Search

In response to the challenges posed by the intricate synthesis process and low conductivity of nickel-based hydroxides, a straightforward and environmentally friendly method was proposed for the preparation of B-doped α-Ni(OH) 2 (α-Ni(OH) 2 –B). Additionally, B-doped NiS 2 @NC composites with sulfur vacancies (B-Sv-NiS 2 @NC) were prepared through nitrogen-doped carbon coating and vulcanization process. The resulting B-Sv-NiS 2 @NC electrode materials exhibited a specific capacity of 659C g−1 under a high specific potential (ΔV) of 1.0 V vs. Hg/HgO. Asymmetric supercapacitors α-Ni(OH) 2 –B//YP-80 and B-Sv-NiS 2 @NC//YP-80 were constructed and obtain 128.45C g−1 and 199.5C g−1 specific capacity at 0.5 A g−1 and 0.7 A g−1, respectively. Meanwhile, the α-Ni(OH) 2 –B//YP-80 and B-Sv-NiS 2 @NC//YP-80 demonstrated energy densities of 30.33 Wh kg−1 and 47.1 Wh kg−1 under 1.7 V working voltage window, respectively. The cycle capacity retention rates of the two devices reached 96% (8000 cycles) and 116% (10,000 cycles). The surface pseudocapacitance mechanism and charge transfer mechanism of α-Ni(OH) 2 –B and B-Sv-NiS 2 @NC were revealed by first principles DFT. The findings of the study demonstrate that the introduction of B doping significantly augmented the adsorption of OH− and facilitated the surface redox reaction. The OH− adsorption energy increased to −1.43 eV upon the incorporation of B and Sv, indicating that the adsorption of OH− on the B-Sv-NiS 2 @NC surface was more stable, thereby promoting a swift electrochemical reaction. The improved electronic structure of the material, coupled with the increased number of electrochemical active sites, resulted in enhanced OH− adsorption, accelerated redox reaction, and improved charge transfer, ultimately leading to improved electrochemical performance. In situ boron-doped flower-like NiS 2 @NC with sulfur vacancy composites were prepared through a straightforward, and environmentally-friendly method. The composites exhibit abundant active sites, enhancing storage of charge, obtained excellent electrochemical performance in 3 M KOH electrolyte. Asymmetrical devices maintain high capacity under 1.7V wide voltage window, enhancing energy density. [Display omitted] • Simple, environmentally-friendly method to synthesize stable α-Ni(OH) 2 –B. • In situ B-doped NiS 2 @NC with sulfur vacancy (Sv) composites were prepared. • No β-Ni(OH) 2 phase was formed during the electrochemical reaction. • Asymmetric device exhibits 47.2 Wh kg−1 high energy density. • B-Sv-NiS 2 @NC electrode materials obtained 659C g−1under high specific potential (ΔV) 1.0 V. [ABSTRACT FROM AUTHOR]