1. The structure and dynamics of water inside armchair carbon nanotube
- Author
-
Zhou Xiao-yan and LU Hang-Jun
- Subjects
Materials science ,Proton ,Hydrogen bond ,General Physics and Astronomy ,Nanotechnology ,Carbon nanotube ,law.invention ,Carbon nanotube quantum dot ,Condensed Matter::Materials Science ,Dipole ,Chemical physics ,law ,Molecular Transport ,Molecule ,Nanotube membrane - Abstract
In this paper we present some simulation results about the behaviour of water molecules inside a single wall carbon nanotube (SWNT). We find that the confinement of water in an SWNT can induce a wave-like pattern distribution along the channel axis, similar phenomena are also observed in biological water channels. Carbon nanotubes(CNTs) can serve as simple nonpolar water channels. Molecular transport through narrow CNTs is highly collective because of tight hydrogen bonds in the protective environment of the pore. The hydrogen bond net is important for proton and other signal transports. The average dipoles of water molecules inside CNTs (7,7), (8,8) and (9,9) are discussed in detail. Simulation results indicate that the states of dipole are affected by the diameter of SWNT. The number of hydrogen bonds, the water–water interaction and water–CNT interaction are also studied in this paper.
- Published
- 2007