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Start Over Author "Nguyen, Joseph Q" Journal dalton transactions: an international journal of inorganic chemistry
1 results on '"Nguyen, Joseph Q"'

1. Cooperative dinitrogen capture by a diboraanthracene/samarocene pair.

Author

Xu, Song, Essex, Laura A., Nguyen, Joseph Q., Farias, Phillip, Ziller, Joseph W., Harman, W. Hill, and Evans, William J.

Subjects
LEWIS acids, COOPERATIVE societies, MOIETIES (Chemistry), TOLUENE, BORON
Abstract

The combination of a boron Lewis acid and a decamethylsamarocene, specifically 9,10-Me2-9,10-diboraanthracene with (C5Me5)2SmII(THF)2, in toluene leads to cooperative reductive capture of N2. The product crystallizes as the salt, [(C5Me5)2SmIII(THF)2][(C5Me5)2SmIII(η2-N2B2C14H14)], 1, which formally is comprised of an (N＝N)2− moiety sandwiched between a [(C5Me5)2SmIII]1+ metallocene cation and the diboraanthracene ditopic Lewis acid. [ABSTRACT FROM AUTHOR]

Published
2021
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