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Increasing extreme rainfall events caused by global climate change have had a significant impact on urban drainage systems. As a critical component of a pumping station, a large-scale slanted axial-flow pump (SAFP) featuring high specific speed plays a critical role in mitigating urban flooding and waterlogging. In this study, to reveal the transient characteristics of a SAFP at shut-off conditions, a computational fluid dynamics (CFD) based approach with dynamic mesh was proposed. Multiple shut-off conditions with various shut-down speeds of the sluice gate (SG) were modeled. Our analysis demonstrated that both the shut-off conditions and the slanted structure have conspicuous impacts on the hydrodynamic performance of a SAFP. Reducing the shut-down speed leads to a greater reverse flow rate and higher runner speed. The water hammer effect was simulated with different shut-down speeds, increasing the water head by 5.07–10.42 m, the axial force by 163.46–297.06 kN∙m, and the axial moment by 116.05–224.01 kN∙m. Compared with the axial direction, moments in the radial directions were found with more obvious oscillation as a result of stronger rotor–stator interaction. Due to the gravitational effect of the slanted structure, the fluctuation of the runner in vertical direction presented an off-axis characteristic compared with the horizontal one. As the SG speed increased, pressure fluctuations gradually decreased at various locations across the SAFP. [ABSTRACT FROM AUTHOR]

To probe the possibility of thiophenolate as an origin of dibenzothiophenes (DBTs) and establish the detailed chemical transformations from thiophenolate to DBTs, the thermal degradation of thiophenolate has been carried out at various temperatures. The characterizations of both gaseous products and solid residues indicate that DBTs together with benzene, diphenyl sulfide, and diphenyl disulfide are the major degradation products. The presence of benzene supports that the thermal degradation of thiophenolate begins with the homolysis of Ar‒H bonds. The subsequent hydroarylation followed by the elimination and cyclization reactions facilely generates DBTs. The transformation of thiophenolate to DBTs is chemically simple and highly geochemically feasible. It readily unifies the chemical pathways involved in the generation of DBTs from thiophenolate and that of dibenzofurans from phenolate in nature. [ABSTRACT FROM AUTHOR]