1. Poly-dopamine carbon-coated stable silicon/graphene/CNT composite as anode for lithium ion batteries.
- Author
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Wang, Fangfang, Lin, Song, Lu, Xuesong, Hong, Ruoyu, and Liu, Huiyong
- Subjects
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LITHIUM-ion batteries , *POLYELECTROLYTES , *GRAPHENE , *ANODES , *SILICON , *CARBON nanotubes , *DOPAMINE - Abstract
To buffer the volume expansion of silicon during charge-discharge process, a 3D carbon-coated stable silicon/graphene/CNT (C@Si/GN/CNT/PDA-C) composite was prepared. Si nanoparticles (SiNPs) were first modified by hexadecyl trimethyl ammonium bromide (CTAB) to enhance their stability and dispersibility in water, then uniformly distributed in graphene/carbon nanotubes (GN/CNT) by electrostatic self-assembly, and ultimately encapsulated by carbonized poly-dopamine carbon layer (PDA-C) at high-temperature. PDA-C not only alleviates the volume expansion of Si and inhibits the direct contact of Si with electrolyte, but also acts as a bridge between the conductive GN/CNT and Si to maintain electrode integrity. As an anode material for lithium-ion batteries, the C@Si/GN/CNT/PDA-C exhibits a superior reversible capacity of 1946 mAh g − 1 after 100 cycles with the capacity retention of 68.9% at a current density of 0.1 A g − 1, and over 1306 mAh g − 1 after 100 cycles at 1 A g − 1. The excellent electrochemical performance of C@Si/GN/CNT/PDA-C is attributed to the stable hierarchical structure. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2022
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