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1. Trinuclear Ni(<scp>ii</scp>) oriented highly dense packing and π-conjugation degree of metal–organic frameworks for efficient water oxidation

Author

Xiao-Min Lu, Lu-Fang Ma, Zhi-Min Zhai, Zhao-Tong Yang, and Xiao-Gang Yang

Subjects
Materials science, Degree (graph theory), Charge carrier mobility, Oxygen evolution, chemistry.chemical_element, 02 engineering and technology, General Chemistry, 010402 general chemistry, 021001 nanoscience & nanotechnology, Condensed Matter Physics, 01 natural sciences, 0104 chemical sciences, Crystal, Nickel, Crystallography, chemistry, Π conjugation, General Materials Science, Metal-organic framework, 0210 nano-technology, Dense packing
Abstract

Oriented by the structure-directing effect of metal clusters, a novel trinuclear nickel-based MOF (Ni–BTC) exhibited highly denser crystal packing and π-conjugation degree, providing a platform for efficient charge carrier mobility between metal clusters through π-conjugated molecular bridges and long-term stability of an efficient oxygen evolution reaction.

Published
2019
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