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Europa likely contains an iron-rich metal core. For it to have formed, temperatures within Europa reached ≳ 1250 K. Going up to that temperature, accreted chondritic minerals - for example, carbonates and phyllosilicates - would partially devolatilize. Here, we compute the amounts and compositions of exsolved volatiles. We find that volatiles released from the interior would have carried solutes, redox-sensitive species, and could have generated a carbonic ocean in excess of Europa's present-day hydrosphere, and potentially an early CO 2 atmosphere. No late delivery of cometary water was necessary. Contrasting with prior work, CO 2 could be the most abundant solute in the ocean, followed by Ca 2 + , SO 4 2 - , and HCO 3 - . However, gypsum precipitation going from the seafloor to the ice shell decreases the dissolved S/Cl ratio, such that Cl > S at the shallowest depths, consistent with recently inferred endogenous chlorides at Europa's surface. Gypsum would form a 3-10 km thick sedimentary layer at the seafloor., (© 2021 Jet Propulsion Laboratory. California Institute of Technology. Government sponsorship acknowledged.)