1. Methanol-based thermochemical energy storage (TCES) for district heating networks.
- Author
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Rodríguez-Pastor, D.A., Carvajal, E., Becerra, J.A., Soltero, V.M., and Chacartegui, R.
- Subjects
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SOLAR thermal energy , *ENERGY storage , *GREEN fuels , *EXOTHERMIC reactions , *GREENHOUSE gases , *METHANOL as fuel - Abstract
With increasing volatility in natural gas markets and the need for residential heat, research for alternative thermal systems based on green hydrogen-based fuels is necessary. Massive implementation of hydrogen in the current fleet presents a challenge for the decarbonisation of conventional thermal processes. This paper presents the integration of green methanol from a seasonal thermochemical energy storage system (TCES) coupled with district heating networks (DHN). It allows for a solar-based storage and low-temperature heat generation from the exothermic discharge reaction. The system uses concentrated solar thermal energy to decompose methanol into syngas at moderate temperatures (<315 °C), reducing GHG emissions from combustion to meet residential heat. Its potential is assessed through an analysis of 458 rural municipalities in Spain, achieving a substitution of 3.1 % of the natural gas demand. The system allows the production of green fuels from syngas using an open-loop approach, offering new market pathways in primary sector. In a closed-loop configuration, roundtrip efficiencies exceeding 60 % and chemical conversion efficiencies exceeding 70 % are reached, resulting in a global efficiency of 12 % for the DHN and methanol-TCES. The results show a levelized cost of stored energy highly competitive with other storage systems (<200€/MWh), given its simplicity. • A novel district heating network integration with methanol TCES is proposed. • Round-trip above 65 % and an overall efficiency of 11.6 % were achieved. • Analysis of presented DH-TCES in 499 rural municipalities in Spain. • Competitive levelized storage price values of €150/MWh was obtained. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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