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Your search keyword '"Duclairoir, Florence"' showing total 2 results
Start Over Author "Duclairoir, Florence" Journal dalton transactions: an international journal of inorganic chemistry
2 results on '"Duclairoir, Florence"'

1. Porphyrin anchoring on Si(100) using a β-pyrrolic position.

Author

Hui Liu, Duclairoir, Florence, Fleury, Benoit, Dubois, Lionel, Chenavier, Yves, and Marchon, Jean-Claude

Subjects
*PORPHYRINS, *SILICON, *PYRROLES, *FUNCTIONAL groups, *HYDROSILYLATION, *RING formation (Chemistry), *SURFACES (Technology)
Abstract

Nickel(II) β-azido-meso-tetraphenylporphyrin was successfully anchored on silicon using a bifunctional linker that bears two terminal alkyne functions by the sequence (i) hydrosilylation of a C=C triple bond of the linker by surface Si-H groups and (ii) 1,3-Huisgen cycloaddition between the alkyne-terminated silicon surface and the azidoporphyrin derivative. [ABSTRACT FROM AUTHOR]

Published
2009
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2. Porphyrin anchoring on Si(100) using a β-pyrrolic positionElectronic supplementary information (ESI) available: NMR and IR of compound 5; MIR of surface 2and 3; global XPS of surface 2and 3; CV data. See DOI: 10.1039/b901309a.

Author

Liu, Hui, Duclairoir, Florence, Fleury, Benoit, Dubois, Lionel, Chenavier, Yves, and Jean-Marchon, Claude

Subjects
*PORPHYRINS, *SILICON, *NUCLEAR magnetic resonance, *ORGANONICKEL compounds, *X-ray photoelectron spectroscopy, *ALKYNES, *HYDROSILYLATION, *CHEMICAL bonds
Abstract

Nickel(ii) β-azido-meso-tetraphenylporphyrin was successfully anchored on silicon using a bifunctional linker that bears two terminal alkyne functions by the sequence (i) hydrosilylation of a CC triple bond of the linker by surface Si–H groups and (ii) 1,3-Huisgen cycloaddition between the alkyne-terminated silicon surface and the azidoporphyrin derivative. [ABSTRACT FROM AUTHOR]

Published
2009
Full Text
View/download PDF

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