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1. An unprecedented bridging [Ag2(NO3)6]4−anion as a component of an infinite silver(<scp>i</scp>) molecular ladder incorporating a dinuclear cationic silver complex of a bis-dipyridylamine ligand

Author

Karsten Gloe, Jack K. Clegg, Bianca Antonioli, Holger Heßke, Kerstin Gloe, Leonard F. Lindoy, and David Barton Bray

Subjects
Chemistry, Stereochemistry, Polymer chemistry, Cationic polymerization, General Materials Science, General Chemistry, Crystal structure, Condensed Matter Physics, Ion
Abstract

The interaction of silver(I) nitrate with the polypyridyl ligand (L) formed from two dipyridylamine units joined at their secondary amines by a 2,6-lutidinyl bridge results in a molecular ladder motif that consists of pairs of cationic [Ag2(L)MeCN]2+ units bridged by an unprecedented [Ag2(NO3)6]4− anion.

Published
2006
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