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After the occurrence of major sudden disasters, the dispatching and distribution of disaster relief materials are particularly important, but in the process of distribution, there may be excessive distribution of similar emergency materials, unbalanced distribution volume of relief materials in different disaster-affected points, high distribution cost, and low effective distribution rate. In order to solve the above problems, based on the application of big data, this paper proposes a three-level network postdisaster material scheduling and distribution model and an improved NSGA-II algorithm. The model takes the loss degree of the disaster area and the dynamic change rate of the demand for postdisaster relief materials as the constraints, takes the demand prediction of postdisaster relief materials, the optimization of distribution path, distribution nodes, and the satisfaction of victims as the objectives, and designs the sample average approximation method and the improved NSGA-II algorithm. In order to verify the effectiveness of the proposed model and strategy, through the comparative experiment of NSGA and PSO, it can be seen from the experimental results that the three-level network allocation model and the improved NSGA-II algorithm (nondominated sorting genetic algorithm II) proposed in this paper can not only solve the existing postdisaster relief material allocation and scheduling problem but also reduce the space-time complexity of the problem. [ABSTRACT FROM AUTHOR]