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The TFC RO/NF membranes are the predominant membranes applied in desalination, and heat curing is an essential step in its industrial production, which increases the polyamide cross-linking degree and facilitate packing but leads permeability decrease. Nevertheless, the mechanism of heat curing on TFC membranes permeation resistance changes is still ambiguous. Figuring it out will aid in crafting a more effective optimization strategy in high flux membrane preparation. Herein, we prepared a range of TFC RO/NF membranes with various monomer concentrations on different substrates and quantified the permeation resistance changes by a resistance-in-series model. For nascent TFC RO/NF membranes, the PA layer provided almost all permeation resistance. After heat curing, the substrate exhibited a marked increase in permeation resistance. The change in the permeation resistance composition was further exacerbated by the decrease in monomer concentration. For TFC NF membranes with heat curing, the proportion of substrate permeation resistance increased significantly, rising from 31.62 % to 75.05 %. This study made a comprehensive analysis of the impact of the permeation resistance in TFC RO/NF membranes caused by heat curing, enriched the insight into the impact of heat curing on TFC membranes, and helped to prepare TFC membranes with better desalination performance. [Display omitted] • The resistance proportions of RO/NF membranes are quantitatively revealed. • The substrate resistance increases significantly due to heat curing. • Low monomer concentration results in high substrate resistance. [ABSTRACT FROM AUTHOR]

Given the critical requirements of environmental preservation and resource reutilization, the recovery of lithium from spent lithium-ion (LIBs) batteries holds immense significance. This study investigates the viability of nanofiltration (NF) membranes for selectively separating lithium from spent LIBs leaching solution. A membrane-based approach uniquely sidesteps the significant metal losses often encountered in traditional methods that necessitate initial pH adjustments. The NF270 and DK membranes were characterized and evaluated. DK demonstrated superior rejection capabilities for high-valence metal ions with over 99.0 % rejection, while allowing a notable 40.1 % lithium passage rate. Furthermore, DK showcased enhanced acid resistance compared to NF270. The findings underscore the characteristics essential for NF membranes in this application, and the study affirms the feasibility of membrane-based lithium recovery, marking a stride in battery recycling research. [Display omitted] • Proposed a novel membrane-based process for spent lithium battery recycling • The battery-grade lithium carbonate can be obtained through two-stage nanofiltration. • DK membrane exhibits excellent acid resistance and high-valence metal ion rejection to the leaching solution. [ABSTRACT FROM AUTHOR]

Although covalent organic frameworks (COFs) membranes have promising applications in water treatment due to their ordered structure and adjustable pore size, most of them are imine-linked ones, which severely limits their application in harsh environments. Herein, we offer a stable novel COFs membrane which is composed of hydrazone bonds and β-ketoenamine structures. Such β-ketoenamine based COFs composite membrane was fabricated via interfacial catalytic polymerization on a nylon substrate, which was generated at the water (P-Toluenesulfonic acid)/n-hexane (2,5-dimethoxyterephthalhydrazide, 1,3,5-triformylphoroglucinol) interface. The resultant COFs membrane demonstrates excellent chemical stability in strong acidic (2 mol/L)/alkaline (9 mol/L)/organic solvents (dioxane, acetone, methanol, and ethanol) media. The optimized COFs membrane achieved 109.73 L m−2 h−1 bar−1 permeance in Congo Red aqueous solution and 99.56 % CR rejection. This study exploits a novel approach to produce robust COFs membranes under extreme conditions. [Display omitted] • TpDMTH COFs membranes were fabricated via interfacial catalytic polymerization. • The combination of hydrazone bonds and β-ketoenamine structures makes membranes show stable chemical structure. • Such COFs membranes maintained excellent separation performance in 9 M NaOH solution. • Such COFs membranes showed excellent dye/salt separation performance. [ABSTRACT FROM AUTHOR]

Currently, most nanofiltration membranes exhibit satisfactory separation performance on the anions or cations, and few membranes could concurrently separate anion and cation. Therefore, preparing nanofiltration membranes with excellent separation performance for both anionic and cationic ions remains a challenge. Herein, we have developed a series of nanofiltration membranes using conventional interfacial polymerization with different ratios of trimesoyl chloride (TMC) and piperazine (PIP) concentrations. In the interface polymerization process, the amine groups carried by PIP imparted a positive charge, while the hydrolysis of acyl chloride groups resulted in the generation of carboxylic acid groups that introduced a negative charge. The mix-charged nanofiltration membrane could be fabricated by varying PIP/TMC concentration ratios. The optimized membrane exhibited high rejection rates for bivalent ions (Na 2 SO 4 rejection of 96.6 %, MgCl 2 rejection of 93.0 %), and its selectivity for Mg2+/Li+ mixed solution was improved significantly. This work provides a novel approach for the development of nanofiltration membranes capable of effectively separating mono-/divalent ions. [Display omitted] • Fabrication of mixed-charged polyamide membranes via regulating the PIP/TMC ratio directly. • High PIP/TMC ratio leads more unreacted amine groups in the polyamide which was beneficial to MgCl 2 rejection. • Such NF membrane showed excellent separation efficiency to Mg2+/Li+ and SO 4 2−/Cl−. [ABSTRACT FROM AUTHOR]

Thin film composite (TFC) hollow fiber nanofiltration (NF) membranes were fabricated via interfacial polymerization, with mixed diamines of piperazine (PIP) and 2,2′-bis(1-hydroxyl-1-trifluoromethyl-2,2,2-triflutoethyl)-4,4′-methylenedianiline (BHTTM) as water phase and trimesoyl chloride (TMC) as organic phase. Fabricated membranes were characterized for ATR-FTIR, SEM, AFM, and water contact angle. Formation conditions of the selective polyamide layer have been optimized for a good NF membrane performance. The pure water flux of NF membrane prepared under optimized conditions was 31.2 L·m − 2 ·h − 1 and the rejection for Na 2 SO 4 was 99.7% at 6 bar. The rejections of NF membranes for different salts followed the order: Na 2 SO 4 > MgSO 4 > NaCl > MgCl 2 . The molecular weight cut-off of NF membrane was around 300 Da. The performance of NF membranes was stable during a 7-day filtration process for rejecting different species ions including heavy metal ferric ion (FeCl 3 and Fe 2 (SO 4 ) 3 ) and oxyanions (SO 4 2 − and HPO 4 2 − ), in addition to different inorganic salts. Also, the NF membranes exhibited chlorine tolerant property. This work demonstrates the potential of PES outer-selective TFC hollow fiber membranes for desalination or water softening process, provides database to fabricate suitable NF membranes for long-term salts removal and raise a simple technique to form a thin chlorine-tolerant polyamide layer. [ABSTRACT FROM AUTHOR]