1. Competing Crystallization between Lanthanide and Actinide in Acidic Solution Leading to Their Efficient Separation.
- Author
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Yin, Xuemiao, Wang, Yaxing, Li, Xiaoyan, Xie, Jian, Silver, Mark A., Chen, Lanhua, Sheng, Daopeng, Ji, Guoxun, Chai, Zhifang, and Wang, Shuao
- Subjects
CRYSTALLIZATION ,RARE earth metals ,ACTINIDE elements ,EUROPIUM ,OXALIC acid - Abstract
Summary of main observation and conclusion: We present a new method for generating europium oxalate compounds by decomposing of N‐methyl 2‐pyrrolidone in HNO3 media. The reaction exhibits high selectivity towards Eu3+ over UO22+, which suggests that these conditions could be applied to a selective crystallization based separation system for trivalent lanthanides and hexavalent actinides. In this work, a new method for the separation of trivalent Eu3+ and hexavalent UO22+ in initial high‐acidity HNO3 solution is presented. N‐Methyl 2‐pyrrolidone was added in the HNO3 solution where Eu3+ and UO22+ coexisted, then the solution was heated. Eu3+ will react with oxalic acid and dimethylamine produced by N‐methyl 2‐pyrrolidone and form compound NH2(CH3)2[Eu(C2O4)2(H2O)], while UO22+ remains in the solution. This method provide a new strategy for separation of trivalent Eu3+ and hexavalent UO22+. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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