1. A controllable foaming approach for the fabrication of "rattan-like" graphene-based composite aerogel with desirable microwave absorption capacity.
- Author
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Zhang, Xiaoxiao, Zheng, Qitan, Chen, Yujie, Fan, Qunfu, Li, Hua, Liu, Hezhou, Chen, Zhixin, Li, Yao, Pan, Hui, Jiang, Xueliang, and Zhu, Shenmin
- Subjects
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AEROGELS , *ABSORPTION of sound , *MICROWAVES , *POLLUTANTS , *IMPEDANCE matching , *CARBON foams , *SURFACE active agents , *ELECTROMAGNETIC wave absorption , *ELECTRIC capacity - Abstract
As a common environmental pollutant, microwave can cause great harms to human health. The development of high-performance microwave absorber with lightweight is indeed necessary. Herein, "rattan-like" graphene-based composite aerogels, having macroscopic pores surrounded by plenty of small pores, were designed and fabricated via an in-situ foaming then carbonized approach. Firstly, graphene oxide (GO), nanocellulose and ferrous ions were integrated into an aerogel with uniform large pores via a freeze-casting method. Then, the aerogel was immersed into a H 2 O 2 solution, during which bubble clusters generated in situ. These bubbles were driven into the stacked GO sheets and formed small pores. With the increase of the H 2 O 2 concentration from 0.5 to 10 wt%, the count percentage of the small pores in the aerogel increased from 81.5 to 95.2%. After the final carbonization, the graphene sheets were dually interconnected with magnetic nanoparticles and carbonized nanocellulose. The unique porous structure and dual-connected networks endowed the aerogel with enhanced conductive loss and optimized impedance matching capacity, and thus an excellent microwave absorption performance, whose maximum reflection loss achieves −68.5 dB. Further, the aerogel also exhibited superior sound absorption performance (noise reduction coefficient up to 0.91 in 1000–6300 Hz), and good mechanical stability. [Display omitted] • An in-situ foaming then carbonized process was developed to controllably fabricate "rattan-like" RGO-based aerogel. • By increasing C H2O2 from 0.5 to 10 wt%, the count percentage of small pores in aerogel increased from 81.5 to 95.2%. • "Rattan-like" structure and dual-connected networks endowed the aerogel with excellent microwave absorption capacity. • The aerogel also exhibited superior sound absorption capacity and good mechanical stability. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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