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A quantitative assessment of pharmaceuticals in surface water in Jordan was conducted using liquid chromatography-tandem mass spectrometry (LC-MS/MS) to evaluate the occurrence, source and distribution of 18 pharmaceutical compounds. Grab samples were collected in the summer from the effluent of two dams in Jordan. Among all of the pharmaceuticals analyzed, the results showed that 10 pharmaceutical compounds were detected in the effluent of King Talal Dam including 1,7-dimethylxanthine, acetaminophen, amphetamine, caffeine, carbamazepine, cotinine, phenazone, sulfamethoxazole, sulfamethazine, trimethoprim. However, four pharmaceutical compounds detected in the effluent of Mujib Dam include 1,7-dimethylxanthine, caffeine, cotinine, phenazone. Moreover, eight pharmaceutical compounds were not detected in both dams (<0.005 μg/L) including cimetidine, diphenhydramine, MDA, MDMA, methamphetamine, morphine, sulfachloropyridazine and thiabendazole. The results also indicated that the compound detected at the highest concentration levels in King Talal Dam was carbamazepine at concentration of 0.358 μg/L. It is very clear that the occurrence of pharmaceuticals at King Talal Dam is higher than in Mujib Dam. This is mainly due to the fact that King Talal Dam is receiving runoff water and treated wastewater from the wastewater treatment plant (WWTP), while the Mujib Dam is only receiving surface runoff water. This is consistent with many studies reported in the literature that municipal WWTPs are considered a primary source for the discharge of pharmaceuticals and personal care products into surface waters. [ABSTRACT FROM AUTHOR]

Jordanian phosphate mine wastes (PMW) at Ruseifa City was fully characterized and tested for its PO4removal capacity by batch experiments using prepared phosphate solutions and domestic wastewater. PMW particles are positively charged with median particle size of 0.625 μm. Mineralogical and chemical analyses of PMW showed that it is mainly composed of calcite, fluorapatite, and quartz with high concentrations of calcium and phosphorous. The phosphate concentrations in PMW range from 11 to 24% expressed as P2O5. PMW as a sorbent has a very high PO4removal efficiency from wastewater and prepared solutions. PO4solutions with concentrations ranging from 5 to 5,000 mg L−1were prepared and utilized in batch experiments in the presence of PMW as a sorbent. The concentration of PO4in the solution phase and pH were the main parameters influencing the PMW sorption capacity of PO4. The PO4removal efficiency from prepared solutions was up to 99%. Moreover, Langmuir sorption model was able to describe the observed data for PO4sorption by PMW. The sorption data at PO4concentrations >50 mg L−1were highly fitted to Langmuir model. The estimated sorption maximum capacity (bmax) of PMW was 46,620 mg kg−1. On the other hand, domestic wastewater samples obtained from six Jordanian wastewater treatment plants were subjected to PO4removal by PMW, and the results showed that the PO4removal efficiency exceeded 97%. The adverse environmental impacts and human health risks associated with PMW presence are briefly discussed. [ABSTRACT FROM PUBLISHER]