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Hydrogen, as a clean and pollution-free energy with high calorific value, is one of the best alternatives to fossil fuels. Hydrogen evolution reaction (HER), as a half reaction of electrochemical water splitting, has also received extensive attention. At present, the development of low-cost and high-performance hydrogen evolution catalysts still faces enormous challenges. In this work, we synthesized a series of RuNi/TiO 2 -oxMWCNT catalysts with different Ru and Ni ratio. After optimizing the composition and proportion, RuNi/TiO 2 -oxMWCNT with Ru:Ni=4:6 has the optimal hydrogen evolution performance. High HER performance of extremely low 14.8 mV overpotential at 10 mA·cm−2 and 38.4 mV·dec−1 Tafel slope with perfect stability is achieved, which is superior to most reported ruthenium-based catalysts and even commercial Pt/C. XPS and UPS indicates that there is a metal synergistic effect of Ru and Ni and a strong SMSI between Ru and TiO 2 in the RuNi/TiO 2 -oxMWCNT catalyst, which helps to improve hydrogen evolution performance. This study provides a pathway for the rational design of multi-component nanostructured catalysts for HER. [Display omitted] • Bimetallic RuNi/TiO 2 -oxMWCNT catalysts were successfully fabricated by deposition-precipitation method. • The strong metal carrier interaction between Ru and TiO 2 optimizes the electronic structure of the catalyst. • The synergistic effect of bimetallic Ru-Ni tremendously improved the hydrogen evolution performance of catalysts. • The RuNi/TiO 2 -oxMWCNT shows an excellent HER performance with the low overpotential and Tafel slope. [ABSTRACT FROM AUTHOR]

Design of catalyst particles bearing excellent diffusion performance and suitable surface wettability is of great importance to the successful application of Pickering interfacial catalysis. In this study, selective oxidation reactions over hydrophobized hollow TS-1 zeolite were applied as probe reactions to investigate the influence of catalyst diffusion performance closely related to mesopore size on its catalytic activity. Hydrophobized hollow TS-1 zeolite particles were prepared via a post desilication treatment accompanied with precrystallization treatment. The synthesized hydrophobized hollow TS-1 zeolite was characterized by Scanning electron microscopy, Transmission electron microscopy, X-ray diffraction, UV–vis absorption spectrometry, Fourier-transform infrared spectroscopy and Nitrogen adsorption-desorption. Stable Pickering emulsions including 1-hexene-hydrogen peroxide, cyclohexene-hydrogen peroxide and cyclohexanone-water were prepared with hydrophobized hollow TS-1 zeolite particles as emulsifier. HTS-1–393(2)-S zeolite synthesized with precrystallization at 393 K for 2 h presented the maximum values of 43.9 mol/(Ti-mol·h) for 1-hexene epoxidation, 15.7 mol/(Ti-mol·h) for cyclohexene epoxidation and 247.3 mol/(Ti-mol·h) for cyclohexanone ammoximation. In addition, HTS-1–393(2)-S zeolite particles displayed good reusability for more than five cycles. HTS-1–393(2)-S zeolite synthesized with precrystallization at 393 K for 2 h presented the maximum TOF values for 1-hexene epoxidation, cyclohexene epoxidation and cyclohexanone ammoximation in Pickering interfacial catalysis system. [Display omitted] • Hydrophobized hollow TS-1 zeolite was prepared via a post desilication and a post silylation modification treatment. • HTS-1–393(2)-S zeolite synthesized with precrystallization at 393 K for 2 h presented the maximum TOF value. • Precrystallization handlement induces a reduction of emulsion droplet size for HTS-1–393(2)-S zeolite. • Precrystallization handlement leads to decreased tetra-coordinated titanium and increased anatase TiO 2. [ABSTRACT FROM AUTHOR]

TiO 2 is one of the more promising anode materials for sodium-ion batteries, but its poor electrical conductivity and slow Na+ diffusion kinetics limit its further development. Herein, C, N, P self-doping KTi 2 (PO 4) 3 /TiO 2 composites were successfully prepared by using lotus pollen as bio-template. And the experimental results show that the introduction of heteroatom and KTi 2 (PO 4) 3 into TiO 2 greatly contributes to improving the conductivity and Na+ mobility of TiO 2. The strategies provided in this paper can not only provide new ideas for the design and preparation of anode materials for TiO 2 -based sodium-ion batteries, but also provide new directions for the utilization of natural biomass. [Display omitted] ● The C, N, P self-doped KTi 2 (PO 4) 3 /TiO 2 with yolk shell structure will improve the conductivity and Na+ mobility of TiO 2. [ABSTRACT FROM AUTHOR]