1. Photoluminescence of SiV centers in CVD diamond particles with specific crystallographic planes
- Author
-
Yingshuang Mei, Xiao Li, Xiaojun Hu, Chengke Chen, Yinlan Ruan, and Meiyan Jiang
- Subjects
Growth pressure ,Materials science ,Photoluminescence ,Composite number ,General Physics and Astronomy ,Diamond ,02 engineering and technology ,Chemical vapor deposition ,Hot filament ,engineering.material ,021001 nanoscience & nanotechnology ,01 natural sciences ,Crystallography ,symbols.namesake ,hemic and lymphatic diseases ,Lattice (order) ,0103 physical sciences ,engineering ,symbols ,010306 general physics ,0210 nano-technology ,Raman spectroscopy - Abstract
We prepared the isolated micrometer-sized diamond particles without seeding on the substrate in hot filament chemical vapor deposition. The diamond particles with specific crystallographic planes and strong silicon-vacancy (SiV) photoluminescence (PL) have been prepared by adjusting the growth pressure. As the growth pressure increases from 2.5 to 3.5 kPa, the diamond particles transit from composite planes of {100} and {111} to only smooth {111} planes. The {111}-faceted diamond particles present better crystal quality and stronger normalized intensity of SiV PL with a narrower bandwidth of 5 nm. Raman depth profiles show that the SiV centers are more likely to be formed on the near-surface areas of the diamond particles, which have poorer crystal quality and greater lattice stress than the inner areas. Complex lattice stress environment in the near-surface areas broadens the bandwidth of SiV PL peak. These results provide a feasible method to prepare diamond particles with specific crystallographic planes and stronger SiV PL.
- Published
- 2019