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The production of low-cost solid adsorbents for carbon dioxide (CO 2 ) capture has gained massive consideration. Biomass wastes are preferred as precursors for synthesis of CO 2 solid adsorbents, due to their high CO 2 adsorption efficiency, and ease of scalable low-cost production. This review particularly focuses on waste biomass-derived adsorbents with their CO 2 adsorption performances. Specifically, studies related to carbon (biochar and activated carbon) and silicon (silicates and geopolymers)-based adsorbents were summarized. The impact of experimental parameters including nature of biomass, synthesis route, carbonization temperature and type of activation methods on the CO 2 adsorption capacities of biomass-derived pure carbon and silicon-based adsorbents were evaluated. The development of various enhancement strategies on biomass-derived adsorbents for CO 2 capture and their responsible factors that impact adsorbent's CO 2 capture proficiency were also reviewed. The possible CO 2 adsorption mechanisms on the adsorbent's surface were highlighted. The challenges and research gaps identified in this research area have also been emphasized, which will help as further research prospects., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The global level of attention has been raised for photocatalytic pollutant removal technologies for degrading organic pollutants because of rising concerns about their toxicity. In this study, NiFe 2 O 4 /TiO 2 core shells and pure samples of NiFe 2 O 4 and TiO 2 were synthesized using the sol-gel process and used to degrade naphthalene which is one among the polycyclic aromatic hydrocarbons (PAHs) pollutant. The synthesized materials were evaluated using a variety of analytical techniques, and the typical NiFe 2 O 4 /TiO 2 core-shell results showed good purity and a lack of other impurity structures. Through morphological characterization, the core-shell structure of NiFe 2 O 4 /TiO 2 has been established. However, the activity of visible light degradation was boosted by the generation of hydroxyl radicals after the electron-hole pair was delayed. Additionally, a lower band gap in NiFe 2 O 4 /TiO 2 than in pure materials promotes photocatalytic activity. Similarly, photocatalytic naphthalene elimination by the core-shell achieved 67% efficiency after 150 min of visible light exposure. Furthermore, the produced core-shell has a high magnetic property, making separation from the photo-irradiated solutions easier; as a result, recycling was likely successful up to three cycles. The photocatalytic mechanism of the NiFe 2 O 4 /TiO 2 composite was proposed. This research could also be applied to the degradation of other polycyclic aromatic hydrocarbon contaminants., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Carbon-integrated binary metal oxide semiconductors have gained prominence in the last decade as a better material for photocatalytic wastewater treatment technology. In this regard, this research describes the investigation of the binary metal oxide TiO 2 @Fe 3 O 4 embedded on reduced graphene oxide (rGO) nanosheets synthesized through a combination of sol-gel, chemical precipitation, and Hummer's processes. Besides, the catalyst is applied for the photocatalytic degradation of organic chlorophenol pollutants. The characterized diffraction results showed the peak broadening of the rGO-TiO 2 @Fe 3 O 4 composite formed with tetragonal and cubic structures having small crystallite sizes. The TEM observation shows an enormous miniature of TiO 2 @Fe 3 O 4 nanospheres spread on the folded 2D-rGO nanosheets with a large BET surface area. The XPS result holds the mixed phases of Fe 3 O 4 and Fe 2 O 3 . Finally, the catalyst demonstrated a low band gap with extended light absorption towards visible light irradiation. The synergistic interactions between Fe 3+ and Fe 2+ improved the visible light activity due to the incorporation of rGO, and also possessed good recycling capacity. The increased mobility of electrons at the interfaces of TiO 2 and Fe 3 O 4 due to the mixing of rGO results in the separation of charge carriers by elevating the photocatalytic degradation efficiency of chlorophenol., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The notion of innovative combinations of semiconducting metal oxides for photocatalytic destruction is a key factor in the removal of environmental contaminants. However, for the first time, the combination was made possible for the aforementioned reason by embedding one-dimensional titanium dioxide (TiO 2 ) semiconductor nanorods on two-dimensional rGO (reduced graphene oxide) nanosheets utilizing hydrothermal and a modified Hummers' method. By applying several sophisticated procedures, the properties of these catalysts were found, and then the degradation of BPA (bisphenol-A) was examined with UV and visible light sources. Further, all the analyses were performed on pure TiO 2 material. As a result of the synergistic interaction between TiO 2 and rGO, the rGO-TiO 2 catalyst produced a favorable photocatalytic outcome. The structural investigation of rGO-TiO 2 has confirmed that the TiO 2 was in anatase phase along with GO and rGO peaks, and the morphological characterization showed that the TiO 2 nanorods were integrated randomly into the rGO nanosheets along with defective sites. Also, adding rGO to TiO 2 causes charge separation, and π-π interactions to improve the visible light absorption range. In this study, the main model organic component in the photocatalytic degradation is bisphenol-A (BPA). During visible light irradiation, the OH radicals were finally produced by the redox reactions. Furthermore, the rGO surface adsorbs the phenol molecules due to graphene π-π interactions, thus narrowing the band gap and increasing the efficiency of BPA degradation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Over the past decades, increasing research in metal-organic frameworks (MOFs) being a large family of highly tunable porous materials with intrinsic physical properties, show propitious results for a wide range of applications in adsorption, separation, electrocatalysis, and electrochemical sensors. MOFs have received substantial attention in electrochemical sensors owing to their large surface area, active metal sites, high chemical and thermal stability, and tunable structure with adjustable pore diameters. Benefiting from the superior properties, MOFs and MOF-derived carbon materials act as promising electrode material for the detection of food contaminants. Although several reviews have been reported based on MOF and its nanocomposites for the detection of food contaminants using various analytical methods such as spectrometric, chromatographic, and capillary electrophoresis. But there no significant review has been devoted to MOF/and its derived carbon-based electrodes using electrochemical detection of food contaminants. Here we review and classify MOF-based electrodes over the period between 2017 and 2022, concerning synthetic procedures, electrode fabrication process, and the possible mechanism for detection of the food contaminants which include: heavy metals, antibiotics, mycotoxins, and pesticide residues. The merits and demerits of MOF as electrode material and the need for the fabrication of MOF and its composites/derivatives for the determination of food contaminants are discussed in detail. At last, the current opportunities, key challenges, and prospects in MOF for the development of smart sensing devices for future research in this field are envisioned., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Vanadia (V 2 O 5 )-incorporated fibrous silica-titania (V/FST) catalysts, which were successfully synthesized using a hydrothermal method followed by the impregnation of V 2 O 5 . The catalysts were then characterized using numerous techniques, including X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, nitrogen adsorption-desorption analyses, ultraviolet-visible diffuse reflectance spectroscopy, Fourier-transform infrared, X-ray photoelectron spectroscopy, and photoluminescence (PL) analyses. The study found that varying the amount of V 2 O 5 (1-10 wt%) had a significant impact on the physicochemical properties of the FST, which in turn improved the photodegradation efficiency of two organic compounds, ciprofloxacin (CIP) and congo red (CR). 5V/FST demonstrated the best performance in degrading 10 mg L -1 of CIP (83%) and CR (100%) at pH 3 using 0.375 g L -1 catalyst under visible light irradiation within 180 min. The highest photoactivity of 5V/FST is mainly due to higher crystallinity and the highest number of V 2 O 5 -FST interactions. Furthermore, as demonstrated by PL analysis, the 5V/FST catalyst has the most significant impact on interfacial charge transfer and reduces electron-hole recombination. The photodegradation of both contaminants follows the Langmuir-Hinshelwood pseudo-first-order model, according to the kinetic study. The scavenger investigation demonstrated that hydroxyl radicals and holes dominated species in the system, indicating that the catalyst effectively generated reactive species for pollutant degradation. A possible mechanism was also identified for FST and 5V/FST. Interestingly, V 2 O 5 acts as an electron-hole recombination inhibitor on FST for selective hole oxidation of ciprofloxacin and congo red photodegradation. Finally, the degradation efficiency of the catalyst remained relatively stable even after five cyclic experiments, indicating its potential for long-term use in environmental remediation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Pendimethalin (PND) is a herbicide that is regarded to be possibly carcinogenic to humans and toxic to the environment. Herein, we fabricated a highly sensitive DNA biosensor based on ZIF-8/Co/rGO/C 3 N 4 nanohybrid modification of a screen-printed carbon electrode (SPCE) to monitor PND in real samples. The layer-by-layer fabrication pathway was conducted to construct ZIF-8/Co/rGO/C 3 N 4 /ds-DNA/SPCE biosensor. The physicochemical characterization techniques confirmed the successful synthesis of ZIF-8/Co/rGO/C 3 N 4 hybrid nanocomposite, as well as the appropriate modification of the SPCE surface. The utilization of ZIF-8/Co/rGO/C 3 N 4 nanohybrid as a modifier was analyzed using. The electrochemical impedance spectroscopy results showed that the modified SPCE exhibited significantly lowered charge transfer resistance due to the enhancement of its electrical conductivity and facilitation of the transfer of charged particles. The proposed biosensor successfully quantified PND in a wide concentration range of 0.01-35 μM, with a limit of detection (LOD) value of 8.0 nM. The PND monitoring capability of the fabricated biosensor in real samples including rice, wheat, tap, and river water samples was verified with a recovery range of 98.2-105.6%. Moreover, to predict the interaction sites of PND herbicide with DNA, the molecular docking study was performed between the PND molecule and two sequence DNA fragments and confirmed the experimental findings. This research sets the stage for developing highly sensitive DNA biosensors that will be used to monitor and quantify toxic herbicides in real samples by fusing the advantages of nanohybrid structures with crucial knowledge from a molecular docking investigation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Despite of our growing understanding of microplastic's implications, research on the effects of fibrous microplastic (FMPs) on the environment is still in its infancy. Some scientists have hypothesized the possibility of natural textile fibres, which may act as one of the emerging environmental pollutants prevalent among microplastic pollutants in the environment. Therefore, this review aims to critically evaluate the toxic effects of emerging FMPs, the presence, and sources of FMPs in the environment, identification and analytical techniques, and the potential impact or toxicity of the FMPs on the environment and human health. About175 publications (2011-2023) based on FMPs were identified and critically reviewed for transportation, analysis and ecotoxicological behaviours of FMPs in the environment. Textile industries, wastewater treatment plants, and household washing of clothes are significant sources of FMPs. In addition, various characterization techniques (e.g., FTIR, SEM, RAMAN, TGA, microscope, and X-Ray Fluorescence Spectroscopy) commonly used for the identification and analysis of FMPs are also discussed, which justifies the novelty aspects of this review. FMPs are pollutants of emerging concern due to their prevalence and persistence in the environment. FMPs are also found in the food chain, which is an alarming situation for living organisms, including effects on the nervous system, digestive system, circulatory system, and genetic alteration. This review will provide readers with a comparison of different analytical techniques, which will be helpful for researchers to select the appropriate analytical techniques for their study and enhance their knowledge about the harmful effects of FMPs., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Water contamination due to soluble synthetic dyes has serious concerns. Membrane-based wastewater treatments are emerging as a preferred choice for removing dyes from water. Poly(vinylidene fluoride) (PVDF)-based nanomembranes have gained much popularity due to their favorable features. This review explores the application of PVDF-based nanomembranes in synthetic dye removal through various treatments. Different fabrication methods to obtain high performance PVDF-based nanomembranes were discussed under surface coating and blending methods. Studies related to use of PVDF-based nanomembranes in adsorption, filtration, catalysis (oxidant activation, ozonation, Fenton process and photocatalysis) and membrane distillation have been elaborately discussed. Nanomaterials including metal compounds, metals, (synthetic/bio)polymers, metal organic frameworks, carbon materials and their composites were incorporated in PVDF membrane to enhance its performance. The advantages and limitations of incorporating nanomaterials in PVDF-based membranes have been highlighted. The influence of nanomaterials on the surface features, mechanical strength, hydrophilicity, crystallinity and catalytic ability of PVDF membrane was discussed. The conclusion of this literature review was given along with future research., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The cupric oxide (CuO) loaded graphitic carbon nitride (g-C 3 N 4 ) nanocomposites (CuO/g-C 3 N 4 ) were prepared by a facile calcination method. The formation of monoclinic CuO nanocrystals along with g-C 3 N 4 was confirmed by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopic analysis. X-ray photoelectron spectral (XPS) analysis further confirms the formation of CuO/g-C 3 N 4 . Distribution of CuO stone-like crystalline nanoparticles on g-C 3 N 4 nanosheets was observed by transmission electron microscopic images. The influence of CuO loading on the optical property of g-C 3 N 4 was determined by ultraviolet (UV)-visible absorption and photoluminescence (PL) spectral analysis. Band gap was decreased from 2.7 to 2.3 eV by the addition of CuO nanoparticles. The catalytic performance of the synthesized samples in 4-nitrophenol (4-NP) and methyl orange (MO) reduction was evaluated. The 5 wt% CuO/g-C 3 N 4 showed 99.5% (7 min) and 99.7% (4 min) reduction efficiency for 4-NP and MO respectively. The 5 wt% CuO/g-C 3 N 4 could become a potential catalyst in the chemical treatment of organic pollutants., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Biogas consisting of carbon dioxide/methane (CO 2 /CH 4 ) gas mixtures has emerged as an alternative renewable fuel to natural gas. The presence of CO 2 can decrease the calorific value and generate greenhouse gas. Hence, separating CO 2 from CH 4 is a vital step in enhancing the use of biogas. Zeolite and zeolite-based mixed matrix membrane (MMM) is considered an auspicious candidate for CO 2 /CH 4 separation due to thermal and chemical stability. This review initially addresses the development of zeolite and zeolite-based MMM for the CO 2 /CH 4 separation. The highest performance in terms of CO 2 permeance and CO 2 /CH 4 selectivity was achieved using zeolite and zeolite-based MMM, which exhibited CO 2 permeance in the range of 2.0 × 10 - 7 -7.0 × 10 - 6  mol m - 2  s - 1  Pa - 1 with CO 2 /CH 4 selectivity ranging from 3 to 300. Current trends directed toward improving CO 2 /CH 4 selectivity via modification methods including post-treatment, ion-exchanged, amino silane-grafted, and ionic liquid encapsulated of zeolite-based MMM. Those modification methods improved the defect-free and interfacial adhesions between zeolite particulates and polymer matrices and subsequently enhanced the CO 2 /CH 4 selectivity. The modifications via ionic liquid and silane methods more influenced the CO 2 /CH 4 selectivity with 90 and 660, respectively. This review also focuses on the possible applications of zeolite-based MMM, which include the purification and treatment of water as well as biomedical applications. Lastly, future advances and opportunities for gas separation applications are also briefly discussed. This review aims to share knowledge regarding zeolite-based MMM and inspire new industrial applications., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

The presence of pollutants in waste water is a demanding problem for human health. Investigations have been allocated to study the adsorptive behavior of graphene-based materials to remove pollutants from wastewater. Graphene (GO) due to its hydrophilicity, high surface area, and oxygenated functional groups, is an effective adsorbent for the removal of dyes and heavy metals from water. The disclosure of green synthesis opened the gateway for the economic productive methods. This article reveals the fabrication of graphene-based composite from aloe vera extract using a green method. The proposed mechanism of GO reduction via plant extract has also been mentioned in this work. The mechanism associated with the removal of dyes and heavy metals by graphene-based adsorbents and absorptive capacities of heavy metals has been discussed in detail. The toxicity of heavy metals has also been mentioned here. The Polyaromatic resonating system of GO develops significant π-π interactions with dyes whose base form comprises principally oxygenated functional groups. This review article illustrates a literature survey by classifying graphene-based composite with a global market value from 2010 to 2025 and also depicts a comparative study between green and chemical reduction methods. It presents state of art for the fabrication of GO with novel adsorbents such as metal, polymer, metal oxide and elastomers-based nanocomposites for the removal of pollutants. The current progress in the applications of graphene-based composites in antimicrobial, anticancer, drug delivery, and removal of dyes with photocatalytic efficacy of 73% is explored in this work. It gives a coherent overview of the green synthesis of graphene-based composite, various prospective for the fabrication of graphene, and their biotoxicity., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

A simple and cost-effective route has been utilized for the preparation of a novel lamellar structured FeOCl/g-C 3 N 5 nanocomposite as Z-scheme photocatalyst. The preparation method was performed under the ambient temperature conditions without any hazardous chemicals. Various characterization techniques, namely XRD, FESEM, TEM, FT-IR, UV-Vis, DRS, and PL were carried out to analyse the nanocomposite for confirmation of FeOCl/g-C 3 N 5 nanocomposite. To evaluate its and visible light degradation performances tetracycline (T-C) was used as target pollutant. Among the optimum loading for the g-C 3 N 5 incorporated FeOCl binary nanocomposites, the g-C 3 N 5 /FeOCl exhibited a superlative degradation performance toward the T-C antibiotic pollutant. The results confirmed that 95% of T-C was degraded within 40 min under photodegradation mechanism. The improved photodegradation performance in degradation of T-C was mainly due to the reduction in electron-hole recombination, broadening in the light absorption by g-C 3 N 5 incorporation, which leads to shortening the degradation time. Furthermore, the hydroxyl and superoxide radicals played a major role in the photodegradation process and the possible mechanism was elucidated and proposed. The present work implies a novel, sustainable, and efficient Z-scheme system that may deliver a convenient method for environment remediation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Globally, ecotoxicologists, environmental biologists, biochemists, pathologists, and other experts are concerned about environmental contamination. Numerous pollutants, such as harmful heavy metals and emerging hazardous chemicals, are pervasive sources of water pollution. Water pollution and sustainable development have several eradication strategies proposed and used. Biosorption is a low-cost, easy-to-use, profitable, and efficient method of removing pollutants from water resources. Microorganisms are effective biosorbents, and their biosorption efficacy varies based on several aspects, such as ambient factors, sorbing materials, and metals to be removed. Microbial culture survival is also important. Biofilm agglomerates play an important function in metal uptake by extracellular polymeric molecules from water resources. This study investigates the occurrence of heavy metals, their removal by biosorption techniques, and the influence of variables such as those indicated above on biosorption performance. Ion exchange, complexation, precipitation, and physical adsorption are all components of biosorption. Between 20 and 35 °C is the optimal temperature range for biosorption efficiency from water resources. Utilizing living microorganisms that interact with the active functional groups found in the water contaminants might increase biosorption efficiency. This article discusses the negative impacts of microorganisms on living things and provides an outline of how they affect the elimination of heavy metals., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Microalgae-based wastewater treatment has previously been carried out in huge waste stabilization ponds. Microalgae, which can absorb carbon dioxide while reusing nutrients from sewage, has recently emerged as a new trend in the wastewater treatment business. Microalgae farming is thought to be a potential match for the modern world's energy strategy, which emphasizes low-cost and environmentally benign alternatives. Microalgae are being used to treat wastewater and make useful products. Microalgae, for example, is a promising renewable resource for producing biomass from wastewater nutrients because of its quick growth rate, short life span, and high carbon dioxide utilization efficacy. Microalgae-based bioremediation has grown in importance in the treatment of numerous types of wastewater in recent years. This solar-powered wastewater treatment technology has huge potential. However, there are still issues to be resolved in terms of land requirements, as well as the process's ecological feasibility and long-term viability, before these systems can be widely adopted. Due to cost and the need for a faultless downstream process, it is difficult to deploy this technology on a large scale. Other recent breakthroughs in wastewater microalgae farming have been investigated, such as how varied pressures affect microalgae growth and quality, as well as the number of high-value components produced. In this review, the future of this biotechnology has also been examined., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

This review provides a quantitative description of the nano-adsorbent processing and its viability against wastewater detoxification by extracting heavy metal ions. The impact of nano-adsorbent functionalities on specific essential attributes such as the surface area, segregation, and adsorption capacity were comprehensively evaluated. A detailed analysis has been presented on the characteristics of nanomaterials through their limited resistance to adsorb some heavy metal ions. Experimental variables such as the adsorbent dosage, pH, substrate concentration, response duration, temperature, and electrostatic force that influence the uptake of metal ions have been studied. Besides, separate models for the adsorption kinetics and isothermal adsorption have been investigated to understand the mechanism behind adsorption. Here, we reviewed the different adsorbent materials with nano-based techniques for the removal of heavy metals from wastewater and especially highlighted the nano adsorption technique. The influencing factors such as pH, temperature, dosage time, sorbent dosage, adsorption capacities, ion concentration, and mechanisms related to the removal of heavy metals by nano composites are highlighted. Lastly, the application potentials and challenges of nano adsorption for environmental remediation are discussed. This critical review would benefit engineers, chemists, and environmental scientists involved in the utilization of nanomaterials for wastewater treatment., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

When it comes to electrocatalysis, the creation of nanodevices, the research of energy and the environment, and diagnostics, nanoporous materials are an asset. Nanoporous membranes, which can be used to filter water, have recently been the subject of new research and are summarized in this review. These membranes are used to remove salts and metallic ions from the water following an analysis of several nanoporous membrane types and production procedures. Demonstrations and discussions of these membrane systems are then conducted. Nanoporous membranes can be used to filter water, according to the conclusions of this study, which will help readers better grasp how they work. As a result, novel water purification nanoporous compounds that are easy to manufacture, inexpensive, and effective will be developed. Merits and demerits of nanoporous membrane for water treatment and its advancements in purification were discussed., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

In the search of the viable candidate for the sensing of pollutant gases, two-dimensional (2D) material transition metal carbides (MXenes) have attracted immense attention due to their outstanding physical and chemical properties for sensing purposes. The formation of unique 2D layered structure with high conductivity, large mechanical strength, and high adsorption properties furnish their strong interactions with gaseous molecules, which holds a promising place for developing ideal gas sensing devices. This review looks at recent achievements in diversified MXenes, with a focus gaining on in-depth understanding of MXene-based materials in room temperature inorganic gas sensors through both theoretical and experimental studies. In the first part of the review, the properties and advantages of sensing material (MXene) in comparison with other 2D materials are discussed. In the second part, the unique advantages of chemiresistive based sensors and the demerits of other detection methods are summarized in detail. This section is followed by the unique structural design of MXene bases materials for improving the sensing performance towards detection of inorganic gases. The interaction between MXene and the adsorbed gases on its surface is discussed, with a possible sensing mechanism. Finally, an overview of the current progress and opportunities for the demand of MXene is emphasized and perspectives for future improvement of the design of MXene in gas sensors are highlighted. Therefore, this review highlights the opportunities and the advancement in 2D material-based gas sensors which could provide a new avenue for rapid detection of toxic gases in the environment., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Harmful Algal Blooms (HABs) have turned out to be a global occurrence owing to the detrimental phenomenon like eutrophication and global climate change caused by human activities. This newly emergent threat imposes a severe hazardous to public health, ecosystems and fishery-based economies. Rapid and exponential growth of certain delirious and toxic algal species shall be held causative to the formation of HABs. The potential disadvantages they pose, make it necessary the identification of efficient treatment methodologies. Photocatalysis has been identified as the most promising solution amongst all the identified and investigated methods, for the environmental and economic benefits beheld. Different treatment methodologies were evaluated and light has been thrown on the advantages beheld by photocatalysis over the other methods. Focus has been given to the different photocatalysts that have been so far put to use towards photocatalytic disinfection of HABs and algal toxins. This present study provides useful information on the application of the traditional and photocatalysis process for removal of HABs in water bodies. Moreover, the results revealed that photocatalysis method could cause potent inhibitory effect on growth of algae species and disrupted algal cells membranes to some extent. Finally, the conventional treatment techniques have been recognized to be insufficient for removal of HABs. However, the photocatalyst technology have been utilized mostly for the mineralization and neutralization of the algal pollutants without any harmful secondary pollutants., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Phenolic compounds would be the emerging pollutant by 2050, because of their wide spread applicability in daily life and therefore the adoption of suitable detection methods in which identification and separation of isomers is highly desirable. Owing to the fascinating features, Metal-organic framework (MOF), a class of reticular materials holds a large surface area with tunable shape and adjustable porosity will provide strong interaction with analytes through abundant functional groups resulting in high selectivity towards electrochemical determination of phenolic isomers. Nevertheless, the sensing performance can still be further improved by building MOF network (intrinsic resistance) with functional (conducting) materials, resulting in MOF based nanocomposite. Herein, this review provides the summary of MOF based nanocomposites for electrochemical sensing of phenolic compounds developed from 2015. In this review, we discussed the demerits of pristine MOF as electrode materials, and the requirement of new class of MOF with functional materials such as nanomaterials, carbon nanotubes, graphene and MXene. The history and evolution of MOF nanocomposite-based materials are discussed and also featured the impressive physical and chemical properties. Besides this review discusses the factors influencing the conducting pathway and mass transport of MOF based nanocomposite for enhanced sensing performance of phenolic compounds with suitable mechanistic illustrations. Finally, the major challenges governing the determination of phenolic compounds and the future advancements required for the development of MOF based electrodes for various applications are highlighted., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Water is the lifeblood of all living things; we often overlook the fact that the water cycle and the life cycle are inextricably linked. However, it has become contaminated as a result of industrialization, which has impacted the ecosystem by emitting numerous dyes, organic solvents, petroleum products, heavy metals, chemicals, diseases, and solid wastes. The absence of treatment in reusing wastewater is the root of the issues. Hence it is essential to treat the water to preserve the ecosystem and also for human health. In recent years, graphene-based photocatalysts are attracted much in the waste water treatment process due to their outstanding physical, chemical, and mechanical properties. Since in the graphene-based photocatalyst, graphene has exceptional electron conductivity, a broad range of light absorption, a large surface area, and a high adsorption capacity. When it is integrated into metals, metal-containing nanocomposites, semiconductor nanocomposites, polymers, MXene, and other compounds, it can greatly boost the photocatalytic activity towards the photo destruction of contaminants. Hence in this review, water pollution, methods of waste water treatment, fundamental principles of photocatalysis, the photocatalytic activity of other materials in wastewater treatment, and how the photocatalytic efficiency against the removal of organic dyes can be enhanced when coalesced with graphene are detailed., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Carbon-related materials are now widely investigated in a various industrial field due to their excellent and unique qualities. It must be tailored to the application in such a way that it fits the application. At the same time, it needs to be generated in sufficient quantities for commercial use, and the synthesis method is the major sticking point here. Because most new materials are discovered by chance, the synthesis process described here may not be the most effective way to create them. The research is merely a steppingstone to discovering a different approach, and it will continue until the substance is no longer being used. If you're developing materials for any purpose, synthesis processes are essential. Fullerene, carbon nanotubes (CNT), graphene, and MXene are only a few of the carbon-based compounds discussed in this overview study, which also gives a brief prognosis on the materials future. Furthermore, the environmental application of these carbon materials was discussed and commented., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Microplastics (MPs) are developing as persistent pollutants that are causing significant concern in terms of environmental health. A microplastic is a particle of plastic that is less than 5 mm in diameter, which has penetrated and harmed the environment. MPs have been the subject of numerous analyses, including several adverse assessments; however, most of these studies have focused on their presence in coastal environments. The current state of knowledge regarding the characteristics, occurrences, and potential impact of MPs in the terrestrial ecosystem is incomplete. The goal of this study is to undertake a thorough review of existing knowledge and scientific publications on MP occurrences in the environment, their fate and mobility, and their consequences, as well as to explore such discoveries. MPs have been elaborately discussed in this review in terms of their occurrences, features, and origins in the oceans, freshwater, sediments, soils, and the atmosphere, along with the data obtained from experiments and models on the fate and mobility of MPs in the environment. This paper also includes research data on the environmental toxicity, bioavailability, and bioaccumulation of MPs., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Pharmaceutical organics are a vital milestone in contemporary human research since they treat various diseases and improve the quality of human life. However, these organic compounds are considered one of the major environmental hazards after the conception, along with the massive rise in antimicrobial resistance (AMR) in an ecosystem. There are various biological and catalytic technologies existed to eliminate these organics in aqueous system with their limitation. Advanced Oxidation processes (AOPs) are used to decompose these pharmaceutical organic compounds in the wastewater by generating reactive species with high oxidation potential. This review focused various photocatalysts, and photocatalytic oxidation processes, especially core-shell materials for photo (electro)catalytic application in pharmaceutical wastewater decomposition. Moreover, we discussed in details about the design and recent developments of core shell catalysts and comparison for photocatalytic, electrocatalytic and photo electrocatalytic applications in pharmaceutical wastewater treatment. In addition, the mixture of inorganic and organic core-shell materials, and metal-organic framework-based core-shell catalysts discussed in detail for antibiotic degradation., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Herein, we propose a facile electrochemical sensing platform for urea detection using pencil graphite electrode modified nanocomposites of CuO/ZnO and Fe 2 O 3 /ZnO. The detection of urea is essential to monitor for identifying its pollution in the water, at the soil surface and in diagnosing urea cycle disorder related diseases. Therefore, an effective, accurate, cost-effective method of diagnosis is urgently needed. Nanostructured metal oxides have the potential ability to detect molecules even at trace level and to explore this, the present work is formulated with Cu and Fe based ZnO nanocomposites for enhancing the sensing performance towards electrochemical sensing of urea. The sensing responses were confirmed from the increase in oxidation current with respect to the concentration of urea. The results show that Fe 2 O 3 /ZnO coated graphite electrode has a higher response against urea compared to ZnO and CuO/ZnO. The cyclic voltammetry studies also validate urea sensing of Fe-ZnO in the linear range of 0.8 μg/mL to 4 μg/mL, with the detection limit of 2.5 μg/mL. This suggests that the cost-effective pencil graphite electrode modified Fe 2 O 3 /ZnO can be utilized as a promising analytical tool for urea sensing., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Metal Organic Frameworks (MOFs) with natural clay materials is a relatively new research avenue that appears to reduce high production costs and address the instability issues of pure MOFs. A novel MOF and natural clay composites of MOF@Sp_n (n = 1-4) were fabricated by the in situ precipitation of stable MOF, Zr 6 O 4 (OH) 4 (ABDC) 6 (where ABDC = 2-aminobenzene-1,4-dicarboxylic acid), over natural sepiolite (Sp) clay and used as a photocatalysts for elimination of organic dyes in aqueous media. The formation of MOF@Sp_n due to its strong electrostatic interactions between the positively charged MOF and the negatively charged sepiolite. Optimizing the Sp content in the composite strongly influenced the dispersibility, crystallinity of MOFs, resulting in progressively functional hybrid materials with an excellent optoelectronic properties. The composites lessened the shortcomings of the individual components and made them suitable as a visible light-active, highly efficient, standalone photocatalyst material that can degrade RhB., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

In this world, water is considered as the Elixir for all living creatures. Human life rolls with water, and every activity depends upon water. Worldwide water resources are being contaminated due to the elevation in the population count, industrialization and urbanization. Ejection of chemicals by industries and domestic sewages remains the major reason in the destruction of natural water resources. Contaminated water with harmful microbes, chemical dyes, pesticides, and carcinogens are the root cause of many diseases and deaths of living species. In this scenario, researchers engaged in producing ultra components to remove the contaminants. Metal organic frameworks (MOF) are the desired combination of organic and inorganic materials to achieve the required target. MOFs possess unique characteristics like tunable internal structure, porosity, crystallinity and high surface area which enable them for energy and environmental application. For the past years, MOFs are concentrated more as a photocatalyst in the treatment of polluted water. These research studies discuss the improvement of photocatalytic performance of MOF by the incorporation of metals, metal coupled with nanoparticles like polymers, graphene, etc., into it to achieve the enhanced photocatalytic activity by scavenging entire chemicals and harmful microbes to retain the quality of water. The target of this review article is to focus on the state of the art research work on MOFs in photocatalytic water treatment technique., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

In this work, we examined the possibility on the application of rice husk as biosorbent for the elimination of heavy metal ions (chromium, lead, and zinc) existing in the aqueous solutions. The biosorbent was prepared from rice husk powder and modified with 0.1 N of HCl for creating the functional groups and increase specific surface area. The FT-IR spectra, SEM& EDX studies of rice hulls powder were examined for the pristine adsorbent and after the adsorption of heavy metal ions. The batch adsorption technique was adopted for this work and adsorption parameters were optimized. The maximum efficiency of adsorption is obtained at 6.0 pH, 1 h of contact duration, the rice husk dosage is 2.5 g/L, and temperature of 30°C for 25 mg/L of Cr, Pb & Zn metal ion solutions. The Cr, Pb & Zn metal ions are removed up to 87.12 %, 88.63 % & 99.28 %, respectively, using the rice husk powder. The adsorption process follows the Temkin & D-R isotherm model. Elovich model was fitted against the kinetic data of metal ion adsorption. Based on the experimental observations, the rice husk powder can be considered as a low cost adsorbent for heavy metal ion removal from the industrial effluent., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

At present, water pollution and demand for clean energy are most pressing global issues. On a daily basis, huge quantity of organic wastes gets released into the water ecosystems, causing health related problems. The need-of-the-hour is to utilize proficient and cheaper techniques for complete removal of harmful organic contaminants from water. In this regard, microbial fuel cell (MFC) has emerged as a promising technique, which can produce useful electrical energy from organic wastes and decontaminate polluted water. Herein, we have systematically reviewed recently published results, observations and progress made on the applications of MFCs in degradation of organic contaminants, including organic synthetic dyes, agro pollutants, health care contaminants and other organics (such as phenols and their derivatives, polyhydrocarbons and caffeine). MFC-based hybrid technologies, including MFC-constructed wetland, MFC-photocatalysis, MFC-catalysis, MFC-Fenton process, etc., developed to obtain high removal efficiency and bioelectricity production simultaneously have been discussed. Further, this review assessed the influence of factors, such as nature of electrode catalysts, organic pollutants, electrolyte, microbes and operational conditions, on the performance of pristine and hybrid MFC reactors in terms of pollutant removal efficiency and power generation simultaneously. Moreover, the limitations and future research directions of MFCs for wastewater treatment have been discussed. Finally, a conclusive summary of the findings has been outlined., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Heavy metal pollution remains a global environmental challenge that poses a significant threat to human life. Various methods have been explored to eliminate heavy metal pollutants from the environment. However, most methods are constrained by high expenses, processing duration, geological problems, and political issues. The immobilization of metals, phytoextraction, and biological methods have proven practical in treating metal contaminants from the soil. This review focuses on the general status of heavy metal contamination of soils, including the excessive heavy metal concentrations in crops. The assessment of the recent advanced technologies and future challenges were reviewed. Molecular and genetic mechanisms that allow microbes and plants to collect and tolerate heavy metals were elaborated. Tremendous efforts to remediate contaminated soils have generated several challenges, including the need for remediation methodologies, degrees of soil contamination, site conditions, widespread adoptions and various possibilities occurring at different stages of remediation are discussed in detail., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Due to the continuous increase in industrial pollution and modern lifestyle, several types of air contaminants and their concentrations are emerging in the atmosphere. Besides, photocatalysis has gained much attention in the elimination of air pollution. Several ultraviolet and visible light active photocatalysts were tested in air pollutant treatment and thereby, the number of reports was increased in the past few years. In this context, this review describes the photocatalytic treatment of gaseous inorganic contaminants like NO x , H 2 S, and organic pollutants like formaldehyde, acetaldehyde, and benzene derivatives. Different photocatalysts with their air pollutant removal efficiency were explained. Improving strategies such as metal/non-metal doping, composite formation for photocatalyst activities have been studied. Moreover, an analysis is presented from each of the existing photocatalytic immobilization approaches. Also, factors responsible for effective photocatalysis were explained. Overall, the photocatalytic abatement technique is an auspicious way to eliminate different air contaminants. Besides, existing drawbacks and future challenges are also discussed., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

A lot of studies on spinel ferrites (MFe 2 O 4 , M = divalent metal ion) and their binary nanocomposites as photocatalysts in the decontamination of wastewater have been performed, because MFe 2 O 4 nanoparticles are relatively stable, biocompatible and low-cost efficient photocatalyst. The separation of MFe 2 O 4 photocatalyst is easy owing to its excellent magnetic behavior. With this background, the recent developments on photocatalytic performances of MFe 2 O 4 based binary nanocomposites were comprehensively reviewed. Especially, a focus on MFe 2 O 4 /metal oxides, MFe 2 O 4 /carbon based materials, MFe 2 O 4 /polymers, MFe 2 O 4 /metal nanoparticles and MFe 2 O 4 /other compounds for the photocatalytic degradation of dyes, emerging contaminants and inorganic pollutants has been thoroughly given. The advantages of MFe 2 O 4 based nanocomposites as photocatalysts were also discussed. In addition, the possible pathway of active free radical generation by these photocatalysts under visible and ultraviolet irradiation has been explained. A comparison of photocatalytic activities of MFe 2 O 4 based binary nanocomposites with recent reports has been carried out. This review concludes that MFe 2 O 4 based binary nanocomposites have potential capacity in water purification technology. Nevertheless, their practical utilization in water treatment plants still needs to be further studied., Competing Interests: Declaration of competing interest The authors declare that there is no conflict of interest., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Many microbial species causing infectious disease all over the world became a social burden and creating threat among community. These microbes possess long lifetime, enhancing mortality and morbidity rate in affected organisms. In this condition, the treatment was ineffective and more chances of spreading of infection into other organisms. Hence, it is necessary to initiate infection control efforts and prevention activities against multidrug resistant microbes, to reduce the death rate of people. Seriously concerning towards this problem progress was shown in developing significant drugs with least side effects. Emergence of nanoparticles and its novelty showed effective role in targeting and destructing microbes well. Further, many research works have shown nanocomposites developed from nanoparticles coupled with other nanoparticles, polymers, carbon material acted as an exotic substance against microbes causing severe loss. However, metal and metal oxide nanocomposites have gained interest due to its small size and enhancing the surface contact with bacteria, producing damage to it. The bactericidal mechanism of metal and metal oxide nanocomposites involve in the production of reactive oxygen species which includes superoxide radical anions, hydrogen peroxide anions and hydrogen peroxide which interact with the cell wall of bacteria causing damage to the cell membrane in turn inhibiting the further growth of cell with leakage of internal cellular components, leading to death of bacteria. This review provides the detailed view on antibacterial activity of metal and metal oxide nanocomposite which possessed novelty due to its physiochemical changes., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)