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Start Over Author "Daniel T. Yonemoto" Journal dalton transactions
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1. Accessing the triplet manifold of naphthalene benzimidazole–phenanthroline in rhenium(<scp>i</scp>) bichromophores

Author

James E. Yarnell, Rosalynd Joyce, Daniel T. Yonemoto, Jonathan R. Palmer, Felix N. Castellano, Sara Sheykhi, Sofia Garakyaraghi, and Kaylee A. Wells

Subjects
Inorganic Chemistry, chemistry.chemical_compound, Photoluminescence, chemistry, Ligand, Excited state, Phenanthroline, Ultrafast laser spectroscopy, chemistry.chemical_element, Molecule, Rhenium, Spectroscopy, Photochemistry
Abstract

The steady-state and ultrafast to supra-nanosecond excited state dynamics of fac-[Re(NBI-phen)(CO)3(L)](PF6) (NBI-phen = 16H-benzo[4′,5′]isoquinolino[2′,1′:1,2]imidazo[4,5-f][1,10]phenanthrolin-16-one) as well as their respective models of the general molecular formula [Re(phen)(CO)3(L)](PF6) (L = PPh3 and CH3CN) has been investigated using transient absorption and time-gated photoluminescence spectroscopy. The NBI-phen containing molecules exhibited enhanced visible light absorption with respect to their models and a rapid formation (

Published
2021
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