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The interaction between flue gas and ash causes the redistribution of heavy metals and affect their emission characteristics. In this study, a double-layer fixed-bed reactor was used to investigate the effect of this interaction on Pb distribution at 800–1000 °C. Obvious gaseous Pb adsorption by ash just occurred in the case of high-Pb flue gas and less ash melting. In other cases, significant Pb release from ash occurred under the action of the high-temperature flue gas. The occurrences of Pb in ash was found to be thermally stable. Ash melting is the main reason for the Pb release. Gaseous Na in the combustion flue gas and reducing components in the pyrolysis flue gas promote the Pb release via promoting the ash melting. H 2 S and HCl in the pyrolysis flue gas also promote the Pb release by forming PbS and PbCl 2 , which are more volatile. [Display omitted] • The interaction between high-temperature flue gas and ash redistributes Pb. • Ash melting causes the significant release of Pb from ash at high temperatures. • Gaseous Na and reducing components in flue gas promote ash melting and Pb release. • H 2 S/HCl in flue gas also promotes Pb release by forming volatile PbS/PbCl 2. [ABSTRACT FROM AUTHOR]

Transformation of As in the post-combustion zone has a significant effect on its emission characteristics. In this study, redistribution of As that occurs during the interaction between flue gas and ash has been elucidated using a double-layer fixed-bed reactor at 800–1000 °C. Herein, flue gas and ash samples with different As contents and inorganic components were produced by two varieties of coals. The As content in the ash with high Ca and Al contents increased after interacting with the flue gas with a high As content, indicating gaseous As adsorption. However, the As content in the ash decreased by up to 67% for other cases. The blank experiments showed that the As occurrences in ash were thermally stable, suggesting that the decrease was caused by the action of flue gas. Accordingly, the effect of flue gas components on the release of As from the ash was investigated. It was found that a significant amount of As release was primarily caused by the reaction of gaseous Na in the flue gas with the residual As in ash. A bi-directional interaction was observed between the high-temperature flue gas and ash, which led to the redistribution of As. Unlabelled Image • Interaction between high-temperature flue gas and ash caused As transformation. • Ash with high Ca and Al contents obviously adsorbed gaseous As in the flue gas. • Gaseous Na promoted the residual As release via reaction with aluminosilicate. [ABSTRACT FROM AUTHOR]