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Start Over Author "Ren, Shishuai" Journal dalton transactions: an international journal of inorganic chemistry
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1. Synthesis of silyl iron hydride via Si–H activation and its dual catalytic application in the hydrosilylation of carbonyl compounds and dehydration of benzamides.

Author

Ren, Shishuai, Xie, Shangqing, Xu, Shilu, Xue, Benjing, Li, Xiaoyan, Sun, Hongjian, Zheng, Tingting, Wang, Yangyang, Fuhr, Olaf, and Fenske, Dieter

Subjects
*IRON hydrides, *LIGANDS (Chemistry), *HYDROSILYLATION
Abstract

The hydrido silyl iron complex (o-Ph2PC6H4SiMe2)Fe(PMe3)3H (2) was obtained via the activation of the Si–H bond of the bidentate silyl ligand o-Ph2P(C6H4)SiMe2H (1) by Fe(PMe3)4. 2 showed good to excellent catalytic activity in both the reduction of aldehydes/ketones and the dehydration of benzamide. In addition, with complex 2 as a catalyst, α,β-unsaturated carbonyls could be selectively reduced to the corresponding α,β-unsaturated alcohols. The mechanisms of the formation of 2 and the catalytic dehydration process are proposed and partly experimentally verified. [ABSTRACT FROM AUTHOR]

Published
2018
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