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Start Over Author "Duclairoir, Florence" Topic functional groups Journal dalton transactions: an international journal of inorganic chemistry
1 results on '"Duclairoir, Florence"'

1. Porphyrin anchoring on Si(100) using a β-pyrrolic position.

Author

Hui Liu, Duclairoir, Florence, Fleury, Benoit, Dubois, Lionel, Chenavier, Yves, and Marchon, Jean-Claude

Subjects
*PORPHYRINS, *SILICON, *PYRROLES, *FUNCTIONAL groups, *HYDROSILYLATION, *RING formation (Chemistry), *SURFACES (Technology)
Abstract

Nickel(II) β-azido-meso-tetraphenylporphyrin was successfully anchored on silicon using a bifunctional linker that bears two terminal alkyne functions by the sequence (i) hydrosilylation of a C=C triple bond of the linker by surface Si-H groups and (ii) 1,3-Huisgen cycloaddition between the alkyne-terminated silicon surface and the azidoporphyrin derivative. [ABSTRACT FROM AUTHOR]

Published
2009
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