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Cretaceous through Eocene plutonic rocks in northeastern Washington, USA, document a 60 m.y. history of crustal thickening and subsequent collapse and extension in response to two terrane-accretion events. Rocks emplaced 113-53 Ma have increasing La/Yb ratios reflecting orogenic plateau development after arrival of the Insular terrane by 100 Ma. Plutons emplaced 52-45 Ma (the Challis episode) document collapse of this plateau and define a SW-younging age progression attributed to breakoff and rollback of the Farallon slab following accretion of the Siletzia terrane at ca. 50 Ma. All of the rocks have chemical traits of arc magmas, likely inherited from their lower-crustal sources, but low B/Be ratios and the lack of evidence for amphibole fractionation indicate the Eocene magmas formed under drier conditions than are typical of active subduction settings. These magmas also originated at greater depth (eclogitic vs. gabbroic source) and were emplaced more shallowly than the earlier ones. All rocks have overlapping Sr-Nd and O isotopic data, indicating significant contributions from older continental crust, and depleted mantle Nd model ages become older toward the east, defining three regions that correspond with previously inferred lowercrustal domains. Farallon slab rollback also drove extension (core complex formation, dike swarms) and crustal uplift, which, along with voluminous magmatism, define the Challis episode. This tectonic model is further supported by seismic tomography, which has identified remnants of a detached slab in the upper mantle beneath the region. [ABSTRACT FROM AUTHOR]

The distribution of Oligo--Miocene magmatic rocks from southern Tibet in space and time yields critical information on the geometry and deformation of the subducted Indian lithosphere which impacts on plateau growth following the India and Eurasia collision. A growing body of geophysical evidence has shown that the subducted Indian lithosphere beneath the Tibetan Plateau has been torn apart. However, the spatiotemporal distribution and cause of the tearing remain enigmatic. Timing of the post-collisional magmatic rocks in southern Tibet exhibits four patterns of decreasing ages; magmatism began earlier in the west and east Himalayan syntaxis and evolved to two age undulations in the central southern Tibet. Seismic images show that regions of slab window (both 90°E and 84°E) and flattened subducted lithosphere (both 86°E and 81°E) are present at depth of 135 km. Correspondingly, increasing mineral crystallization temperatures (absolute value of 50 °C) were recorded in the Oligo--Miocene ultrapotassic-potassic rocks at 90°E and 84°E, while opposing trends were shown by coeval ultrapotassic-potassic rocks at 86°E and 81°E. Besides, the melting depth of the Oligo--Miocene ultrapotassic-potassic primitive melts decreases from nearly 100 km to 70 km between 81°E and 90°E, probably indicating progressive rising of the lithosphere-asthenosphere boundary. Such variations were possibly the results of the focused flow and upwelling of asthenosphere, which advanced rapidly but diachronously through weakened and torn sectors within the overlying Indian slab. The upwellings probably induced diachronously upward bending of the residual Indian slab and its flattening, which accelerated the tearing of the Indian lithosphere during continental subduction. [ABSTRACT FROM AUTHOR]

Recycling of Fe-rich materials through subduction may affect the element budgets and redox properties of the mantle, thus in- fluencing the differentiation trends and mineralization types of mantle-derived magmas. However, the effects of different recycled Ferich materials on the mantle are dependent on their lithologies, which are still poorly constrained. Stable Fe isotopes can act as useful tracers for distinguishing among different recycled Fe-rich lithologies, and their imprints may be documented in mantle-derived magmas. This study focuses on the Fe isotopes of ferrobasalts and the associated dacites and magnetite ores in the Chagangnuoer Fe deposit of the Awulale Arc, Central Asia, to identify recycled Fe-rich materials and explore the Fe enrichment mechanism in continental arcs. Our results indicate that the ferrobasalts and dacites possess the lowest known δ56Fe, -0.40‰ ± 0.04‰ (2SE), among their counterparts worldwide. The low δ56Fe signatures are considered to originate from a hybridized mantle source, which may have been modified by recycled ferrocarbonates. The recycled ferrocarbonates may have melted during the decompressional heating stage of the slab subduction of the South Tianshan Ocean, coupled with asthenospheric upwelling under "wet" mantle conditions. The addition of ferrocarbonate melts to the mantle might have decreased the oxygen fugacity of the mantle wedge to below the fayalite--magnetite--quartz buffer, accounting for the Fe enrichment in arc tholeiites and large-scale Fe mineralization along the Awulale. Notably, our study reveals a novel carbonate recycling pathway in the cold subduction zones, where ferrocarbonates were subducted into the mantle and then recycled by the upwelling asthenosphere to mix with the fluid-metasomatized mantle through mantle convection. [ABSTRACT FROM AUTHOR]

The late Paleozoic tectonic evolution of the Lhasa terrane and opening of the Sumdo Paleo-Tethys Ocean remain controversial due to limited data and the ambiguous tectonic significance of Paleozoic magmatism in the southern Lhasa subterrane. Here, we explore the petrogenesis of meta-basalt from the Tangjia area and meta-gabbro from the Sumdo area to provide new constraints on the evolution of the Lhasa terrane. The geochemical characteristics of meta-gabbro are similar to those of oceanic island basalt and have positive whole-rock εNd(t) values (+0.08 to +1.03) and zircon εHf(t) values (+3.4 to +4.9), which suggests that they originated from asthenospheric mantle with minor contributions from lithospheric mantle in an intracontinental rift setting. The meta-basalt yields positive whole-rock εNd(t) values (+6.47 to +6.60) and zircon εHf(t) values (+14.2 to +15.2) and has enriched mid-oceanic-ridge--like geochemical characteristics; we suggest that the meta-basalt was sourced from the depleted mantle and interacted with enriched components in an initial oceanic basin setting. Zircon U--Pb geochronology of meta-basalt and metagabbro yielded crystallization ages of ca. 338 Ma and ca. 345 Ma, respectively. We suggest that the Sumdo Paleo-Tethys Ocean opened in the early Carboniferous. Negative buoyancy of Paleo-Tethys oceanic slab during subduction toward Eurasia drove the opening of the Sumdo Paleo-Tethys Ocean. Given that the Sumdo Paleo-Tethys Ocean was a limited oceanic basin, the Lhasa terrane was not completely separated from the northern margin of Gondwana before the Permian. [ABSTRACT FROM AUTHOR]

Arc magmatism along convergent plate boundaries has been a major contributor to continental crustal growth. During the late Paleoproterozoic--Mesoproterozoic assembly of the supercontinent Nuna, following arc-backarc-continent collisions, the Makkovik Orogen, along the southern margin of the Archean North Atlantic Craton, experienced a pulse of continental arc magmatism at ca. 1800 Ma. Lithogeochemistry indicates compositions typical of ferroan, alkali to alkali-calcic, A-type granites. The granitic rocks have εNd(t) values varying from -5.3 to +2.0 and model ages [T(DM)] from 2750 to 1880 Ma. The very high εNd(t) and young model ages imply a substantial juvenile mantle component in their formation. Oxygen fugacity (ƒO2) ratios, estimated by the proxy ratio of FeOT/(FeOT + MgO), range from 0.58 to 0.99, indicating the parental magmas formed in both reducing and oxidizing conditions. The granites also preserve an alkali-calcic alteration that together with inferred ƒO2 makes them more prospective for a variety of intrusion-related styles of mineralization including iron-oxide-copper-gold and uranium. Based on the petrology, lithogeochemistry, and isotopic compositions, the ca. 1800 Ma magmatic event is interpreted to have been developed post-collisionally following the docking of the Cape Harrison Arc/micro-continent with the North Atlantic Craton during the assembly of the supercontinent Nuna. This collision was followed by slab rollback (possibly breakoff), extensional collapse, and mantle upwelling resulting in the generation of the abundant ca. 1800 Ma felsic magmatism. The timing of the ca. 1818-1799 Ma plutonism in the Makkovik Orogen is coeval with significant felsic plutonism preserved in the Julianehåb Igneous Complex (Ketilidian Orogen) of southern Greenland. [ABSTRACT FROM AUTHOR]

Differentiating between advancing and retreating subduction zones and delineating the timing and processes for switching between these end-member types are critical factors in understanding orogenic evolution. In this study, we used temporal composition variations and spatiotemporal distribution of igneous rocks to constrain the types and directions of the subduction zone beneath the Lhasa terrane in southern Tibet during the mid-Mesozoic. Comprehensive geochronological and geochemical data from mid- Mesozoic magmatic rocks in five areas of the central Lhasa terrane document two compositionally distinct magmatic suites: older (ca. 172-150 Ma) high-Mg diorite-granodiorite and younger (ca. 150-130 Ma) low-Mg granodiorite-syenogranite. The high-Mg rocks with enriched isotopes were likely generated by the mixing of Lhasa terrane basement- derived magmas with mantle-derived magmas that incorporated extensive contributions from subducted sediments. The low- Mg rocks with relatively depleted isotopes are interpreted as derived from a mixed lowercrust source (ancient basement and juvenile crust) with minor mantle contributions followed by crystal fractionation. Both high-Mg and low-Mg rocks show arc signatures and formed the 1200 km Shiquan-Zhegu-Menba arc. A combination of the Mesozoic geological and geochemical data suggests that both the Neo-Tethyan and Bangong Tethyan slabs were likely subducting beneath the Lhasa terrane, creating two opposing subduction zones. The change from high-Mg to low- Mg magmatism within the Shiquan-Zhegu- Menba arc likely records a tectonic switch from advancing to retreating subduction of the south-dipping Bangong Tethyan slab. Our results provide a good example for identification of subduction polarities and types of ancient orogenic belts through spatiotemporal distributions and changes in geochemical compositions of igneous rocks. [ABSTRACT FROM AUTHOR]

The tectonic mechanisms that may trigger a transition from calc-alkaline to alkaline volcanic activity above a subduction zone are enigmatic. We report major/trace elemental and Sr-Nd-Ca isotopic compositions of a suite of magmatic samples from the Miocene Gördes calc-alkaline dacites and the Quaternary Kula alkaline basalts from Western Anatolia, Turkey. Zircon sensitive high-resolution ion microprobe dating shows that the Gördes dacites formed at ca. 18 Ma. They are characterized by high-K calc-alkaline affinities, enrichment of light rare earth elements and large-ion lithophile elements (Rb, Th, U), positive Pb anomalies and negative Eu and high field strength element (HFSE) (Nb, Ta, and Ti) anomalies with high 87Sr/86Sri (0.70977-0.71010) and low εNd(t) (-7.3 to -7.0). They have small δ44/40Ca (0.59‰-0.69‰) values lower than that of mid-ocean ridge basalt (0.83% ± 0.11%). The Kula basalts exhibit alkaline affinities and are more enriched in incompatible elements (e.g., Rb, Ba, Th, Nb, Ta, Pb, and Sr) than those of typical oceanic island basalts. Their low 87Sr/86Sri (0.70307-0.70343) and high εNd(t) (+4.2 to +6.5) are consistent with an asthenospheric mantle source. Their δ44/40Ca values, ranging from 0.67‰ to 0.81‰, are higher than those of the dacites and lower than that of the bulk silicate earth (0.94‰ ± 0.10‰). Geochemical modeling suggests that variable degrees of partial melting of an asthenospheric mantle involving recycled oceanic crust may have resulted in low δ44/40Ca values of the Kula basalts. Combined with reported mantle tomographic images, we interpret that sub-slab asthenospheric mantle upwelling through a slab tear during subduction roll-back may have played a key role in the Sr-Nd-Ca isotopic variability from Miocene calc-alkaline dacites to Quaternary alkaline basalts in Western Anatolia. [ABSTRACT FROM AUTHOR]

The newly identified Neoproterozoic Yuanmou high-Nb mafic and adakitic rocks at the western margin of the Yangtze Block in South China are investigated for petrogenesis and geodynamic implications. Zircon U-Pb ages show the adakitic granodiorite host and mafic microgranular enclaves (MMEs) were synchronously emplaced at 811-806 Ma, and were cut by an 802 ± 11.5 Ma mafic dike. The medium-grained granodiorites consist mainly of plagioclase, quartz, K-felspar, biotite, and amphibole. High SiO2 (62.8-67.5 wt%), Al2O3 (13.1-16.8 wt%) contents, high Sr/Y (17.4-49.0), and (La/Yb)N (16.3-52.6) but low Y (6.83-16.1 ppm) and Yb (0.74-1.82 ppm) concentrations of the granodiorites point toward their calc-alkaline and adakitic nature. Further, their high Dy/Yb (1.52-2.31) and Gd/Y (2.35-4.43) and low K2O/Na2O (0.22-0.48) and Th/La (0.14-0.20) ratios, constant bulk rock εNd(t) (-0.5 to -1.5) and zircon εHf(t) (0.0 to +2.3) values, suggest that the granodiorites were derived from partial melting of a mafic lower crustal source. The MMEs in the granodiorites and mafic dike intrusions are composed of amphibole, plagioclase, clinopyroxene, and olivine, and have similar chemical compositions, such as high Nb (15.7-41.9 ppm) and TiO2 (2.13-3.39 wt%) contents and high Nb/U (18.7-30.9) values, akin to alkaline high-Nb basalts (HNB). Their variable Ba/Nb (7.68-79.2), Nb/Zr (0.09-0.16), high Nb/Th (5.47-6.68), and low Th/Zr (0.01-0.03) and La/Nb (1.03-1.37) ratios indicate a mantle source modified by melts derived from subducted oceanic crust and sediments. The Yuanmou HNB with high εNd(t) (+4.8 to +6.9) were probably generated during back-arc extension by decompression melting of a mantle source metasomatized by adakitic slab melts formed during earlier stages of the subduction. This implies that the location of the back-arc was far from the subducted oceanic slab, possibly due to a slab rollback process. In this scenario, HNB intrusions provided the heat for partial melting and adakitic melt formation in the mafic lower crust. The model suggests that the Yuanmou and other similar associations of HNBs and adakitic rocks emplaced along the western margin of the Yangtze Block are products of a widespread Neoproterozoic back-arc extension. [ABSTRACT FROM AUTHOR]

Slab breakoff can explain the postcollisional igneous and metamorphic events in many collisional orogens and triggers the transition from initial continental collision to deep subduction. However, the relationship between the deep-seated geometry of slab breakoff and shallow tectono-magmatic events remains unclear. In this study, we report new geochronological, geochemical, and Hf isotope data for granitic rocks from the Qiangtang block. Three granitic samples yielded zircon U-Pb ages of 226-214 Ma and mostly gave negative zircon εHf(t) values of -20.1 to +0.57. These granitoids are K-rich, calc-alkaline, magnesian, and metaluminous to weakly peraluminous. We propose that the granites were generated by partial melting of compositionally heterogeneous lower crust in the Southern Qiangtang block. Our new data, along with previously published data for igneous and metamorphic rocks in the Qiangtang block, suggest that the Longmu Co--Shuanghu suture zone represents a remnant of the closure of the Paleo-Tethys Ocean, and that the Late Triassic tectono-magmatic evolution was controlled by slab breakoff after continental collision. The contrasting magmatic and metamorphic ages show that the two stages of tectono-magmatic activity in the Late Triassic were due to a change in the subduction angle of the continental lithosphere from steep (225-215 Ma) to shallow (215-205 Ma) during slab breakoff. Furthermore, we infer that slab breakoff of the oceanic lithosphere caused extensive crustal melting and reworking and initiated far-field subduction. Our results provide new insights into the slab breakoff processes that control the geometry of subducting continental lithosphere and related postcollisional magmatic and metamorphic events in collision zones. [ABSTRACT FROM AUTHOR]

The contributions of deeply subducted slabs to post-collisional magmatism are poorly constrained. Here, we present a study of the post-collisional, Early Permian (ca. 279 Ma), Hamisite basalts from the Western Tianshan NW China to trace the geochemical fingerprints of deeply subducted slab. The Hamisite basalts have arc-like trace element patterns but high Nb/Ta ratios (18.4-23.0). They have slightly enriched Sr--Nd isotopic compositions (87Sr/86Sr = 0.7048-0.7052; εNd[t] = 2.02--3.85), which indicates that the basalts were derived from an enriched mantle source. Extremely low δ7Li values (-5.76‰ to 0.20‰) imply the involvement of a deeply subducted slab (i.e., eclogites) in the source. Correlations among Nb/Ta and (Dy/Yb)N ratios, and rare earth element contents, indicate that the deeply subducted slab contained residual rutile and garnet but no epidote. Given that melting of eclogites requires an anomalously hot mantle source, we propose that mantle upwelling during post-collisional extension triggered melting of the deeply subducted slab. Our results indicate that melting of a deeply subducted slab can generate a metasomatized mantle source with high Nb/Ta ratios, which could be a hidden, high-Nb/Ta reservoir on Earth. Low δ7Li values and high Nb/Ta ratios could be a fingerprint of recycling of a deeply subducted slab. [ABSTRACT FROM AUTHOR]

Arc magmatism can provide crucial information about crustal recycling and growth in subduction zones. However, the crustal material transfer process and mechanism from subducting slab to overlying mantle wedge are controversial. Here, we present detailed petrological, geochronological, geochemical, and Sr-Nd-Hf isotopic data, and previously published data for two episodes of subduction-related magmatism in the Northern Yili Block, NW China, to study these issues in relation to the recycling of continental crust and the growth of two separate magmatic episodes at 400-350 Ma and 350-300 Ma, respectively. The Nd-Sr isotope modeling results, low Nd/Sr, and variable Hf/Nd ratios demonstrate that the arc magmatism of these two episodes could be derived from two distinct mélange sources that formed at the slab-mantle interface during subduction of the Junggar oceanic plate. In the first episode, magmatic rocks exhibit high Th/Yb and (La/Sm)N ratios and the decoupling of Nd-Hf isotopes, which leads to an interpretation that the primary magmas were derived from sources mainly mixed by sediments and mantle-wedge peridotites. In contrast, the magmas of the second episode exhibit high Ba/La and Ba/Th ratios and the coupling of Nd-Hf isotopes, which implies that these magmas were likely produced from mélange diapirs dominated by the mixing of midoceanic-ridge basalts and mantle peridotites. The episodes of Nd-Hf isotopic decoupling and coupling coincided with crustal material recycling and crustal growth in subduction zones, respectively. Considering that the Northern Yili Block at 400-350 Ma was characterized mainly by enriched Nd-Hf isotopes of magmatic rocks and no development of the forearc accretionary complex, while the Northern Yili Block at 350-300 Ma featured high εHf(t)-εNd(t) values of magmatic rocks, occurrences of extension-related magmatism, and distribution of the forearc accretionary complex and immature back-arc basin, we propose that these two different mélange sources probably developed in response to subduction transition. That is, one resulted from advancing and the other was relevant to retreating regime. The partial melting of these mélanges in the mantle wedge generated intermediate felsic magmas, which might have acted as a leading mechanism for crustal recycling and growth of the accretionary orogenic belt. [ABSTRACT FROM AUTHOR]