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Your search keyword '"Khan, Arif Ali"' showing total 1 results
Start Over Author "Khan, Arif Ali" Publication Year Range Last 3 years Journal dalton transactions: an international journal of inorganic chemistry
1 results on '"Khan, Arif Ali"'

1. Dehydrogenation reaction of triethylamine by an electrophilic terminal phosphinidene complex.

Author

Khan, Arif Ali, Kalisch, Tim, Espinosa Ferao, Arturo, and Streubel, Rainer

Subjects
*MASS spectrometry, *TRIETHYLAMINE, *DEHYDROGENATION, *ETHYLAMINES, *NUCLEAR magnetic resonance spectroscopy
Abstract

Reaction of a transiently formed terminal phosphinidene complex with triethylamine resulted in the formation of an sp3 C–H insertion product, as revealed by 31P NMR spectroscopy, which was isolated as semi-solid compound. However, if the reaction was continued for 24 h, a primary phosphane complex was obtained eventually. The compounds were characterised by NMR spectroscopy and mass spectrometry. Formation of the final products is explained by a mechanistic proposal based on DFT calculations. [ABSTRACT FROM AUTHOR]

Published
2023
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