1. Rheology, crystal structure, and nanomechanical properties in large-scale additive manufacturing of polyphenylene sulfide/carbon fiber composites
- Author
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Ngoc A. Nguyen, Ralph B. Dinwiddie, Rama K. Vasudevan, Vlastimil Kunc, Jong K. Keum, John Lindahl, Peng Liu, and Stephen Jesse
- Subjects
chemistry.chemical_classification ,Materials science ,Sulfide ,General Engineering ,Nucleation ,Crystal growth ,02 engineering and technology ,Polymer ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Microstructure ,01 natural sciences ,0104 chemical sciences ,chemistry ,Rheology ,Ceramics and Composites ,Extrusion ,Composite material ,0210 nano-technology ,Material properties - Abstract
Extrusion based high-throughput Additive Manufacturing (AM) provides a rapid and versatile approach for producing complex structures by using a variety of polymer materials. An underexplored aspect of this technique is concerned with the formation of interfaces between successively deposited layers. This is particularly important for large-scale additive manufacturing of semi-crystalline polymers because of the highly non-isothermal conditions involved, which influence both nucleation and crystal growth. The objective of this work is to investigate the microstructure and the corresponding viscoelastic properties of carbon fiber (CF) reinforced polyphenylene sulfide (PPS) resulting from extrusion-based high-throughput AM process. Questions on development of morphology focus on polymer crystal structure and carbon fiber orientation in the vicinity of the interface between successive layers. This study attempts to establish a fundamental understanding of the role of the AM has in transferring a set of intrinsic material properties to the macroscopic properties of the final AM structure.
- Published
- 2018
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