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Abstract: The distribution of dissolved (soluble and total) and particulate (leachable and total) aluminum was examined in the Columbia River and estuary, in near-field and far-field river plumes, and in adjacent coastal waters of Washington and Oregon during the River Influence on Shelf Ecosystems (RISE) cruise of May/June 2006. Dissolved and particulate aluminum (Al) concentrations were significantly greater in the river than in the coastal waters that mixed to form the plume. Dissolved Al concentrations in the Columbia River (∼80nM) were low relative to other major rivers. Leachable and total particulate Al concentrations within the river reached concentrations greater than 1000nM and 18,000nM, respectively. Dissolved Al within the Columbia River estuary showed a significant removal (∼60%) at salinities between 0 and 10 with salt-induced flocculation of colloidal Al complexes and enhanced particle scavenging being probable explanations for aluminum removal. Dissolved and particulate Al concentrations were significantly greater in near-field plumes relative to surrounding coastal waters. As the plume advected from near-field to far-field away from the river mouth, dilution of the plume with lower dissolved Al surface waters as well as particle scavenging along the flow path appeared to be controlling dissolved Al distributions. Particle settling as well as dilution with lower particle-load waters led to observed decreases in particulate Al as the plume moved from near-field to far-field. However, the percent-leachable particulate aluminum in both near-field and far-field plumes was remarkably constant at ∼7%. Dissolved and particulate Al in a far-field plume over 100km southwest of the Columbia River mouth were over an order-of-magnitude greater than surrounding waters, illustrating the importance of the Columbia River plume as a mechanism for transporting Al offshore. Aluminum could be used to trace the input of biologically-required elements such as iron into waters off the shelf. [Copyright &y& Elsevier]

Abstract: This study examines the distribution of leachable particulate iron (Fe) in the Columbia River, estuary, and near-field plume. Surface samples were collected during late spring and summer of 2004–2006 as part of four River Influence on Shelf Ecosystems (RISE) cruises. Tidal amplitude and river flow are the primary factors influencing the estuary leachable particulate Fe concentrations, with greater values during high flow and/or spring tides. Near the mouth of the estuary, leachable particulate Fe [defined as the particulate Fe solubilized with a 25% acetic acid (pH 2) leach containing a weak reducing agent to reduce Fe oxyhydroxides and a short heating step to access intracellular Fe] averaged 770 nM during either spring tide or high flow, compared to 320 nM during neap tide, low flow conditions. In the near-field Columbia River plume, elevated leachable particulate Fe concentrations occur during spring tides and/or higher river flow, with resuspended shelf sediment as an additional source to the plume during periods of coastal upwelling and spring tides. Near-field plume concentrations of leachable particulate Fe (at a salinity of 20) averaged 660 nM during either spring tide or high flow, compared to 300 nM during neap tide, low flow conditions. Regardless of tidal amplitude and river flow, leachable particulate Fe concentrations in both the river/estuary and near-field plume are consistently one to two orders of magnitude greater than dissolved Fe concentrations. The Columbia River is an important source of reactive Fe to the productive coastal waters off Oregon and Washington, and leachable particulate Fe is available for solubilization following biological drawdown of the dissolved phase. Elevated leachable Fe concentrations allow coastal waters influenced by the Columbia River plume to remain Fe-replete and support phytoplankton production during the spring and summer seasons. [Copyright &y& Elsevier]