1. The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs
- Author
-
Dapeng Lu, Qiang Huang, Shengda Wang, Jinyi Wang, Pingsen Huang, and Pingwu Du
- Subjects
supramolecular chemistry ,fullerene guest ,non-fullerene guest ,carbon nanohoop ,cycloparaphenylene ,Chemistry ,QD1-999 - Abstract
Cycloparaphenylenes (CPPs) and their analogs have recently attracted much attention due to their aesthetical structures and optoelectronic properties with radial π-conjugation systems. The past 10 years have witnessed a remarkable advancement in CPPs research, from synthetic methodology to optoelectronic investigations. In this present minireview, we highlight the supramolecular chemistry of CPPs and their analogs, mainly focusing on the size-selective encapsulation of fullerenes, endohedral metallofullerenes, and small molecules by these hoop-shaped macrocycles. We will also discuss the assembly of molecular bearings using some belt-persistent tubular cycloarylene molecules and fullerenes, photoinduced electron transfer properties in supramolecular systems containing carbon nanohoop hosts and fullerene guests, as well as the shape recognition properties for structure self-sorting by using dumbbell-shaped dimer of [60]fullerene ligand. Besides, the supramolecular complexes with guest molecules other than fullerenes, such as CPPs themselves, iodine, pyridinium cations, and bowl-shaped corannulene, are also discussed.
- Published
- 2019
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