1. The electrochemical behavior of TiO2-NTAs electrode in H+ and Al3+ coexistent aqueous solution.
- Author
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Sang, Shangbin, Liu, Yingying, Zhong, Wenjie, Liu, Kaiyu, Liu, Hongtao, and Wu, Qiumei
- Subjects
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ELECTROCHEMISTRY , *TITANIUM dioxide , *ELECTRODES , *HYDROGEN ions , *AQUEOUS solutions , *SURFACES (Technology) , *HYDROXYLATION , *INTERCALATION reactions - Abstract
The concept of aqueous solution Al-ion battery inspires much enthusiasm in developing a novel chemical power source. In this work, the electrochemical behavior of TiO 2 -NTAs electrode in Al 3+ aqueous solution with different acidity is evaluated. Electrochemical studies showed that both of H + and Al 3+ in aqueous solution are electrochemical active to TiO 2 -NTAs, however, H + is preferential to hydroxylate on the TiO 2 -NTAs surface rather than to intercalate in the TiO 2 -NTAs lattice as compared with Al 3+ under the assistance of Cl − . The surface hydroxylation of TiO 2 -NTAs can retard Al 3+ diffusion in the TiO 2 -NTAs lattice as evidenced by the increase of faradic resistance R F (by EIS) at initial cathodic polarization process, however, the subsequent decrease of R F is due to the conductance improvement of TiO 2 -NTAs with the Al 3+ intercalation. Here it can be concluded that for Al 3+ aqueous solution battery with TiO 2 -NTAs as electrode, the suitable acidity (pH≈3) is required to minimizing the effect of H + . [ABSTRACT FROM AUTHOR]
- Published
- 2016
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