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In the background region of the Tibetan Plateau (TP), the rapid urbanization probably results in the massive generation of persistent organic pollutants (POPs), which lacks monitoring and evaluation. Since landfill could serve as an important sink of the locally used POPs, the analysis of POPs in the Tibetan landfill area might help us to understand the source composition and their transport in the TP. In this study, the concentration variations of polybrominated diphenyl ethers (PBDEs) in five soil profiles and seven surficial sediments around the largest Tibetan landfill were investigated. The total concentrations of PBDEs ranged from 128 to 1219 ng/kg in soils, and from 447 to 7295 ng/kg in sediments. The dominance of nona- and deca-BDEs possibly indicated the wide usage of deca-BDE as flame retardant in the TP. The vertical and spatial distribution patterns of PBDEs within soils plausibly revealed their main transport pathways by atmospheric dispersion and leachate seepage from landfill. Based on principal components analysis and multiple linear regression, these two pathways were estimated to account for 61% and 39% of the total concentrations, respectively. Additionally, the spatial and vertical distributions of octa-to deca-BDEs within soils were significantly influenced by soil particle size. Although the PBDEs inventory in the study area was comparatively low, the rapid urbanization in the TP might dramatically accelerate the PBDE emissions in the future. This study firstly introduced the presence of local PBDEs in the TP, and the inventory already influenced the surrounding environment. Once involved in the regional cycle of the TP, the local source of PBDEs from waste might significantly serve to raise background level resulting otherwise primarily from long-range atmospheric transport., (Copyright © 2018 Elsevier Ltd. All rights reserved.)

The sedimentary core in remote alpine lakes has been recognized as an ideal proxy to reconstruct the emission and air deposition histories of persistent organic pollutants (POPs). Nevertheless, POPs formerly stored in a catchment might also contribute to the variation in the lake sediment by lateral remobilization. In this study, to reveal the relative importance of lateral remobilization, we measured the vertical profiles and isomeric ratios of dichlorodiphenyltrichloroethanes (DDTs), hexachlorocyclohexanes (HCHs) and endosulfan in a dated sedimentary core collected from Lake Yamzho Yumco in the southern Tibetan Plateau. In addition to the flux peaks in the 1970s corresponding to the heavy atmospheric deposition of DDTs and HCHs, these pollutants' fluxes displayed rebounds in the flood periods, with characteristic low ratios of DDT/DDE (α-/β-HCH). This might indicate a massive remobilization of "weathered" pesticides from catchment soil to the lake because of strong hydro-dynamics. Moreover, the relative contribution of lateral remobilization to the lake sediment in the past decades was recognized through the correlation between DDT/DDE (α-/β-HCH) ratios and ∑DDT (∑HCH) fluxes. The results showed that the lateral remobilization contributed to 20-42% of the total fluxes. This study discriminated the air deposition from the contribution of lateral remobilization, which improves current understanding of the vertical POPs profiles in the sedimentary core., (Copyright © 2017 Elsevier Ltd. All rights reserved.)

Glacier alluvial deposits record persistent organic pollutants (POPs) not only derived from the atmospheric deposition but also from the release of glacial melting. The evidence for melting glacier in the Tibetan Plateau (TP) as a secondary source of pollutants is introduced through investigating the concentration of organochlorine pesticides (OCPs) in four deposited profiles collected at the edge of the Changwengluozha glacier. Two concentration peaks were observed for dichlorodiphenyltrichloroethanes (DDTs) and hexachlorocyclohexanes (HCHs) in the past century. The first peak was observed in the 1970s, corresponding with the heavy usage of HCHs and DDTs in the surrounding countries and regions. The second one was in 2000 when the production and usage of DDTs and HCHs were strictly limited, which possibly indicated a significant release from melting glacier. This result was further supported by the enantiomeric fraction values for α-HCH and o,p'-DDT. On the other hand, the dramatic increase of polycyclic aromatic hydrocarbons (PAHs) from atmospheric deposition, which was associated with the socioeconomic development in Tibet, shaded the release of PAHs from melting glacier. This study reveals not only the air deposition history of legacy POPs but also a substantial release of OCPs from glacier to the adjacent environment. Our research supports the hypothesis that the melting glacier in the TP represents a secondary source of OCPs, which is consistent with the findings in the Alps glaciers., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

The fraction of trans-chlordane (TC) in chlordane was used to indicate racemic degradation while the enantiomer fractions (EFs) indicated enantioselective depletion. In 44 soils of the Central Tibetan Plateau, the fractions of TC ranged from 0.368 to 0.411. The EFs ranged from 0.174 to 0.696 for TC and from 0.483 to 0.672 for cis-chlordane (CC). (-) enantiomer excess (ee) was found to be 80.0% in the soils for TC and (+) ee was 86.5% for CC. The fraction of TC changed with the clay content while the EFs changed with the soil organic carbon. Meanwhile, the fractions of TC and the EFs were determined for the surficial sediments in Yamzhog Yumco Lake, which were compared with those in the soils at its catchment area. The composition and chiral signature of chlordane did not vary between soils and sediments. Our results will help to elucidate the transformation of chlordane in soils and in surficial transport., (Copyright © 2015 Elsevier Ltd. All rights reserved.)

Forty-four soil samples were collected across the central Tibetan Plateau (CTP) at altitudes between 3711 m and 5352 m, and their polycyclic aromatic hydrocarbons (PAHs) contents were measured to be from 0.43 to 26.66 ng/g. The main sources of PAHs were identified for each of four sub-areas, and their concentrations in soils were determined to be mainly influenced by local sources. Along a 600 km sampling trajectory from Lhasa, which served as the biggest local source, the concentrations of PAHs decreased logarithmically with increasing distances from the source. Meanwhile, the fractional proportions of PAHs were observed to change logarithmically according to the transport distances. Conclusively, PAHs from local sources were transported within the CTP and dominated PAHs concentrations in the soils, but few of them were transported outside the CTP. In global cycling, the soils in the CTP mainly serve as background and a "sink" for PAHs., (Copyright © 2015 Elsevier Ltd. All rights reserved.)

The soils in the Central Tibetan Plateau (CTP), which is a unique background region, play an important role in the fate of the global cycling of polychlorinated biphenyls (PCBs). Forty-four soil samples from across the CTP were collected at altitudes between 3711 m and 5352 m, and the concentrations of 122 PCB congeners were measured from 66.98 to 150.81 ng/kg. The concentration of PCBs was positively correlated with the sampling altitude and clay content. Furthermore, enantiomeric fractions (EFs) of CB-95, CB-136 and CB-149 in soils of CTP were first determined. A (+)-enantiomer excess was identified for CB-136 and CB-149 in all of the samples investigated. Additionally, enantiomer-specific excess was found for CB-95. The dominance of enantiomer-specific excess decreased with increased the sampling altitude and congener concentration. It is likely that the addition of enantiomeric mixtures of PCBs from the atmosphere changed the EFs in the soils according to the altitude.

Sixteen soil samples were collected from the central Tibetan Plateau (CTP). The soil concentrations of polybrominated diphenyl ethers (PBDEs) in CTP were analyzed. The detected 42 congeners were divided into light, intermediate and heavy fractions. In addition to the various minerals, other soil properties were also characterized, including the content of soil organic carbon (SOC) and the particle size distribution. The clay content is positively related to the intermediate fraction of the PBDEs and negatively related to the light and heavy fractions. Similar correlations were observed for SOC and the fine-particle fraction (size < 2 μm). The coefficient of determination (r(2)) associated with a linear regression indicated that the clays were more highly correlated with the fractional pattern of the PBDEs than with the other properties, such as SOC and the fine-particle fraction. The values of r(2) between clays and three fractions of PBDEs are 0.70, 0.69 and 0.58., (Copyright © 2012 Elsevier Ltd. All rights reserved.)