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Valorization of industrial low-value side-streams are of great interest, contributing to boosts in the circular economy. In this context, lignin side-streams of the pulp and paper industry were oxypropylated to produce biobased polyols and tested in the synthesis of rigid polyurethane (RPU) foams. E. globulus lignins, namely a lignin isolated from an industrial Kraft black liquor and depolymerized lignins obtained as by-products of an oxidation process, were used. RPU foams, synthesized with 100% lignin-based polyols and using a 1.1 NCO/OH ratio, were characterized concerning apparent density, morphology, thermal conductivity, thermal stability, and heat release rate (HRR). Foams containing the lignin-based polyols presented densities varying from 44.7 to 112.2 kg/m3 and thermal conductivity in the range of 37.2–49.0 mW/mK. For the reference foam (sample produced with 100% wt. Daltofoam TP 32015 polyol), values of 70.9 kg/m3 and 41.1 mW/mK were obtained, respectively. The achieved results point out the viability of using the generated lignin-based polyols at 100% content in RPU foams, mainly when depolymerized lignins are used. Moreover, fire retardancy was favored when the lignin-based polyols were introduced. The proposed strategies can contribute to establishing the integrated pulp and paper biorefinery concept where material synthesis (polyols and RPU foams) can be combined with chemical production (vanillin and syringaldehyde). Foundation for Science and Technology (FCT, Portugal) and FEDER under Program PT2020 for financial support to CIMO (UIDB/00690/2020), and to UIDB/50020/2020 of the Associate Laboratory LSRE-LCM—funded by national funds through FCT/MCTES (PIDDAC); national funding by FCT, PI, through the institutional scientific employment program contract for Isabel P. Fernandes. This work was carried out under the Project No. 33969 Bioblocks—Design of biobased products from renewable lignocellulosic sources as precursors for the bioindustry of chemical synthesis and biomaterials—financed by FEDER through the Operational Program for Competitiveness Factors (POFC) and QREN. To COST Action LignoCOST (CA17128) supported by COST (European Cooperation in Science and Technology). info:eu-repo/semantics/publishedVersion

The aging of power transformers causes several defects and damages in the insulating system, especially in the insulating paper. The degradation of the insulating paper generates dissolved gases in the insulating oil, which are measured by gas chromatography and used as an indicator of the insulation status. The state of the insulating paper can be identified based on the degree of polymerization (DP) measurement. In some cases, when the measurement of DP is difficult, estimating DP can be accomplished through gathering information about some of the testing parameters, such as the dissolved gases (DGA), breakdown voltage (BDV), oil interfacial tension (IF), oil acidity (ACI), moisture content (MC), oil color (OC), dielectric loss (Tan δ), and furans concentration specifically (2-furfuraldhyde (FA)). The statistical tools (correlation and multiple linear regression), based on 131 transformer samples, can be used to build a relation linking DP and one or more of the previous parameters to identify the insulating paper status and the percentage of remaining life of the transformer. The results indicated that it is difficult to build a mathematical model to relate between the DP and the testing variables, except with FA, where the trend of DP with FA is more obvious than with other variables. The empirical formula to compute DP based on the FA concentration was developed and gave promising results to compute DP and the remaining life of the power transformers.

The article presents the results of comparative investigations of partial discharges in two insulation systems, aramid-enhanced cellulose paper-mineral oil, and pure cellulose paper-mineral oil. Partial discharges were investigated in a diagonal electric field with vertical and horizontal components. This field is treated as the most dangerous for insulation. The research was carried out on Nomex&reg, 910 paper and cellulose paper samples, each paper being 0.25 mm thick. Samples of the two materials were tested at four levels of moisture. The inception voltage of partial discharges of all samples tested decreased as their moisture content increases. It was also proved that Nomex&reg, 910 has a significantly higher partial discharge inception voltage than the cellulose paper, although this difference decreased with increasing moisture content.

This paper presents the effect of the impact of moisture in paper insulation used as insulation of transformer windings on its thermal conductivity. Various types of paper (cellulose and aramid) and impregnated (mineral oil, synthetic ester, and natural ester) were tested. The impact of paper and impregnated types on the changes in thermal conductivity of paper insulation caused by an increase in moisture were analyzed. A linear equation, describing the changes in thermal conductivity due to moisture, for various types of paper and impregnated, was developed. The results of measuring the thermal conductivity of paper insulation depending on the temperature are presented. The aim of the study is to develop an experimental database to better understand the heat transport inside transformers to assess aging and optimize their performance.

As a part of our research in the field of thermochemical energy storage, this study aims to investigate the potential of three fly ash samples derived from the fluidized bed reactors of three different pulp and paper plants in Austria for their use as thermochemical energy (TCES) and CO2 storage materials. The selected samples were analyzed by different physical and chemical analytical techniques such as X-ray fluorescence spectroscopy (XRF), X-ray diffraction (XRD), particle size distribution (PSD), scanning electron microscopy (SEM), inductively coupled plasma atomic emission spectroscopy (ICP-OES), and simultaneous thermal analysis (STA) under different atmospheres (N2, CO2, and H2O/CO2). To evaluate the environmental impact, leaching tests were also performed. The amount of CaO as a promising candidate for TCES was verified by XRF analysis, which was in the range of 25–63% (w/w). XRD results indicate that the CaO lies as free lime (3–32%), calcite (21–29%), and silicate in all fly ash samples. The results of STA show that all fly ash samples could fulfill the requirements for TCES (i.e., charging and discharging). A cycling stability test of three cycles was demonstrated for all samples which indicates a reduction of conversion in the first three reaction cycles. The energy content of the examined samples was up to 504 kJ/kg according to the STA results. More energy (~1090 kJ/kg) in the first discharging step in the CO2/H2O atmosphere could be released through two kinds of fly ash samples due to the already existing free lime (CaO) in those samples. The CO2 storage capacity of these fly ash samples ranged between 18 and 110 kg per ton of fly ash, based on the direct and dry method. The leaching tests showed that all heavy metals were below the limit values of the Austrian landfill ordinance. It is viable to say that the valorization of fly ash from the pulp and paper industries via TCES and CO2 storage is plausible. However, further investigations such as cycling stability improvement, system integration and a life cycle assessment (LCA) still need to be conducted.

By analyzing the three-dimensional digital model of a real carbon paper gas diffusion layer (GDL) reconstructed by X-ray computed tomography (CT), it was found that fibers are not distributed at any angle but within a certain range. The fiber orientation can be represented by fiber pitch (i.e., the angle between a single fiber and the in-plane direction). The effect of fiber orientation on stochastic reconstruction and transport properties (permeability) was investigated in this paper to find which fiber pitch range can achieve a better GDL on fluid flow. First, the actual fiber pitch was measured by analyzing SGL-24BA images obtained by X-ray CT. Also, seven different ranges of fiber pitch were randomly chosen to reconstruct GDL. Then, the permeability of these digital models was calculated using the Lattice Bolzmann Method (LBM) and discussed to obtain the fiber pitch range of the optimal permeability. The results show that the mean fiber pitch of SGL-24BA is 2.40&deg, and the individual values are all less than 6&deg, also, the permeability of the through-plane direction increases gradually as the range of fiber pitch increases, which can be used for the structural design of carbon paper GDL.

Each year the pulp and paper industries generate enormous amounts of effluent treatment sludge. The sludge is made up of various fractions including primary, secondary, deinked, fiber rejects sludge, etc. The goal of this study was to evaluate the fuel properties of the hydrochars produced from various types of paper mill sludges (PMS) at 180 °C, 220 °C, and 260 °C. The hydrochars, as well as the raw feedstocks, were characterized by means of ultimate analysis, proximate analysis, moisture, ash, lignin, sugar, and higher heating value (HHVdaf) measurements. Finally, combustion indices of selected hydrochars were evaluated and compared with bituminous coal. The results showed that HHVdaf of hydrochar produced at 260 °C varied between 11.4 MJ/kg and 31.5 MJ/kg depending on the feedstock. This implies that the fuel application of hydrochar produced from PMS depends on the quality of feedstocks rather than the hydrothermal carbonization (HTC) temperature. The combustion indices also showed that when hydrochars are co-combusted with coal, they have similar combustion indices to that of coal alone. However, based on the energy and ash contents in the produced hydrochars, Primary and Secondary Sludge (PPS2) could be a viable option for co-combustion with coal in an existing coal-fired power plant.

In January 2011, the introduction of high-efficiency cogeneration in Europe radically modified the incentive scheme for combined heat and power (CHP) plants. Since then, the techno-economic feasibility of new cogeneration plants in different areas of application (industry, service, residential, etc.), along with the definition of their optimal operation, have inevitably undergone a radical change. In particular, with reference to the Italian case and according to the most recent ministerial guidelines following the new EU regulation, in the event that cogeneration power plants do not reach an established value in terms of overall efficiency, their operation has to be split into a CHP and a non-CHP portion with incentives proportional to the energy quantities pertaining to the CHP portion only. In the framework of high-efficiency cogeneration, the present study compares different CHP solutions to be coupled with the paper industry that, among all the industrial processes, appears to be the best suited for cogeneration applications. With reference to this particular industrial reality, energy, environmental, and economic performance parameters have been defined, analysed, and compared with the help of GateCycle software. Among the proposed CHP alternatives, results show that gas turbines are the most appropriate technology for paper industry processes.

This study used the subcritical hydrothermal liquefaction technique (SHLT) in the co- liquefaction of process rejects at a wastepaper-based paper mill (PRWPM) and waste soybean oil (WSO) for the production of biofuels and bio-char material. PRWPM emits complicated waste composed of cellulose, hemicellulose, lignin, and plastic from sealing film. The waste is produced from the recycled paper process of a mill plant located in central Taiwan. The source of WSO is the rejected organic waste from a cooking oil factory located in north Taiwan. PRWPM and WSO are suitable for use as fuels, but due to their high oxygen content, their use as commercial liquid fuels is not frequent, thus making deoxygenation and hydrogenation necessary. The temperature and pressure of SHLT were set at 523–643 K and 40–250 bar, respectively. The experimental conditions included solvent ratios of oil–water, temperature, reaction time, and ratios of solvent to PRWPM. The analysis results contained approximated components, heating values, elements, surface features, simulated distillations, product compositions, and recovery yields. The HHV of the product occurred at an oil–water ratio of 75:25, with a value of 38.04 MJ kg−1. At an oil–water ratio of 25:75, the liquid oil-phase product of SHTL has the highest heating value 42.02 MJ kg−1. Higher WSO content implies a lower heating value of the oil-phase product. The simulated distillation result of the oil-phase product with higher content of alcohol and alkanes obtained at the oil–water ratio of 25:75 is better than the other ratios. Here, the carbon number of the oil product is between C8–C36. The product conversion rate rises with an increase of the WSO ratio. It is proved that blending soybean oil with water can significantly enhance the quality of liquefied oil and the conversion rate of PRWPM. Therefore, the solid and liquid biomass wastes co-liquefaction to produce gas and liquid biofuels under SHLT are quite feasible.

This paper presents analysis, diagnosis and disposal with a typical internal breakdown failure of the resin impregnated paper (RIP) valve side bushing in high voltage direct current (HVDC) converter transformer. Based on the analysis of fault current characteristics at the time of the RIP valve side bushing failure, and field test results of insulation parameters, a method of diagnosing typical breakdown failures of valve side bushings is proposed. Through disassembly inspection of the internal overheating and arcing traces on the failure bushing, the root cause of this typical breakdown failure is found, which is upper axial flashover along the RIP condenser/SF6 interface caused by the abnormal contact of two current-carrying conductive tubes. Temperature distribution inside the bushing with an abnormal contact resistance between the copper conductive tube and aluminum conductive tube under different load current is simulated by using the finite element method. An special device is also developed for repairing defective bushing on-site, and 75 bushings with conductive contact defects have been repaired on the premise of not pushing converter transformers away from the valve hall and even without pulling out defective bushings.

This paper presents research results of the loss factor of high voltage insulation samples made of aramid paper impregnated with various types of insulating oil. The analysis was carried out in the high frequency domain in the range of 50 Hz to 1 MHz. The experiments were carried out for three impregnation types: mineral oil, synthetic ester and natural ester. The influence of temperature in the range of 20 &deg, C to 100 &deg, C, which is typical when using this type of insulation in power transformers, was taken into account. In addition, the process of influence of initial aging of aramid paper was simulated by heat soaking the samples before their impregnation at a temperature of 250 &deg, C in multiple time intervals. Based on the analyses of dispersion characteristics of insulation sample loss factors, conclusions and recommendations for further diagnostics of aramid-oil insulations using the method described were delineated.

Mineral oil is the most popular insulating liquid for high voltage transformers due to its function as a cooling liquid and an electrical insulator. Kraft paper has been widely used as transformer solid insulation for a long time already. The degradation process of transformer paper due to thermal aging in mineral oil can change the physical and chemical structure of the cellulose paper. Fourier transform infrared (FTIR) spectroscopy analysis was used to identify changes in the chemical structure of transformer paper aged in mineral oil. FTIR results show that the intensity of the peak absorbance of the O–H functional group decreased with aging but the intensity of the peak absorbance of the C–H and C=O functional groups increased with aging. Changes in the chemical structure of the cellulose paper during thermal aging in mineral oil can be analyzed by an oxidation process of the cellulose paper and the reaction process between the carboxylic acids in the mineral oil and the hydroxyl groups on the cellulose. The correlation between the functional groups and the average number of chain scissions of transformer paper gives initial information that the transformer paper performance can be identified by using a spectroscopic technique as a non-destructive diagnostic technique.

The article presents issues related to the aging behavior of oil-paper insulations in transformers using different oil- and ester-based insulating fluids. Despite numerous conducted studies on the subject of oil-paper aging, the use of new insulating fluids is creating open questions. In addition, new liquids such as synthetic and natural esters, as well as oil of the newest generation, are being used. Furthermore, there is still little research on the formation of aging markers with this form of the dielectric. For this reason, in this contribution, oil-paper insulations with mineral oil-based insulating fluids, natural and synthetic esters, as well as oil from natural gas, are aged thermally accelerated at 130 °C over a duration of 15 weeks, by considering two cases of free-breathing and hermetically sealed transformers. Therefore, various aging markers are investigated to allow a condition assessment. The results show that differences exist between the fluids and design of the transformer, as in the aging rate of the paper and the formation of aging markers in the insulating liquid such as acids. These findings can be used to improve asset management strategies by a more precise determination of the aging state depending on the transformer type as well as the type of insulating fluid.

Improving energy efficiency is an effective way to address the issues of economic development, energy saving and emissions reduction. For any important industries it is therefore necessary to measure energy efficiency and set a practical target for it. In this paper, we use CCR, SBM and energy intensity to measure the energy efficiency of the paper industries of 22 EU countries. Results indicate that the SBM and CCR efficiency value is more meaningful for policy makers than that of energy intensity, as measurement results of energy intensity deviate from reality and economic efficiency. The CCR and SBM have roughly the same fluctuation trends and the average SBM energy efficiency value is 0.71, always 10 percent lower than CCR model, as it takes simultaneous account of both the optimal input-output and has more discriminatory power in efficiency measurement. Furthermore, EU policy makers could improve energy efficiency by raising energy prices. As for the 2030 EU target of energy saving and emission reduction, the EU should pay more attention to five major paper producers: Finland, Sweden, Germany, the United Kingdom and Italy.

Paper mill sludge (PMS) solids are predominantly comprised of cellulosic fibers and fillers rejected during the pulping or paper making process. Most sludges are dewatered and discharged into landfills or land spread at a cost to the mill; creating large economic and environmental burdens. This lignocellulosic residual stream can be used as a source of sugars for microbial fermentation to renewable chemicals. The aim of this study was to determine the possibility of converting mill sludge to sugars and then fermentation to either isoprene or ethanol. Chemical analysis indicated that the cellulosic fiber composition between 28 to 68% and hemicellulose content ranged from 8.4 to 10.7%. Calcium carbonate concentration in the sludge ranged from 0.4 to 34%. Sludge samples were enzyme hydrolyzed to convert cellulose fibers to glucose, percent conversion ranged from 10.5 to 98%. Calcium carbonate present with the sludge resulted in low hydrolysis rates; washing of sludge with hydrochloric acid to neutralize the calcium carbonate, increased hydrolysis rates by 50 to 88%. The production of isoprene “very low” (190 to 470 nmol) because the isoprene yields were little. Using an industrial yeast strain for fermentation of the sludge sugars obtained from all sludge samples, the maximum conversion efficiency was achieved with productivity ranging from 0.18 to 1.64 g L−1 h−1. Our data demonstrates that PMS can be converted into sugars that can be fermented to renewable chemicals for industry.

Cellulosic insulation paper is usually used in oil-immersed transformer insulation systems. In this study, the molecular dynamics method based on reaction force field (ReaxFF) was used to simulate the pyrolysis process of a cellobiose molecular model. Through a series of ReaxFF- Molecular Dynamics (MD) simulations, the generation path of ethanol at the atomic level was studied. Because the molecular system has hydrogen bonding, force-bias Monte Carlo (fbMC) is mixed into ReaxFF to reduce the cost of calculation by reducing the sampled data. In order to ensure the reliability of the simulation, a model composed of 20 cellobioses and a model composed of 40 cellobioses were respectively established for repeated simulation in the range of 500–3000 K. The results show that insulating paper produced ethanol at extreme thermal fault, and the intermediate product of vinyl alcohol is the key to the aging process. It is also basically consistent with others’ previous experiment results. So it can provide an effective reference for the use of ethanol as an indicator to evaluate the aging condition of transformers.

Based on the existing acknowledgement that space charge modulates AC and DC breakdown of insulating materials, this investigation promotes the related investigation into the situations of more complex electrical stress, i.e., AC-DC combined voltages. Experimentally, the AC-DC breakdown characteristics of oil impregnated paper insulation were systematically investigated. The effects ofpre-applied voltage waveform, AC component ratio, and sample thickness on AC-DC breakdown characteristics were analyzed. After that, based on an improved bipolar charge transport model, the space charge profiles and the space charge induced electric field distortion during AC-DC breakdownwere numerically simulated to explain the differences in breakdown characteristics between the pre-applied AC and pre-applied DC methods under AC-DC combined voltages. It is concluded that large amounts of homo-charges are accumulated during AC-DC breakdown, which results in significantly distorted inner electric field, leading to variations of breakdown characteristics of oil impregnated paper insulation. Therefore, space charges under AC-DC combined voltages must be considered in the design of converter transformers. In addition, this investigation could provide supporting breakdown data for insulation design of converter transformers and could promote better understanding on the breakdown mechanism of insulating materials subjected to AC-DC combined voltages.

To facilitate better interpretation of dielectric response measurements—thereby directing numerical evidence for condition assessments of oil-paper-insulated equipment in high-voltage alternating current (HVAC) transmission systems—a novel approach is presented to estimate the parameters in the extended Debye model (EDM) using wideband frequency domain spectroscopy (FDS). A syncretic algorithm that integrates a genetic algorithm (GA) and the Levenberg-Marquardt (L-M) algorithm is introduced in the present study to parameterize EDM using the FDS measurements of a real-life 126 kV oil-impregnated paper (OIP) bushing under different controlled temperatures. As for the uncertainty of the EDM structure due to variable branch quantity, Akaike’s information criterion (AIC) is employed to determine the model orders. For verification, comparative analysis of FDS reconstruction and results of FDS transformation to polarization–depolarization current (PDC)/return voltage measurement (RVM) are presented. The comparison demonstrates good agreement between the measured and reconstructed spectroscopies of complex capacitance and tan δ over the full tested frequency band (10−4 Hz–103 Hz) with goodness of fit over 0.99. Deviations between the tested and modelled PDC/RVM from FDS are then discussed. Compared with the previous studies to parameterize the model using time domain dielectric responses, the proposed method solves the problematic matching between EDM and FDS especially in a wide frequency band, and therefore assures a basis for quantitative insulation condition assessment of OIP-insulated apparatus in energy systems.

Space charge has close relation with the trap distribution in the insulation material. The phenomenon of charges trapping and detrapping has attracted significant attention in recent years. Space charge and trap parameters are effective parameters for assessing the ageing condition of the insulation material qualitatively. In this paper, a new method for calculating trap distribution based on the double exponential fitting analysis of charge decay process and its application on characterizing the trap distribution of oil impregnated insulation paper was investigated. When compared with the common first order exponential fitting analysis method, the improved dual-level trap method could obtain the energy level range and density of both shallow traps and deep traps, simultaneously. Space charge decay process analysis of the insulation paper immersed with new oil and aged oil shows that the improved trap distribution calculation method can distinguish the physical defects and chemical defects. The trap density shows an increasing trend with the oil ageing, especially for the deep traps mainly related to chemical defects. The greater the energy could be filled by the traps, the larger amount of charges could be trapped, especially under higher electric field strength. The deep trap energy level and trap density could be used to characterize ageing. When one evaluates the ageing condition of oil-paper insulation using trap distribution parameters, the influence of oil performance should not be ignored.

The breakdown property of oil-impregnated paper is a key factor for converter transformer design and operation, but it is not well understood. In this paper, breakdown voltages of oil-impregnated paper were measured at different temperatures. The results showed that with the increase of temperature, electrical, electro-thermal and thermal breakdown occurred successively. An electro-thermal breakdown model was proposed based on the heat equilibrium and space charge transport, and negative differential mobility was introduced to the model. It was shown that carrier mobility determined whether it was electrical or thermal breakdown, and the model can effectively explain the temperature-dependent breakdown.

The article describes a case study when the voltage collapse during lightning impulse tests of new power transformers was noticed and when the repeated tests finished with a positive result. The step-by-step process of reaching the conclusion on the basis of dissolved gas analysis (DGA) as a key method of the investigations was presented. The considerations on the possible source of the analysis showed that the Duval triangle method, used in the analysis of the concentration of gases dissolved in oil samples taken from bushings, more reliably and unambiguously than the ratio method recommended in the IEC 60599 Standard, indicated a phenomenon which was identified in the insulation structure of bushings analyzed. Additionally, the results from DGA were found to be consistent with an internal inspection of bushings, which showed a visible trace of discharge on the inside part of the epoxy housing, as a result of the lightning induced breakdown.

The electric field distortion caused by space charge is an important factor affecting the operation reliability of oil–paper insulation in a converter transformer. To study the accumulation and decay characteristics of the space charge within oil-impregnated pressboard under DC and polarity reversal voltage, and consider the possible operating conditions of the converter transformer, the space charge behavior of oil-impregnated pressboard was measured by the pulsed electro-acoustic (PEA) method in the temperature range from −20 °C to 60 °C. The effect of temperature on the accumulation and decay characteristics of space charge is also analyzed. The space charge accumulated within the pressboard at low temperature is mainly homocharge injected by the electrode, while heterocharge formed by ion dissociation counteracts some of the homocharge at high temperature. Thus, the space charge of pressboard first increases, then decreases, with an increase in temperature. However, slow decay of the space charge causes severe distortion of the electric field distribution in the pressboard during voltage polarity reversal.

Breakdown strength is an important electrical property of insulating paper. Oil-impregnated paper of various aging states was prepared. Its breakdown voltage was then measured at pulsating direct current (DC) voltage with various ripple factors, and alternating current (AC) and DC voltage for comparison, respectively. The AC breakdown voltage is the smallest, and pulsating DC (r = 1/5) breakdown voltage is the greatest before the paper reaches its end of life. A dielectric model was adopted to investigate the difference in magnitude of breakdown voltage at different voltage waveforms. Meanwhile, it was found that breakdown voltage fluctuated and even increased occasionally during the thermal aging process, and a somewhat opposite changing tendency versus aging time was observed for breakdown voltage at DC voltage and pulsating DC voltage with small ripple factors (r = 1/5 and 1/3), compared with AC voltage. The degree of polymerization (DP) and moisture content of the paper were measured, and the characteristics of the pores and cracks of the paper were obtained to investigate the possible influencing factors of breakdown voltage at different aging states. The results showed that the moisture content, oil absorption ability associated with pores and cracks of paper, and the damage to paper structure all contributed to the variation of the breakdown voltage versus aging time, while the importance of their influence differed as the aging state of paper varied.

A key challenge in prevention of global warming is how to increase energy efficiency, to be able to deal with increased fossil CO2 emissions from rising energy usage. Increasing energy efficiency will decrease energy usage and is in a key role in emission mitigation. The focus is the pulp and paper industry, which is energy-intensive. Development of industrial energy efficiency has been studied before but the role of industrial transformation is still mostly unknown. The knowledge must be improved, to be able to predict future developments in the most effective way. In this research, impact of various production unit closures and start-ups on energy efficiency of the Finnish pulp and paper industry were studied utilizing statistical analysis. Results indicate that about 20% of the Finnish pulp and paper industry energy efficiency improvement between 2011 and 2017 is caused by the major structural changes. The rest, 80% of the progress, was mainly due to improved technology and more optimal operational modes. Additional findings suggest that modern mill start-ups have a significantly greater potential to reduce energy consumption than old mill closures.

To study the microscopic thermal aging mechanism of insulating paper cellulose through molecular dynamics simulation, it is important to select suitable DP (Degree of Polymerization) and force field for the cellulose model to shorten the simulation time and obtain correct and objective simulation results. Here, the variation of the mechanical properties and solubility parameters of models with different polymerization degrees and force fields were analyzed. Numerous cellulose models with different polymerization degrees were constructed to determine the relative optimal force field from the perspectives of the similarity of the density of cellulose models in equilibrium to the actual cellulose density, and the volatility and repeatability of the mechanical properties of the models through the selection of a stable polymerization degree using the two force fields. The results showed that when the polymerization degree was more than or equal to 10, the mechanical properties and solubility of cellulose models with the COMPASS (Condensed-phase Optimized Molecular Potential for Atomistic Simulation Studies) and PCFF (Polymer Consistent Force Field) force fields were in steady states. The steady-state density of the cellulose model using the COMPASS force field was closer to the actual density of cellulose. Thus, the COMPASS force field is favorable for molecular dynamics simulation of amorphous cellulose.

In this paper, polysiloxane is used to modify insulation paper cellulose, and molecular dynamics methods are used to evaluate the glass transition temperature and mechanical properties of the paper before and after the modification. Analysis of the static mechanical performance of the model shows that, with increasing temperature, the elastic modulus of both the modified and unmodified cellulose models decreases gradually. However, the elastic modulus of the modified model is greater than that of the unmodified model. Using the specific volume method and calculation of the mean square displacement of the models, the glass transition temperature of the modified cellulose model is found to be 48 K higher than that of the unmodified model. Finally, the changes in the mechanical properties and glass transition temperature of the model are analyzed by energy and free volume theory. The glass transition temperatures of the unmodified and modified cellulose models are approximately 400 K and 450 K, respectively. These results are consistent with the conclusions obtained from the specific volume method and the calculation of the mean square displacement. It can be concluded that the modification of insulation paper cellulose with polysiloxane will effectively improve its thermal stability.

Most power transformers operating in a power system possess oil-paper insulation. A serious defect of this type of insulation, which is associated with long operation time, is an increase in the moisture content. Moisture introduces a number of threats to proper operation of the transformer, e.g., ignition of partial discharges (PDs). Due to the varying temperature of the insulation system during the unit’s normal operation, a dynamic change (migration of water) takes place, precipitating the oil-paper system from a state of hydrodynamic equilibrium. This causes the PDs to be variable in time, and they may intensify or extinguish. Studies on model objects have been conducted to determine the conditions (temperature, humidity, time) that will have an impact on the ignition and intensity of the observed phenomenon of PDs. The conclusions of this study will have a practical application in the evaluation of measurements conducted in the field, especially in relation to the registration of an online PD monitoring system.

Using mathematical programming with activity-based costing (ABC) and based on the theory of constraints (TOC), this study proposed a green production model for the traditional paper industry to achieve the purpose of energy saving and carbon emission reduction. The mathematical programming model presented in this paper considers (1) revenue of main products and byproducts, (2) unit-level, batch-level, and product-level activity costs in ABC, (3) labor cost with overtime available, (4) machine cost with capacity expansion, (5) saved electric power and steam costs by using the coal as the main fuel in conjunction with Refuse Derived Fuel (RDF). This model also considers the constraint of the quantity of carbon equivalent of various gases that are allowed to be emitted from the mill paper-making process to conform to the environmental protection policy. A numerical example is used to demonstrate how to apply the model presented in this paper. In addition, sensitivity analysis on the key parameters of the model are used to provide further insights for this research.

The research aims were to construct an air-breathing paper-based microfluidic fuel cell (paper-based μ FC) and to evaluated it with different soft drinks to provide energy for their prospective use in portable devices as an emergency power source. First, in a half-cell configuration, cyclic voltammetry showed that glucose, maltose, and fructose had specific oxidation zones in the presence of platinum-ruthenium on carbon (PtRu/C) when they were individual. Still, when they were mixed, glucose was observed to be oxidized to a greater extent than fructose and maltose. After, when a paper-based μ FC was constructed, PtRu/C and platinum on carbon (Pt/C) were used as anode and cathode, the performance of this μ FC was mostly influenced by the concentration of glucose present in each soft drink, obtaining maximum power densities at room temperature of 0.061, 0.063, 0.060, and 0.073 mW cm − 2 for Coca Cola ® , Pepsi ® , Dr. Pepper ® , and 7up ® , respectively. Interestingly, when the soft drinks were cooled, the performance was increased up to 85%. Furthermore, a four-cell stack μ FC was constructed to demonstrate its usefulness as a possible power supply, obtaining a power density of 0.4 mW cm − 2 , using Coca Cola ® as fuel and air as oxidant. Together, the results of the present study indicate an alternative application of an μ FC using soft drinks as a backup source of energy in emergencies.

This manuscript presents a comprehensive literature review with the aim to provide readers a reference document with up-to-date information on the field of methanol use as a chemical marker. It has been a little more than a decade since methanol was first introduced as a marker for assessing solid insulation condition in power transformers. It all started when methanol was identified in the laboratory during thermal ageing tests carried out with oil-immersed insulating papers and was subsequently also identified in transformer field samples. The first publication on the subject was released in 2007 by our research group. This review covers the methanol fundamentals such as the analytical methods for its determination in transformer oil, which is generally performed by headspace gas chromatography with mass spectrometry or flame ionization as a detector. Current standardization efforts for its determination include ASTM working group 30948 and IEC TC10. Kinetic studies have confirmed the relationship between methanol generation, the number of broken 1,4-β-glycosidic bonds of cellulose and changes in mechanical properties. Laboratory tests have confirmed its stability at different accelerated ageing temperatures. Several utilities have identified methanol during field measurements, case studies on power and some distribution transformers are presented, as well as transformer postmortem investigations. These field-testing results demonstrate its utility in monitoring cellulosic insulation degradation. Recently, a model of methanol interpretation has become available that allows for evaluation of the average degree of polymerization of core type transformer cellulose winding. Methanol has a role as an indicator of cellulosic solid insulation ageing in transformer mineral oil, and it is expected that in the future it will be in routine use by utilities.

Aging of a power transformer&rsquo, s insulation system produces carboxylic acids. These acids&mdash, acetic, formic and levulinic&mdash, are absorbed by the paper insulating material, thus accelerating the degradation of the whole insulation system. In this contribution, the effect of these acids on the aging of oil-impregnated paper insulation used in power transformer is reported. A laboratory aging experiment considering different concentrations of these three acids was performed to assess their effect on the insulation system&rsquo, s degradation. Each acid was individually mixed with virgin oil, and a mixture of acids was also blended with oil. The paper&rsquo, s degradation was assessed by the degree of polymerization (DPv). It was found that the DPv of paper aged with formic acid decreased much faster in comparison to the other acids.

The thermal aging property of oil-paper insulation is a key factor affecting the service life of transformers. In this study, nano-Al2O3 was added to insulating paper to improve its anti-thermal aging property and delay the aging rate of the insulating oil. The composite paper containing 2% nano-Al2O3 had the highest tensile strength and therefore was selected for the thermal aging test. The composite and normal papers were treated with an accelerated thermal aging experiment at the temperature of 130 °C for 56 days. The variations of the degree of polymerization (DP) and tensile strength of the insulating papers with aging time were obtained. The characteristics of the insulating oil, including color, acid content, breakdown voltage, and dielectric loss were analyzed. The results revealed that compared with a plain paper, the composite paper maintained a higher DP, and its tensile strength decreased more slowly during the aging process. The oil-impregnated composite paper presented a lighter-colored oil, less viscosity changes, and a considerably lower quantity of thermal aging products. In addition, nano-Al2O3 can effectively adsorb copper compounds and keep part of the acid products and water away from the thermal aging process. This characteristic restrained the catalysis of copper compounds and H+ in the thermal aging reaction and reduced the thermal aging speed of both the insulating paper and the insulating oil.

In order to explore a non-destructive method for measuring the polymerization degree (DP) of paper insulation in transformer, a new method that based on the optical properties of free fiber particles in transformer oil was studied. The chromatic dispersion images of fibers with different aging degree were obtained by polarizing microscope, and the eigenvalues (r, b, and Mahalanobis distance) of the images were extracted by the RGB (red, blue, and green) tricolor analysis method. Then, the correlation between the three eigenvalues and DP of paper insulation were simulated respectively. The results showed that the color of images changed from blue-purple to orange-yellow gradually with the increase of aging degree. For the three eigenvalues, the relationship between Mahalanobis distance and DP had the best goodness of fit (R2 = 0.98), higher than that of r (0.94) and b (0.94). The mean square error of the relationship between Mahalanobis distance and DP (52.17) was also significantly lower than that of r and b (97.58, 98.05). Therefore, the DP of unknown paper insulation could be calculated by the simulated relationship of Mahalanobis distance and DP.

Mineral oil is widely used as liquid insulation in high voltage equipment. Due to environmental considerations, recently natural esters have been considered as naturally friendly liquid insulation candidates for high voltage transformers. In this experiment, transformer insulation paper was subjected to get accelerated aging test with copper strip in natural ester in a hermeneutical heat-resistant glass bottle at temperatures of 120 °C and 150 °C for 336 h, 672 h and 1008 h. The experimental results of Fourier transform infrared spectroscopy (FTIR) showed that the intensity of the absorbance peak of the O–H functional group decreased with aging, while the intensity of the C–H and C=O functional group absorbance peaks have increased with aging and the intensity of the C–O functional group absorbance peak has a tendency to increase with aging. The energy dispersive X-ray spectroscopy (EDS) experimental results showed that the weight percent of the element C increased with aging and the weight percent of the element O has decreased with aging. The experimental results show a good correlation between the degree of polymerization (DP) and the weight percent of O element. This indicates that EDS may be used as a new method for estimating the DP of transformer insulation paper.

Partial discharge (PD) behaviors of oil-paper insulation is distinctive in AC and DC combined electric fields in converter transformers from PD behaviors in pure AC or DC electric fields. The present study focuses on the PD developing processes and characteristics of oil-paper insulation systems with needle-plane defects under different AC/DC proportions. The degradation of oil-paper insulation can be accelerated by PD pulses incurred by needle-plane defects. AC-DC combined voltages are applied to the needle-plane defect model simultaneously in the established experimental platform, and the proportions of AC/DC voltages are decided according to the cases in actual converter transformers. The developing processes from the initiation of partial discharge until final breakdown were observed for each AC/DC proportion. PD parameters and patterns were acquired by a detector using the pulse current method. The test results indicate that the inception and breakdown voltages increase with the increase of the DC component in AC-DC combined voltages. However, pulse repetition rate and amplitude of PD shows a descending trend when AC/DC proportion decreases. Meanwhile, the PD recurrence rate in the phase between 180° and 360° becomes higher than that in the phase between 0° and 180° at the initial stage as the DC proportion increases; high-amplitude discharges mainly occur in the phase range between 180° and 360° when the pressboard is close to breakdown. The current study is useful in further research on fault diagnosis in converter transformers.

This article presents an algorithm for modelling an Adaptive Neuro Fuzzy Inference System (ANFIS) for power transformer paper conditions in order to estimate the transformer’s expected life. The dielectric characteristics, dissolved gasses, and furfural of 108 running transformers were collected, which were divided into 76 training datasets and another 32 testing datasets. The degree of polymerization (DP) of the transformer paper was predicted using the ANFIS model based on using the dielectric characteristics and dissolved gases as input. These inputs were analyzed, and the best combination was selected, whereas CO + CO2, acidity, interfacial tension, and color were correlated with the paper’s deterioration condition and were chosen as the input variables. The best combination of input variables and membership function was selected to build the optimal ANFIS model, which was then compared and evaluated. The proposed ANFIS model has 89.07% training accuracy and 85.75% testing accuracy and was applied to a transformer paper insulation assessment and an estimation of the expected life of four Indonesian transformers for which furfural data is unavailable. This proposed algorithm can be used as a furfural alternative for the general assessment of transformer paper conditions and the estimation of expected life and provides a helpful assistance for experts in transformer condition assessment.

The resistivity of oil impregnated paper will decrease during its aging process. This paper takes paper resistivity as an assessment index to evaluate the insulation condition of oil impregnated paper in power transformer. The feasibility of this method are discussed in two aspects: reliability and sensitivity. Iterative inversion of paper resistivity was combined with finite element simulation. Both the bisection method and Newton’s method were used as iterative methods. After the analysis and comparison, Newton’s method was selected as the first option of paper resistivity iteration for its faster convergence. In order to consider the spatial distribution characteristic of paper aging and enhance the calculation accuracy, the resistivity calculation is expanded to a multivariate iteration based on Newton’s method, in order to consider the spatial distribution characteristic of paper aging and improve the calculation accuracy. This paper presents an exploratory research on condition assessment of oil impregnated paper insulation, and provides some reference to the security and economy operation of power transformers.

Frequency domain spectroscopy is considered to be a promising and novel method for the assessment of the insulation condition of power equipment. This work has practical significance as it explains the microscopic mechanism of this method in a wide temperature range and further establishes its quantitative model. To achieve this, in the present paper, we select oil-impregnated paper—one of the most common insulation materials for power equipment with a complex microstructure—as a test sample, deduce a formula based on the relationship between the real and imaginary parts of the complex permittivity to extract the spectra of independent dielectric processes and measure the frequency domain spectra of oil-impregnated paper under different temperatures, as well as its thermally stimulated depolarization current with a series of bias voltages. The analysis results reveal that oil-impregnated paper’s frequency domain spectra in a wide temperature range are mainly determined by dielectric processes whose generation mechanisms are low-frequency dispersion, DC conduction, electrode relaxation, interfacial relaxation and dipole relaxation, respectively. Moreover, due to the different thermal properties of charge motions, the macroscopic characteristics and microscopic generation mechanisms of both spectra vary significantly with the sample’s temperature. After verifying the generation mechanisms of the spectra in high, middle and low-temperature ranges, function models for those spectra with clear physical meanings are established separately, providing sufficient physical parameters to carry out insulation assessment.

Scientific research plays an important role in the achievement of a sustainable society. However, grasping the trends in sustainability research is difficult because studies are not devised and conducted in a top-down manner with Sustainable Development Goals (SDGs). To understand the bottom-up research activities, we analyzed over 300,000 publications concerned with sustainability by using citation network analysis and natural language processing. The results suggest that sustainability science’s diverse and dynamic changes have been occurring over the last few years; several new topics, such as nanocellulose and global health, have begun to attract widespread scientific attention. We further examined the relationship between sustainability research subjects and SDGs and found significant correspondence between the two. Moreover, we extracted SDG topics that were discussed following a convergent approach in academic studies, such as “inclusive society” and “early childhood development”, by observing the convergence of terms in the citation network. These results are valuable for government officials, private companies, and academic researchers, empowering them to understand current academic progress along with research attention devoted to SDGs.

I have read, with interest, the article authorized by Hong and Kim, which was published in Energies 2018, 11, 407; doi:10.3390/en11020407: entitled “Development of a Data-Driven Predictive Model of Supply Air Temperature in an Air-Handling Unit for Conserving Energy”[...]

The healthy state of insulation in oil-impregnated bushings is traditionally evaluated by tan&delta, and capacitance at power frequency and mostly at 10 kV in the test standard. However, there has frequently been insulation accidents induced by moisture ingress (MI) for bushings that have passed the standard. The mechanism and new diagnostic features for MI into bushings were not distinct enough and an accurate test method is urgently needed research. To address this technical gap, a bushing model with a transparent sheath was designed and an ultrasonic humidifier device was adopted to simulate the environment of MI in bushings and recorded by digital camera. The parameters of dielectric dissipation factor, capacitance, partial discharge (PD), frequency domain response, and moisture content in oil were measured at room temperature with time. The results presented that both the increment dissipation factor at low frequency of 0.001 Hz and the increment dissipation factor of 1.2 Um could be used for detecting the earlier insulation defect of oil-impregnated paper (OIP) bushings. The phase resolved partial discharge (PRPD) can serve as the diagnostic basis of the severe state (S3) of insulation deterioration caused by MI into bushings around the phases of 0&ndash, 117&deg, 151&ndash, 303&deg, and 325&ndash, 360&deg, The research findings would provide a useful reference for the condition diagnosis and maintenance of OIP bushings. Especially, the increment detection of Frequency Domain Spectroscopy (FDS) at the frequency of 1 mHz and 10 kHz was recommended firstly for the operative bushings in real sites.

The aging of oil-paper insulation in power transformers may cause serious power failures. Thus, effective monitoring of the condition of the transformer insulation is the key to prevent major accidents. The purpose of this study was to explore the feasibility of confocal laser Raman spectroscopy (CLRS) for assessing the aging condition of oil-paper insulation. Oil-paper insulation samples were subjected to thermal accelerated ageing at 120 °C for up to 160 days according to the procedure described in the IEEE Guide. Meanwhile, the dimension of the Raman spectrum of the insulation oil was reduced by principal component analysis (PCA). The 160 oil-paper insulation samples were divided into five aging stages as training samples by clustering analysis and with the use of the degree of polymerization of the insulating papers. In addition, the features of the Raman spectrum were used as the inputs of a multi-classification support vector machine. Finally, 105 oil-paper insulation testing samples aged at a temperature of 130 °C were used to further test the diagnostic capability and universality of the established algorithm. Results demonstrated that CLRS in conjunction with the PCA-SVM technique provides a new way for aging stage assessment of oil-paper insulation equipment in the field.

The pulp and paper industry faces an emerging challenge for valorising wastes and side-streams generated according to the biorefinery concept. Eucalyptus globulus bark, an abundant industrial residue in the Portuguese pulp and paper sector, has a high potential to be converted into biobased products instead of being burned. This work aimed to evaluate the ethanol production from E. globulus bark previously submitted to kraft pulping through separate hydrolysis and fermentation (SHF) configuration. Fed-batch enzymatic hydrolysis provided a concentrated hydrolysate with 161.6 g L−1 of cellulosic sugars. S. cerevisiae and Ethanol Red® strains demonstrated a very good fermentation performance, despite a negligible xylose consumption. S. passalidarum, a yeast known for its capability to consume pentoses, was studied in a simultaneous co-culture with Ethanol Red®. However, bioethanol production was not improved. The best fermentation performance was achieved by Ethanol Red®, which provided a maximum ethanol concentration near 50 g L−1 and fermentation efficiency of 80%. Concluding, kraft pulp from E. globulus bark showed a high potential to be converted into cellulosic bioethanol, being susceptible to implementing an integrated biorefinery on the pulp and paper industrial plants.

In this paper, a study on the feasibility of the treatment of raw cheese whey by anaerobic co-digestion using coffee pulp residues as a co-substrate is presented. It considers raw whey generated in artisanal cheese markers, which is generally not treated, thus causing environmental pollution problems. An experimental design was carried out evaluating the effect of pH and the substrate ratio on methane production at 35◦C (i.e., mesophilic conditions). The interaction of the parameters on the co-substrate degradation and the methane production was analyzed using a response surface analysis. Furthermore, two kinetic models were proposed (first order and modified Gompertz models) to determine the dynamic profiles of methane yield. The results show that co-digestion of the raw whey is favored at pH = 6, reaching a maximum yield of 71.54 mLCH4 gVSrem−1 (31.5% VS removed) for raw cheese whey and coffee pulp ratio of 1 gVSwhey gVSCoffe−1 . The proposed kinetic models successfully fit the experimental methane production data, the Gompertz model being the one that showed the best fit. Then, the results show that anaerobic co-digestion can be used to reduce the environmental impact of raw whey. Likewise, the methane obtained can be integrated into the cheese production process, which could contribute to reducing the cost per energy consumption.

Sources such as solar and wind energy are intermittent, and this is seen as a barrier to their wide utilization. The increasing grid integration of intermittent renewable energy sources generation significantly changes the scenario of distribution grid operations. Such operational challenges are minimized by the incorporation of the energy storage system, which plays an important role in improving the stability and the reliability of the grid. This study provides the review of the state-of-the-art in the literature on the economic analysis of battery energy storage systems. The paper makes evident the growing interest of batteries as energy storage systems to improve techno-economic viability of renewable energy systems; provides a comprehensive overview of key methodological possibilities for researchers interested in economic analysis of battery energy storage systems; indicates the need to use adequate economic indicators for investment decisions; and identifies key research topics of the analyzed literature: (i) photovoltaic systems with battery energy storage systems for residential areas, (ii) comparison between energy storage technologies, (iii) power quality improvement. The last key contribution is the proposed research agenda.

The constant increase in the amount of food waste accumulating in landfills and discharged into the water reservoirs causes environment pollution and threatens human health. Solid and liquid food wastes include fruit, vegetable, and meat residues, alcohol bard, and sewage from various food enterprises. These products contain high concentrations of biodegradable organic compounds and represent an inexpensive and renewable substrate for the hydrogen fermentation. The goal of the work was to study the efficiency of hydrogen obtaining and decomposition of solid and liquid food waste via fermentation by granular microbial preparation (GMP). The application of GMP improved the efficiency of the dark fermentation of food waste. Hydrogen yields reached 102 L/kg of solid waste and 2.3 L/L of liquid waste. The fermentation resulted in the 91-fold reduction in the weight of the solid waste, while the concentration of organics in the liquid waste decreased 3-fold. Our results demonstrated the potential of granular microbial preparations in the production of hydrogen via dark fermentation. Further development of this technology may help to clean up the environment and reduce the reliance on fossil fuels by generating green hydrogen via recycling of household and industrial organic wastes.

Due to the recent global increase in fuel prices, to reduce emissions from ground transportation and improve urban air quality, it is necessary to improve fuel efficiency and reduce emissions. Water, methanol, and a mixture of the two were added at the pre-intercooler position to keep the same charge and cooling of the original rich mixture, reduce BSFC and increase ITE, and promote combustion. The methanol/water mixing volume ratios of different fuel injection strategies were compared to find the best balance between fuel consumption, performance, and emission trends. By simulating the combustion mechanism of methanol, water, and diesel mixed through the Chemkin system, the ignition delay, temperature change, and the generation rate of the hydroxyl group (−OH) in the reaction process were analyzed. Furthermore, the performance and emission of the engine were analyzed in combination with the actual experiment process. This paper studied the application of different concentration ratios of the water–methanol–diesel mixture in engines. Five concentration ratios of water–methanol blending were injected into the engine at different injection ratios at the pre-intercooler position, such as 100% methanol, 90% methanol/10% water, 60% methanol/40% water, 30% methanol/70% water, 100% water was used. With different volume ratios of premixes, the combustion rate and combustion efficiency were affected by droplet extinguishment, flashing, or explosion, resulting in changes in combustion temperature and affecting engine performance and emissions. In this article, the injection carryout at the pre-intercooler position of the intake port indicated thermal efficiency increase and a brake specific fuel consumption rate decrease with the increase of water–methanol concentration, and reduce CO, UHC, and nitrogen oxide emissions. In particular, when 60% methanol and 40% water were added, it was found that the ignition delay was the shortest and the cylinder pressure was the largest, but the heat release rate was indeed the lowest.

This paper presents bioenergy value chain modelling to estimate the biomass and bioenergy cost of production and biomass netback in combined heat and power (CHP) systems. Modelling compares biomass cost and netback to analyse the feasibility of CHP systems, as well as the internal rate of return (IRR) and payback period (PBP). Models are implemented into the IMP Bio2Energy® software (Instituto Mexicano del Petróleo, Mexico City, Mexico) for practical application and demonstrated for bioenergy generation in the agroindustrial processes of tequila production, coffee and orange processing using as biomass the agave bagasse, coffee pulp and orange peels coproducts, respectively. Results show that the CHP systems are economically feasible, i.e., biomass cost of production is lower than netback, PBP between 3 and 4 years and IRR > 20%. The cost of bioenergy is lower than the cost of fuel oil and grid electricity being replaced. The sensitivity analysis for boiler steam pressure showed that there is an optimal pressure for coffee pulp (40 bar), a threshold pressure for orange (60 bar) and agave bagasse (70 bar). Sensitivity to biomass input indicated a maximum capacity where economy of scale does not produce any improvement in the indicators. Results demonstrate the usefulness of the modelling approach and IMP Bio2Energy® in analysing biomass CHP systems.

The aim of the study was to assess leaching of Cl−, SO42−, and PO43− from ashes formed in household furnaces. The ashes were obtained following the combustion of conventional fuels, namely wood and hard coal, and alternative fuels with various fractions of municipal waste in a household boiler. Aqueous leachates of the ashes were used to determine concentrations of chlorides by titration (Mohr’s method) (21.3–3049.6 mg/dm3), sulphates by the gravimetric method (12.2–244.1 mg/dm3), and phosphates by spectrophotometry (0.01–67.2 mg/dm3). It was found that co-combustion of municipal waste with plastic-coated paper cartons, diapers, or a mixed waste fraction leaves the greatest amount of ashes on the furnace grate. The highest amounts of Cl−, SO42−, and PO43− were leached from ashes generated from burning a mix of wood and coals, or wood alone (different species). The addition of municipal waste to the process of burning the conventional and alternative fuels studied did not significantly increase Cl−, SO42−, and PO43− content in aqueous extracts of ashes, the exception being diapers and plywood. In light of the study results, it was concluded that all the ashes could be reused (as an additive to concrete) except for the ash generated from the combustion of a mixed municipal waste fraction and coal (due to the content of Cl−) and diapers (due to the content of PO43−). It was demonstrated that Cl−, SO42−, and PO43− content in the entire set of samples and in individual ash groups is highly heterogeneous and variable.

Sludge incineration is a sludge resource management and disposal method that can greatly decrease the volume of sludge, reduce the degree of harm and realize the recovery of sludge heat energy. Most of the research on sludge incineration focuses on the combustion process and gas emissions, but there are relatively few studies on the sludge fuel molding and drying process before sludge incineration. Besides, independent incineration of sludge has high energy consumption. This paper proposes a pre-incineration treatment method in which sludge and corn stover are mixed to make fuel pellets and then dried. Specifically, the influence of molding pressure, raw material ratio and raw material particle size on the physical properties of the fuel, and the related mechanism, were studied. The density of fuel particles is mainly affected by the forming pressure, and the impermeability is mainly determined by the proportion of sludge in the raw material. The order of the variables based on their effect of improving fuel physical properties was: molding pressure &gt, raw material ratio &gt, raw material particle size. Moreover, the influence of drying temperature (40 °C, 60 °C, 80 °C, 100 °C, 120 °C) has been explored. When the initial water content is similar, the drying rate increases with the increase in temperature. It provides a reference for the sludge fuel molding and drying process, and promotes the practical application of mixing sludge and corn stalks to make fuel.