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Start Over Author "Cordero, Miguel" Journal dalton transactions: an international journal of inorganic chemistry

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1. Development and application of redox-active cyclometallating ligands based on W(II) alkyne complexes.

Author

Hüttenschmidt, Mareike, Lange, Helge, Cordero, Miguel Andre Argüello, Villinger, Alexander, Lochbrunner, Stefan, and Seidel, Wolfram W.

Subjects
*LIGANDS (Chemistry), *MOIETIES (Chemistry), *ALKYNES, *COOPERATION
Abstract

The assembly of dinuclear complexes with the ultimate smallest ditopic ligands based on side-on complexes of methyl substituted alkynes is presented. In fact, the coordination of Ru(II) and Ir(III) by a W alkyne complex based cyclometallating metalla-ligand causes close intermetallic electronic cooperation, which substantially changes the electrochemical and photophysical properties of the single isolated moieties. [ABSTRACT FROM AUTHOR]

Published
2022
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