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k-symplectic manifolds are a convenient framework to study classical field theories and they are a generalization of polarized symplectic manifolds. This paper focus on the existence and the properties of left invariant k-symplectic structures on Lie groups having a bi-invariant pseudo-Riemannian metric. We show that compact semi-simple Lie groups and a large class of Lie groups having a bi-invariant pseudo-Riemannian metric does not carry any left invariant k-symplectic structure. This class contains the oscillator Lie groups which are the only solvable non abelian Lie groups having a bi-invariant Lorentzian metric. However, we built a natural left invariant n-symplectic structure on SL (n , R) . Moreover, up to dimension 6, only three connected and simply connected Lie groups have a bi-invariant indecomposable pseudo-Riemannian metric and a left invariant k-symplectic structure, namely, the universal covering of SL (2 , R) with a 2-symplectic structure, the universal covering of the Lorentz group SO (3 , 1) with a 2-symplectic structure, and a 2-step nilpotent 6-dimensional connected and simply connected Lie group with both a 1-symplectic structure and a 2-symplectic structure. [ABSTRACT FROM AUTHOR]