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Asphalt crack repair materials, known as crack sealants, are directly exposed to ultraviolet (UV) radiation in asphalt pavements. This exposure causes the gradual aging and deterioration of both their surface and internal properties. To study this phenomenon, the sealant was subjected to UV irradiation for a range of 0–385 hours, with the basic properties of the aged sealant tested every 55 hours. Several techniques were employed to investigate the changes in the internal chemical composition of the sealant, including Fluorescence microscopy (FM), gel permeation chromatography (GPC) and Fourier transform infrared spectroscopy (FT-IR). The results revealed that the UV aging of the sealant mainly occurs in the thinner surface layer, which becomes progressively lighter in color. Notably, obvious surface cracks form after aging process. The cone penetration and softening point of the sealant exhibit an exponential or logarithmic change corresponding to the aging time. The most pronounced changes occur during the early stages of UV aging, with the properties tending to stabilize after approximately 220 h of aging. In addition, the FM images showed that the dispersed polymer particles within the sealant gradually transform into a continuous network structure after aging over time. The GPC spectrum of the aged sealant shifts to the left, indicating an increase in molecular weight, particularly in the polymer modifier. This is consistent with the transformation observed in the FT-IR analysis, which demonstrates that UV irradiation leads to the breaking and recombination of polymer chemical bonds in the sealant. The FT-IR analysis reveals the conversion of monosubstituted benzene to polysubstituted benzene in the polymer modifier, which also correlates with the formation of the network structure observed in the FM images and the increase in molecular weight detected in the GPC spectrum of the polymer modifier. • UV aging of the sealant only exists in its surface, and obvious surface cracks appeare after aging. • Cone penetration and softening point changes exponentially or logarithmically with UV aging time. • Polymer particles dispersed in sealant gradually change into continuous network structure after aging. • The styrene of monosubstituted benzene in polymer gradually changes into poly-substituted benzene. [ABSTRACT FROM AUTHOR]

The porous hydrophilic nature of cement-based material is susceptible to water and corrosive media, severely reducing the durability. In this paper, methyl siloxane-based hydrophobic powder was prepared, and its effect on the physicochemical and anti-corrosion properties of mortar with different water-cement ratios were investigated. The results show that the addition of hydrophobic powder significantly improved the hydrophobic properties of mortars. Especially for the mortars with w/c ratios of 0.2 and 0.4, it showed superhydrophobicity with a water contact angle up to 156.5 ° and 152.3 ° respectively. Lower w/c ratio mortar has a denser microstructure, which reduces the water absorption rate of the mortar, and the hydrophobic powder enhances the hydrophobic effect of low w/c ratio mortar more significantly. The methyl siloxane groups in the hydrophobic powders will bind to the C-S-H gel in the mortar through Si-O bonding, preventing the C-S-H gel connections from forming a continuous network structure. This increased the pore volume and reduced the compressive strength by 14.6%-22.7%, but the total hydration degree was increased, and significant corrosion protection of the steel rebar was demonstrated. [Display omitted] • Super hydrophobicity of mortar was achieved by modification of hydrophobic powder. • Hydrophobic mortar with lower w/c ratio exhibits better anti-corrosion performance. • Methylsiloxane groups combine with C-S-H gel by Si-O enhancing hydrophobic properties of mortar. [ABSTRACT FROM AUTHOR]