1. Kinetics‐Controlled Synthesis of {100}‐Facet‐Enclosed Gold Quasi‐Square Nanosheets with Curved Edges.
- Author
-
Zhou, Jing, Jia, Qinglei, Zhang, Gongguo, Zhang, Haifeng, Zhao, Na, and Zheng, Yiqun
- Subjects
NANOSTRUCTURED materials ,OXIDATION of methanol ,GOLD nanoparticles ,TRANSMISSION electron microscopy ,CHEMICAL kinetics - Abstract
We report the preparation of gold (Au) nanosheets with a quasi‐square morphology and curved edges (Au QSNSs). The atomic packing on the edge, corner, and central part of an individual Au QSNS is carefully observed via spherical aberration corrected high‐resolution transmission electron microscopy, and the atomic‐resolution images confirm the dominant presence of {100} facets on all these regions. Such type of two‐dimensional nanostructure is of great interest, as conventional gold nanoplates/nanoprisms are mainly enclosed with {111} facets on upper/bottom faces. The use of glutathione and octadecyltrimethylammonium chloride as the shape‐directing agent and the capping agent, respectively, at appropriate amounts, together with a dropwise addition of Au precursor at controlled rate, have been validated to be crucial for the formation of such a unique two‐dimensional nanostructure. When acting as electrocatalysts for the methanol oxidation reaction in alkaline medium, the Au QSNSs/C exhibited noticeable enhancement, compared to spherical counterparts, in terms of mass activity, reaction kinetics, and long‐term durability, demonstrating their structural advantage. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF