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The occurrence of boron in low concentration is essential; however, a higher concentration of boron source in water has a toxic effect on humans as well as have retard effect on agricultural plant growth. Thus, the affordable and facile method to remediate water from higher boron concentrations is highly demanded. This report explores the ability of naturally occurring sustainable bio-waste os sepiae (cuttlefish bone, CFB) as an effective adsorbent for the removal of boron from water. Chemical activation of the os sepiae powder was examined to improve the efficiency of boron adsorption. A batch adsorption study for boron considering various parameters such as chemical modification of os sepiae, pH, initial boron concentration, and the temperature was scrutinized. Untreated (CFB), alkali-treated (CFB-D) and acid-treated (CFB-A) os sepiae powders were investigated and the adsorption capacities reached up to 53.8 ± 0.04 mg/g, 66.4 ± 0.02 mg/g and 69.8 ± 0.02 mg/g, respectively, at optimal pH 8 and 25 °C. Boron adsorption by CFB, CFB-D, and CFB-A were well fitted with the linear Freundlich adsorption isotherm model with a correlation coefficient of 99.4%, 99.8%, and 99.7% respectively. Thermodynamic parameters indicated that the adsorption of boron by CFB is an exothermic process and more feasible at a lower temperature around 25 °C. Moreover, detailed morphological and chemical characterization of the influence of adsorbed boron on adsorbents was conducted and discussed. The Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analysis spectra confirms the involvement of various functional groups including amino, carbonate (CO3)2−, and hydroxyl groups on the adsorbent in the adsorption mechanisms for boron removal. The results indicate that CFB can be an excellent example for the recycling and reuse of biowaste for water remediation. [ABSTRACT FROM AUTHOR]

The goal of this study was to evaluate the impact of using yeast wastewater (YW) on weed communities. The study showed that all ecological parameters including species richness, dispersion, density, frequency, and % of vegetation cover were significantly increased in the site irrigated with YW compared to a natural rain fed site and another site irrigated with fresh water. The vegetation cover (%) was significantly increased by 2-folds in the site irrigated with YW (52%) than the one irrigated with fresh water (27%). Species richness increases to 23 in the site irrigated with yeast wastewater compared to 12 species in natural rain fed site and 7 species in areas irrigated with fresh water. The 10 studied weed species germinated better at 10 and 20% dilutions of baker's YW. However, only five species achieved few germination (3-25%) at 50% of YW and the two species Sisymbrim irio and Cardariia droba achieved (6-13%) germination using 100% YW. No germination occurred for the crop seeds (tomato, squash, lentil, and barley) at 50 and 100% YW. For tomato, 10 and 20% of YW achieved better germination (82 and 63%, respectively) than the seeds of other species, followed by barley with 80 and 53% of germination. Squash showed the lowest germination percentage with 59 and 42% at 10 and 20% of YW, respectively. Yeast wastewater seems to be crop specific and can affect weed species composition and relative abundances and care should be taken before using the effluent for irrigation of tree plantations and crops. [ABSTRACT FROM AUTHOR]