and applied to PA6 fabrics. Needle-like β-FeOOH with a high surface area was firstly constructed onto the surface of PA6 fabrics by the hydrolysis of Fe3+, sulfamic acid (SA) was then introduced by a facile dipping and nipping method. The growth of β-FeOOH also endowed the PA6 fabrics with certain hydrophilicity and moisture permeability, resulting in improved comfortability. The limiting oxygen index (LOI) of the prepared PA6/Fe/6SA sample was increased to 27.2% from 18.5% of control PA6 sample, and the damaged length was reduced to only 6.0 cm from 12.0 cm of control PA6 sample. Meanwhile, the melt dripping was also eliminated. The heat release rate and total heat release values of the PA6/Fe/6SA sample were decreased to 318.5 kW/m2 and 17.0 MJ/m2, respectively, compared with those of control PA6 (494.7 kW/m2 and 21.4 MJ/m2). The analysis results indicated that nonflammable gases diluted flammable gases. The observation of char residues demonstrated that the stable char layer was formed, which effectively inhibited the transfer of heat and oxygen. The organic solvent-free coating does not contain any conventional halogens/phosphorus elements, which provides a useful methodology to produce environmentally friendly flame-retardant fabrics. [Display omitted] • An eco-friendly coating containing sulfamic acid (SA) and β-FeOOH was constructed. • The halogens and phosphorus elements were not involved in the organic solvent free coating. • β-FeOOH as a scaffold to provide space for the adsorption of sulfamic acid (SA). • The coated PA6 fabrics displayed excellent flame retardancy without dripping. • The coating increased the hydrophilicity and moisture permeability of PA6 fabrics. [ABSTRACT FROM AUTHOR]