Search

[Display omitted] • In soil, adsorption of FA is limited by the binding to external surfaces of nano-aggregates. • The overall adsorption of FA is pH independent and has a relatively low affinity. • In acid soils, FA prefers direct interaction with soil oxide particles, releasing phosphate. • NOM-oxide interaction can be reduced by soil liming, decreasing the solubility of oxyanions. • A dual-phase model is developed to describe the release of PO 4 upon FA addition. For more insight into the interaction of natural organic matter (NOM) with metal (hydr)oxides and oxyanions, the adsorption of added fulvic acid (FA) and the corresponding release of phosphate (PO 4) were studied for a series of agricultural soils (∼0 – 25 cm), strongly varying in soil properties. Interpretation of the data with surface complexation modeling using the NOM-CD model applied in a dual-phase mode shows that the adsorption of added FA, in contrast to PO 4 , is restricted to the external surfaces of nano-aggregates. The adsorption is relatively weak and pH-independent, due to its competition with the native NOM of the organo-mineral phase. At low pH, the functional groups of both added FA and native NOM shift in the interface towards the soil oxide surfaces, making both a good competitor for adsorbed phosphate, resulting in a higher amount of phosphate being released. With an increase in pH, the competition becomes weaker. As a result, more phosphate is bound and less is released when FA is added. Our surface complexation modeling points to the existence of organo-mineral nano-aggregates with sizes of >∼10 – 270 nm, which depends on the total reactive surface area of the soil. Our findings imply that organic amendments containing FA equilibrate with only a portion of the total reactive surface area. In acidic soils, the addition of such organic amendments will be more effective in solubilizing phosphate, which is beneficial from a plant nutrition perspective, but simultaneously it may also contribute more to environmental eutrophication. [ABSTRACT FROM AUTHOR]

[Display omitted] • 5 RDs neutralise 500 up to 10 000 mmol H+/kg, variation in mineralogy and target pH. • Automatic titration (pH stat) estimates pH-dependent dissolution rates and slopes. • Novel soil-RD suspension estimates fast/slow pools of acid neutralising capacity. • Low and high doses (12 Mg/ha, 340 Mg/ha) for validation in 2 year soil-RD mesocosm. • Mechanistic model using pH stat and soil-RD suspension predicts mesocosm soil pH. The ongoing acidification of soil poses a significant threat to the proper functioning of various ecosystems worldwide. Silicate rock dusts (RD) are increasingly amended to acid soils to restore their pH, but the acid neutralising capacity (ANC) and dissolution rate of these products are highly variable and lack proper assessment protocols. It is expected that pH-dependent RD ANCs and dissolution rates dictate the pH increase in soils depending on the initial pH and pH buffer power of the soil. This study addressed these questions by comparing and validating three accelerated weathering tests for their capacity to predict the gradual liming effects in a two-year outdoor mesocosm. Five commercial RDs (two basalts, phonolite, foidite, and trachy-andesite) were tested in four acidified forest soils varying in initial pH, in texture and associated pH buffer power. First, RD dissolution was measured in aqueous batch renewal systems during one year at various starting pH (3.5, 4.5, and 5.5) and constant temperatures (20 °C, 37 °C, and 65 °C). These showed that the ANCs of RDs exhibit a fast fraction (half-life < 1 day) followed by a slower fraction. Second, titration tests of RDs at fixed solution pH, i.e., pH stat , performed between pH 3.5 and 4.5 revealed surface normalised dissolution rates that decreased factors 10–100 per unit pH increase, the slope depending on the RD's mineralogy. Indeed, the rate ranking of observed surface area normalised dissolution rates confirmed that of literature-based values, weighed by the XRD-derived mineralogical fractions. Third, lime-calibrated agitated soil-RD suspension tests were conducted for two months, illustrating the dependency of RD ANC on soil context, and yielding ANCs that were factor 2–5 times larger than in the batch renewal test because of pH buffering effects of soil particulates. Finally, an outdoor soil mesocosm on the four acid soils amended with RDs at 12 Mg/ha and 340 Mg/ha was established and soil pH was monitored for 2 years. The observed pH trends corresponded well for both the low dose (R2 a = 0.67) and the high dose (R2 a = 0.93) with model predictions made using the pH- and temperature-dependent RD dissolution rates (pH stat test) and the soil pH buffer power and RD slow ANC-fraction (soil-RD suspension test). This model predicts half-lives of RD dissolution ranging between <1 month to >100 years depending on the starting pH of the soil, its pH buffer power, the RD mineralogy (XRD based) and its specific surface area. This study shows that the dissolution and ANC of RD can be most pragmatically predicted with a series of lime-calibrated soil-RD suspension tests of maximally two months. [ABSTRACT FROM AUTHOR]

[Display omitted] • No-liming decreased approximately 30% of P use efficiency in CT and NT systems. • The use of NT increased P use efficiency by about 10–12% compared to the CT system. • NT without lime resulted in the highest P legacy but was non-accessible due to high Al3+. • Soil P forms and P use efficiency in NT and occasional tillage systems were similar. • Liming with soil incorporation effects persists for four decades, enhancing P use by crops. Liming combined with no-tillage (NT) can increase the efficiency of P use by accumulating soil P in more available forms and improving root exploration due to the absence of toxic Al3+. This study aimed to evaluate the long-term effect of different combinations of soil tillage managements and liming in a subtropical Oxisol on the accumulation of P forms, legacy P index, and P use efficiency. A long-term experiment was used, established in 1987 testing (i) conventional tillage with lime (lime-CT) and control (control-CT), (ii) NT with lime (lime-NT) and control (control-NT), and (iii) occasional tillage with lime (lime-OT). The NPK fertilization was the same for all treatments. The accumulated grain yield and P use efficiency of 56 crops between 1987 and 2019 were evaluated. In 2019, soil samples were collected in the 0–5, 5–10, and 10–20 cm layers and submitted to a sequential chemical fractionation of P, P indexes, and soil acidity parameters. The results reveal that is necessary to correct acidity to increase crop yields and P use efficiency, regardless of the soil management used. This increase is enhanced when soil acidity correction by liming is combined with the use of conservation systems such as NT. Furthermore, after liming with incorporation, liming can be done on the soil surface, without the need to repeat the operation of lime incorporation, ensuring high efficiency of P use even after more than four decades. [ABSTRACT FROM AUTHOR]

• Silicate-containing amendments increased calcium and available silicate contents. • Silicate-containing amendments moderately increased soil fertility. • Silicate and lime co-application increased the relative change in soil fertility. • Long-term application of silicate and lime reduced C stratification. • Carbon stocks reduced in lime and silicate amended soils. Most agricultural soils are unproductive due to soil acidity which limits crop growth and yield. To ameliorate soil acidity constraints and enhance the ecosystem services the soil renders to achieve optimum crop yields, lime, and silicate are mostly used. However, there are few studies reporting the impacts of the combined application of silicate and lime on soil properties, soil fertility and carbon stocks and stratification in long-term experiments. This study evaluated the impacts of the combined application of silicate and lime on soil fertility indicators (pH, soil organic matter (SOM), available phosphorus, exchangeable potassium, magnesium, and calcium, and available SiO 2), carbon stratification and stocks in comparison to sole lime and sole silicate applied to a Fluvaquentic Eutrudepts over a 67-year period. Each treatment's rate of application was calculated to raise the soil pH to 6.5. Incorporation of the treatments increased the soil pH by 1.30, 1.22, and 1.35 folds in the sole silicate, sole lime, and combined silicate and lime-treated soils, respectively, relative to the baseline soil pH (5.5). The combined application of silicate and lime resulted in significant decreases in C stratification and C stocks. The significant reduction in the C stocks in the silicate and lime-treated soils implies that its long-term application could potentially reduce carbon sequestration and increase the carbon footprint of rice cultivation. This information is crucial to develop sustainable soil management interventions to curtail the environmental footprint in rice paddy ecosystems. Comparatively, the combined silicate and lime treatment caused an increase in the relative change of soil fertility by 65.7% and the average annual growth rate in the soil fertility improvement by 0.0115, as compared to the untreated soil. Among the soil variables, soil pH, exchangeable calcium, and available silicate contributed most to the variation the soil fertility. The obtained results could serve as a guide in revising the lime and silicate fertilization programs instituted by the Korean Government and reviewing national soil fertility management systems in temperate paddy ecosystems. [ABSTRACT FROM AUTHOR]

• Liming and labile C addition interacted to affect N 2 O emission. • Liming reduced N 2 O emission by 13–28% compared to unlimed soil following labile C addition. • Liming reduced the Q 10 of N 2 O following labile C addition. • Labile C addition facilitated denitrification. • N 2 O emission was positively related to (nirK + nirS)/(nosZI + nosZII) ratio and NO 3 − consumption. Lime has been widely applied for ameliorating soil acidification, potentially improving soil fertility and crop production. However, the long-term effects of liming and its interaction with carbon (C) availability on the emission and temperature sensitivity (Q 10) of greenhouse gas nitrous oxide (N 2 O) from acidic arable soil are not well understood. Here, the limed and unlimed acidic soils collected from a long-term field trial, amended with and without glucose as labile C, were incubated at 15℃ and 25℃ to investigate the responses of the emission and Q 10 of N 2 O and the underlying mechanisms. Results showed that liming had no effect on N 2 O emission without labile C addition. While after labile C addition, N 2 O emissions were 13–28% lower in the limed relative to unlimed soils, indicating that the mitigation effect of liming on N 2 O emission can mainly be seen when labile C (e.g., from rhizodeposition) is highly available in soils. High temperature did not affect N 2 O emissions from soil without labile C addition, but greatly increased N 2 O emissions after labile C addition with significantly lower Q 10 of N 2 O in the limed (1.23) relative to unlimed soils (1.48). These results suggested that liming could decrease the Q 10 of N 2 O emission in the presence of labile C. Elevated soil pH by liming caused increases in the abundances of N 2 O reductase genes (nosZI and nosZII) over nitrite reductase genes (nirK and nirS), thus significantly lowering (nirK + nirS)/(nosZI + nosZII) ratio compared to the unlimed soil, particularly after labile C addition. Soil N 2 O emissions were strongly positively related to the nirK abundance, (nirK + nirS)/(nosZI + nosZII) ratio, and NO 3 − consumption after labile C addition, indicating that denitrification was mostly responsible for N 2 O emission. Concluding, long-term liming could potentially reduce N 2 O emission and its Q 10 via decreased (nirK + nirS)/(nosZI + nosZII) ratio in acidic soils in the presence of labile C. [ABSTRACT FROM AUTHOR]

In paddy soils, plant availability of phosphorus (P) increases during the flooding period due to the reductive dissolution of iron (Fe)-bearing minerals on which P is sorbed. Soil chemical properties are a determining factor of P availability and are subject to change after prolonged paddy rice cultivation. The purpose of this study was to evaluate the effects of long-term application of rice straw compost and slaked lime on changes in soil chemical properties, particularly focusing on the increase in available P under reductive conditions. The rice cultivation experiment was launched in 1926 to clarify the effects of mineral fertilizer (NPK), rice straw compost, and slaked lime application on soil properties. The amount of P solubilized under reductive conditions was evaluated by the difference in the P extracted by the Bray II method with and without reductive treatment of the soil. Continuous application of NPK mineral fertilizer without slaked lime resulted in higher amounts of aluminum extracted by acid ammonium oxalate and P extracted by the Bray II method until the 92nd cropping, while the increase in the proportion of available P under reductive conditions was low. In contrast, the amounts of Fe extracted by acid ammonium oxalate and P solubilized under reductive conditions were higher with increasing application of compost. The application of the compost caused strongly reductive conditions in the soil during the flooding period, and the dissolution of P in the Fe-bound fraction was facilitated. However, excessive application of compost led to the dissolution of high amounts of Fe-bound P, resulting in a loss of Fe and P from the cultivated soil. These results suggest that excessive application of rice straw compost and no application of slaked lime may cause a decrease in available P in paddy soils. [ABSTRACT FROM AUTHOR]

• Accurate and rapid method to measure low concentrations (>0.5%) of inorganic carbon established. • Detection and prediction of inorganic carbon can be used to measure agricultural lime in soils. • Various lime sources can be detected and measured in different soil types and depths. • This method can be used to monitor lime movement and assist with management of acidic soils. • Infrared Spectroscopy approach is a viable alternative to traditional laboratory methods. Globally, surface and subsurface soil acidity pose a serious threat to crop production and require effective management to prevent yield losses. The application of lime (calcium carbonate, CaCO 3) is a well-recognised remediation technique for surface soil acidity. However, for subsurface acidity, improved application and detection methods are required to manage acidity due to the stratification of acidic layers. Mid infrared (MIR) spectroscopy has potential as a rapid, cost effective and accurate method of CaCO 3 detection in soils. However, for this technology to be valuable in an agricultural context, there is a need to develop MIR spectroscopy methods for the detection of CaCO 3 at agriculturally relevant concentrations of <1%, which was the aim of this study. MIR Partial Least Square Regression (PLSR) carbonate prediction models were developed using carbonate-specific spectral regions to predict CaCO 3 concentrations in soil. Prediction models were initially developed using a single soil type spiked with reagent grade CaCO 3 and were tested further with soils collected from field trials that had been treated with various rates and sources of lime. Prediction models using specific carbonate peak regions were established and compared with models using the entire MIR spectrum to assess the model performance. Models built using a single peak range at 2560–2460 cm−1 gave the best results (highest R2 values and lowest RMSE values) followed by the single peak range at 1840–1760 cm−1. Specifically, model performance was improved when developed with a single soil type and reagent grade CaCO 3 in the 2560–2460 cm−1 spectral region, with PLSR R2 of 0.834 and RMSE of 0.030. Performance was reduced but still satisfactory (R2 of 0.735 and RMSE of 0.069) when applied to field trial soils using a range of different lime sources, including dolomitic lime. The MIR method enabled accurate prediction of carbonate concentrations and had a detection limit of 0.05% CaCO 3 , similar to what can be achieved using a pressure calcimeter. Findings suggest that MIR spectroscopy measurements of agriculturally applied CaCO 3 in soils may provide valuable insights into monitoring the movement and efficacy of lime treatments and will enable more informed lime applications in the future. The method may also be used to detect naturally-occurring carbonates at low concentrations and may be useful for rapid isolation of inorganic carbon from organic carbon in soil carbon measurements and carbon accounting. [ABSTRACT FROM AUTHOR]

• Lime addition impacts organic matter (OM) preservation in both top- and sub-soil. • Lime addition destabilizes N-poor OM associated with minerals in the topsoil. • The effect of lime on OM decomposition with depth depends on the OM availability. The development of effective strategies to maintain/increase soil C is hindered by the poor process-level understanding of the impact of management practices on C preservation, particularly at different soil depths. Based on the distinct biogeochemistry existing across a soil profile, a depth-dependent response of organic matter (OM) to soil amendments was hypothesized. To test this, we investigated the effect on OM preservation of lime addition to the topsoil and the subsoil of a volcanic soil classified as Andosol – the mineral soil with the largest organic C content worldwide. We incubated samples from each soil layer with (or without) lime addition, in the presence or absence of 13C- and 15N-labeled plant residue (simulating plant C inputs to the soil). The fate of OM in bulk soil and OM-mineral associations of microaggregates was measured using conventional chemical analyses and nano-scale secondary ion mass spectrometry, respectively. The results revealed contrasting geochemical properties existing within the soil profile, i.e. pH and amount of allophane increasing with soil depth. Functional complexity of OM also increased with depth, as revealed by an increase in spatial and molecular heterogeneity of OM, i.e. a larger proportion of microbial-derived OM with high spatial separation found in the subsoil. Lime addition caused OM destabilization as denoted by the increase in the amount of water-extractable C in both the topsoil and the subsoil (P < 0.05). In the topsoil, OM coverage of mineral surfaces decreased with liming from 49% to 30% whereas the opposite was observed in the subsoil, where it increased from 23% to 29%. Thus, liming caused the disruption of OM-mineral associations within microaggregates in the topsoil, but not in the subsoil. We infer that, at depth, the OM destabilization involved the mobilization of OM previously protected within macroaggregates. This pulse of labile C generated an advantageous environment for microbial OM mineralization in the subsoil, but this effect was diluted in the topsoil, richer in OM and where OM functional complexity is smaller. Depth-dependent soil geochemical properties and functional complexity determine differences in the effect of liming on the fate of soil OM in top vs. subsoils. [ABSTRACT FROM AUTHOR]

• Low-lability S contents in soil decreased with depth. • Ca-phosphate extractable S contents increased with depth after surface application of phosphogypsum. • Sulfate adsorbed to hematite was the main oxidized inorganic S-species. Sulfur (S) is present mainly in organic forms in the most superficial layers of well-drained soils, despite sulfate (SO 4 2−) being the main S-species absorbed by plants. Coupled broadcast application of lime and phosphogypsum (PG) is widely deployed as an agricultural practice to improve soil chemical properties and increase crop yields in highly weathered tropical soil areas under no-tillage system (NTS). However, the effects of large-scale application of these soil amendments to S-species distribution in soil in NTS are largely unknown. We combined S wet-chemical analysis with Synchrotron-based X-ray Absorption Near-Edge Structure Spectroscopy (XANES) to evaluate the effects of lime and PG application to S-species distribution along the soil profile (up to 150 cm). Soil samples were collected from a field-scale experiment under NTS for over 15 years. Soil was amended with lime and PG, either individually or in combination, four times during the experiment. Soil sampling was conducted 16 months after the last amendments' application, and treatments (lime, PG and lime + PG) were compared to a control (under NTS without amendments' application) and with soil samples from a native forest (reference for an undisturbed site). Broadcast PG application increased the contents of Ca-phosphate extractable S and pseudo-total S (microwave assisted acid digestion) contents in the deeper layers. Two peaks representing reduced and oxidized S species were detected in S K -edge XANES spectra of all treatments and NF soil. The oxidized S peak gets sharper with increase in depth, as reduced S peak intensity decreases, and fingerprint analysis suggested a greater contribution of reduced organic S species in the most superficial soil layer followed by an increase in highly oxidized S species as depth increased. Linear combination fitting analysis confirmed a greater contribution of highly oxidized S species to the total S-species as depth increased, especially in soil samples that received PG application. [ABSTRACT FROM AUTHOR]

• Data fusion did not significantly improve soil attributes prediction. • Clay, SOM, and CEC were better predicted than chemical soil attributes. • Even 1 sample per 0.25 ha were not sufficient to accurate map soil chemical attributes. • However, 1 sample per ha is adequate to map clay, SOM, and CEC. Precision agriculture aspires to manage the soil spatial variability within a field. However, agricultural practices can decrease the spatial autocorrelation of soil properties at a short distance, which requires an increase in sampling density to improve the reliability of interpolated surfaces. Data fusion of several soil spectrometers is a promising alternative that can increase knowledge about soil physicochemical variability. Therefore, this research aimed to evaluate whether the synergy of portable X-ray fluorescence, Vis-NIR, and Mid-Infrared spectrometers can successfully increase sampling density and improve the quality of the soil attribute maps, in a high fertilization management study area. We conducted a case study on a sugarcane field in Southeast Brazil. Our spectral data fusion approach did not increase the prediction performance for soil properties, achieving the same accuracy (α ≤ 5%) of the single spectral ranges (Vis-NIR or MIR or pXRF) individually. Thus, Vis-NIR was chosen to evaluate if spectroscopy could improve soil properties prediction and mapping. We used three dataset scenarios to build soil property maps: two were based on soil wet-chemical laboratory analysis using 1 sample per ha, and 1 sample per 0.25 ha and a third used a spectroscopy model with 0.25 samples per ha calibrated using soil wet-chemical laboratory analysis at the rate of 1 sample per ha. In a field with strong anthropic influences, due to liming and soil fertilization, Vis-NIR spectroscopy cannot predict well the amount of phosphorus and pH at a sampling density of 1 sample per 0.25 ha. Increased soil sampling enhances soil mapping accuracy only for chemical properties (e.g., potassium) that are correlated with soil texture. Nevertheless, soil spectra can classify areas of similar soil texture and help farmers with the site-specific management of crops. [ABSTRACT FROM AUTHOR]