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Inter-provincial power transmission in China solved the problem of electricity production and consumption spatial mismatch, which also facilitated Chinese green energy transition and sustainable development. Aiming to understand the spatial patterns and main driving factors, this paper accounted the aggregate carbon intensity per electricity produced by each province, built the inter-provincial Out–Destination matrixes of carbon emission embodied in power transmission among 27 provincial areas of 2006 and 2019, and quantitatively analyzed the change in spatial patterns of carbon flow and carbon intensity difference between power inward and outward provinces. We found that the inter-provincial power transmission has led to the reduction in the national average carbon intensity per electricity produced from 0.855 kg/kWh in 2006 to 0.628 kg/kWh in 2019 and the green energy transition of all provinces. The spatial morphology characteristics of carbon flow show the 'three corridors of West-East Power Transmission (WEPT)' pattern, in which power is transmitted from some main thermal power-dominated provinces in central and north-west China to the eastern coastal provinces. Further, it resulted in the carbon leakage from electricity consumption of the coastal provinces and carbon overload of the hinterland provinces. Despite natural resource endowment, the location of the provinces in the national power grid, the national low-carbon energy transition strategy, as well as advances in long-distance ultra-high-voltage power transmission technologies were the main factors to the formation and evolution of Chinese electricity green transition. [ABSTRACT FROM AUTHOR]