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The presence of dome-and-keel provinces in Archean cratons has been connected with the initiation of plate tectonics on Earth as these features are most commonly observed in Archean rocks. The Quadrilátero Ferrífero in Brazil has been identified as a Paleoproterozoic dome-and-keel province for more than three decades. The prevailing model suggests that it formed during the Rhyacian Transamazonian orogeny, making it unique among dome-and-keel provinces. However, a lack of appropriate lithologies, datable minerals and the metamorphic overprint of later orogenesis has resulted in a cryptic metamorphic record for the formation of this dome-and-keel province. A clinopyroxene-bearing migmatite from the core of the Bação dome has peak P – T conditions of 5–7 kbar and 700–750 °C and a published age of ca. 2730 Ma based on U–Pb ages of zircon from leucosomes, suggesting that this age represents the migmatisation event. A fine-grained epidote-albite-titanite assemblage overprints the coarse-grained clinopyroxene and amphibole, giving P – T conditions of 8–9 kbar and 550 °C with an associated titanite age of ca. 2050 Ma. A garnet-bearing amphibolite sample also from the core of the dome has peak P – T conditions of 7–8 kbar and 650–700 °C, and texturally late titanite from this sample produces an age of ca. 2060 Ma. Three additional samples were collected from the edges of the dome. A garnet-gedrite bearing felsic schist produces peak P – T conditions of 8–9 kbar and 650–700 °C on a clockwise P – T evolution. This sample has a U–Pb zircon age of ca. 2775 Ma, which could date metamorphism or be the age of its volcaniclastic protolith. Texturally unconstrained titanite from the sample gives an age of ca. 2040 Ma. A garnet-bearing amphibolite that occurs as a boudin within the felsic schist gives both zircon and titanite ages of ca. 2050 Ma and has peak P – T conditions of 5–6 kbar and 650–700 °C on a near isobaric P – T path. An amphibolite dike, observed to cross-cut the felsic schist produces a zircon U–Pb age of ca. 2760 Ma. Altogether this data suggests that the samples were metamorphosed in the Archean (ca. 2775–2730 Ma) and again during the Transamazonian event. The most plausible explanation for this data is that dome-and-keel formation occurred in the Archean with migmatisation and high-temperature metamorphism occurring at this time. The Paleoproterozoic event is interpreted as a reactivation of the dome-and-keel formation structures, with Paleoproterozoic keels crosscutting Archean keels and producing metamorphic aureoles. The high radiogenic heat production and the presence of dense sedimentary successions in Archean terranes make dome-and-keel provinces a uniquely Archean feature, but they are susceptible to reworking, resulting in an enigmatic record of formation. Image 1 • The formation of a Proterozoic dome-and-keel province was investigated. • Samples record two metamorphic events at ca. 2730 and ca. 2000 Ma. • Dome-and-keel formation occurred in the Archean and reactivated in the Paleoproterozoic. • The properties of Archean rocks result in dome-and-keel formation. [ABSTRACT FROM AUTHOR]

Plutonic rocks from the Mineiro Belt, Brazil record a delayed onset of the transition from TTG to sanukitoid-type magmatism (high Ba-Sr), starting during the Siderian magmatic lull when little juvenile magma was added to the continental crust. Rocks mostly belong to the calc-alkaline series, meta- to peraluminous and originally “I-type”, meaning that oxidized magmas were formed by partial melting of subducted material. The temporal distribution and apparent secular changes of the magmas are consistent with the onset of subduction-driven plate tectonics due to an increase of the subduction angle and opening of the mantle wedge. New isotopic analyses (Sm-Nd whole rock and Lu-Hf in zircon) corroborate the restricted juvenile nature of the Mineiro Belt and confirm the genetic link between the Lagoa Dourada Suite, a rare ca. 2350 Ma high-Al tonalite-trondhjemite magmatic event, and the sanukitoid-type ca. 2130 Ma Alto Maranhão Suite. U-Pb dating of zircon and titanite constrain the crystallisation history of plutonic bodies; coupled with major and trace element analyses of the host rocks, they distinguish evolutionary trends in the Mineiro Belt. Several plutons in the region have ages close to 2130 Ma but are distinguished by the lower concentration of compatible elements in the juvenile high Ba-Sr suite. [ABSTRACT FROM AUTHOR]

[Display omitted] • Campos Gerais Domain: Archean–Ediacaran segment of the São Francisco paleocontinent. • New Mesoarchean (2.9 Ga) mafic magmatism is identified in the Campos Gerais Complex. • First Rhyacian (2.1 Ga) arc-related ultramafic rocks is recognized. • Metaultramafites register metamorphic overprint at 590 Ma. The Campos Gerais Domain (CGD) in southeastern Brazil is an approximately 180 km × 35 km area of Archean–Proterozoic rocks located southwest of the São Francisco Craton (SFC). The Archean–Paleoproterozoic evolution of the CGD — alongside its potential correlation with the SFC or other cratonic blocks in the region — is currently poorly-constrained. We present the results of systematic petrography, bulk-rock geochemistry, mineral chemistry and geochronology for a suite of scarcely studied mafic–ultramafic rocks from the CGD. We also provide a compilation of previously reported bulk-rock geochemical and spinel group mineral chemical data for mafic–ultramafic rocks throughout the CGD, and geochronological information for various lithotypes in the region. The CGD records a protracted Mesoarchean to Statherian (3.1–1.7 Ga) crustal evolution, which we interpret to share a common history with the southern SFC and their related reworked segments, suggesting that it is a westward extension of this cratonic terrain. The metavolcano-sedimentary rocks of the Fortaleza de Minas and Alpinópolis segments represent a Mesoarchean greenstone belt that is stratigraphically and chemically comparable to Archean greenstone belts worldwide, and that is broadly coeval with a local suite of tonalite-trondhjemite-granodiorite (TTG) gneisses and migmatites. U-Pb SHRIMP zircon data from a subalkaline metagabbro yielded a concordia age of ca. 2.96 Ga, revealing a previously unrecognized phase of Archean magmatism in the CGD that can be chrono-correlated with metakomatiite and TTG generation elsewhere in the São Francisco paleocontinent. Our data contradict a hypothesis whereby the metavolcano-sedimentary rocks of the Jacuí-Bom Jesus da Penha and Petúnia segments represent an ophiolite, as previously suggested, instead presenting features that point to formation in association with a continental arc. Coupled with a U-Pb (SHRIMP) crystallization age of ca. 2.13 Ga recorded by zircon grains from a metaultramafic rock, these data highlight that a magmatic event was chrono-correlated with the main accretionary phase of the Minas Orogeny, and with the Pouso Alegre/Amparo and São Vicente complexes. Finally, a U-Pb (SHRIMP) concordia age of ca. 590 Ma — obtained from metamorphic-textured zircon grains from a metaultramafic rock — points to a late metamorphic overprint related to upper amphibolite conditions, brittle fault activation and the juxtaposition of crustal blocks in association with the latest stages of western Gondwana's assembly in the southern SFC, with later retrogression to greenschist-facies. [ABSTRACT FROM AUTHOR]

[Display omitted] • The Mairi Gneiss Complex contains the oldest rocks of São Francisco Craton and South America. • Multiple magmatic episodes from the Eo- to the Palaeoarchaean and in the Neoarchaean. • No Mesoarchaean rocks occur in the Mairi Complex. • Lu-Hf isotope data show a progressive evolution of depleted-mantle, and crustal growth and recycling. • Interaction of pre-existing crust and juvenile contribution. The composition and formation of the Earth's primitive continental crust and mantle differentiation are key issues to understand and reconstruct the geodynamic terrestrial evolution, especially during the Archean. However, the scarcity of exposure to these rocks, the complexity of lithological relationships, and the high degree of superimposed deformation, especially with long-lived magmatism, make it difficult to study ancient rocks. Despite this complexity, exposures of the Archean Mairi Gneiss Complex basement unit in the São Francisco Craton offer important information about the evolution of South America's primitive crust. Therefore, here we present field relationships, LA-ICP-SFMS zircon U-Pb ages, and LA-ICP-MCMS Lu-Hf isotope data for the recently identified Eoarchean to Neoarchean gneisses of the Mairi Complex. The Complex is composed of massive and banded gneisses with mafic members ranging from dioritic to tonalitic, and felsic members ranging from TTG (Tonalite-Trondhjemite-Granodiorite) to granitic composition. Our new data point to several magmatic episodes in the formation of the Mairi Gneiss Complex: Eoarchean (ca. 3.65–3.60 Ga), early Paleoarchean (ca. 3.55–3.52 Ga), middle-late Paleoarchean (ca. 3.49–3.33 Ga) and Neoarchean (ca. 2.74–2.58 Ga), with no records of Mesoarchean rocks. Lu-Hf data unveiled a progressive evolution of mantle differentiation and crustal recycling over time. In the Eoarchean, rocks are probably formed by the interaction between the pre-existing crust and juvenile contribution from chondritic to weakly depleted mantle sources, whereas mantle depletion played a role in the Paleoarchean, followed by greater differentiation of the crust with thickening and recycling in the middle–late Paleoarchean. A different stage of crustal growth and recycling dominated the Neoarchean, probably owing to the thickening of the continental crust by collision, continental arc growth, and mantle differentiation. [ABSTRACT FROM AUTHOR]

[Display omitted] • Detrital zircon U-Pb geochronology as fingerprints of the 2.47–2.00 Ga Minas orogeny. • Supracrustal rocks mainly sourced from the Mineiro juvenile crust. • Rhyacian convergent to collisional and extensional precursor basin settings. • Metamorphic overprint at ca. 2.0 Ga coeval with continental plate collision. We document new U-Pb detrital zircon LA-MC-ICP-MS data for seven metavolcanic-sedimentary successions and metasedimentary sequences and reassess additional dates of five siliciclastic samples toward their tectonic significance in the context of the Mineiro belt, Southern São Francisco Craton. This belt represents a crustal segment of the 2.47–2.00 Ga Minas Orogen, classically known by its Siderian and Rhyacian juvenile rocks with important implications in the Earth's geodynamics. The new and compiled detrital provenance constraints unravel the long-lived magmatic and sedimentary history of the studied basins, lasting ca. 230–220 Myr. The maximum depositional dates around 2.1 Ga reflect the renewed sediment budget with the subsequent metamorphic episode ca. 2.0 Ga. Most of the unmixed relative probability diagrams are consistent with sourcing from the Siderian and Rhyacian arcs of the Mineiro belt, determining a detrital provenance change in time and space for the precursor basins. Alternative potential sources could be the youngest rocks of the Mantiqueira and Juiz de Fora terranes that constitute the other segments of the Minas Orogen, given the age match. The overall detrital fingerprints determine the study basins resumed mainly in Rhyacian fore-arc and/or back-arc settings, i.e., akin to a subduction-related system that evolved to a collisional (foreland) environment. Few samples show fingerprints of primary extensional settings, determined by major Archean detrital populations sourced from areas outside the Mineiro belt beside the Paleoproterozoic detritus. The working model considers the collage between the Mineiro belt and the ancient foreland around 2.10 Ga and eventual interaction with other crustal segments of the Minas Orogen, generating the ca. 2.0 Ga metamorphism over the metasedimentary samples. The more complete isotopic repository in detrital and igneous zircon grains for the studied supracrustal successions and the associated rocks allows new insights into the Rhyacian–Orosirian dynamics of the Minas orogeny. In a broader perspective, the juvenile nature of the Mineiro belt reinforces the paradigm of uninterrupted continental growth during the Paleoproterozoic Earth. [ABSTRACT FROM AUTHOR]

[Display omitted] • CA-LA-ICPMS of U–Pb–Hf isotopes of zircons from rocks of the São Francisco Craton. • Long-lived high-grade metamorphism and partial melting (2750–2600 Ma). • 150 Myr of crustal melts and magmatism predate the cratonic stabilization at 2600 Ma. Field observations and CA-LA-ICP-MS U–Pb zircon ages and Hf isotope compositions obtained from migmatitic orthogneisses and granitoids from the Belo Horizonte Complex, southern São Francisco Craton, indicate a major period of partial melting and production of felsic rocks in the Neoarchean. Our observations show that the complex is an important site for studying partial melting processes of Archean crystalline crust. Much of the complex exposes fine-grained stromatic migmatites that are intruded by multiple leucogranitic veins and sheeted dikes. Both migmatites and leucogranite sheets are crosscut by several phases of granitoid batholiths and small granitic bodies; both of which are closely associated with the host banded gneisses. Chemical abrasion followed by detailed cathodoluminescence imaging revealed a wide variety of zircon textures that are consistent with a long-lived period of partial melting and crustal remobilization. Results of U-Pb and Hf isotopes disclose the complex as part of a much wider crustal segment, encompassing the entire southern part of the São Francisco Craton. Compilation of available U-Pb ages suggests that this crustal segment was consolidated sometime between 3000 Ma and 2900 Ma and that it experienced three main episodes of partial melting before stabilization at 2600 Ma. The partial melting episodes took place between 2750 Ma and 2600 Ma as a result of tectonic accretion and peeling off the lithospheric mantle and lower crust. This process is likely responsible for the emplacement of voluminous potassic granitoids across the entire São Francisco Craton. We believe that the partial melting of Meso-Archean crystalline crust and production of potassic granitoids are linked to a fundamental shift in the tectonics of the craton, which was also responsible for the widespread intrusion of large syenitic bodies in the northern part of the craton, and the construction of layered mafic–ultramafic intrusions to the south of the BHC. [ABSTRACT FROM AUTHOR]

[Display omitted] • Geochemistry and zircon Hf-O isotopes suggest magmatism in a back-arc basin. • Fingerprints of subduction processes and assimilation of Eoarchean crustal components. • Pyrite multiple sulfur isotopes data indicate distinct sources for supracrustal rocks. Greenstone belts contain several clues about the evolutionary history of primitive Earth. Here, we describe the volcano-sedimentary rock association exposed along the eastern margin of the Gavião Block, named the Northern Mundo Novo Greenstone Belt (N-MNGB), and present data collected with different techniques, including U–Pb–Hf–O isotopes of zircon and multiple sulfur isotopes (32S, 33S, 34S, and 36S) of pyrite from this supracrustal sequence. A pillowed metabasalt situated in the upper section of the N-MNGB is 3337 ± 25 Ma old and has zircon with ε Hf (t) = −2.47 to −1.40, Hf model ages between 3.75 Ga and 3.82 Ga, and δ18O = +3.6‰ to +7.3‰. These isotopic data, together with compiled whole-rock trace element data, suggest that the mafic metavolcanic rocks formed in a subduction-related setting, likely a back-arc basin juxtaposed to a continental arc. In this context, the magma interacted with older Eoarchean crustal components from the Gavião Block. Detrital zircons from the overlying quartzites of the Jacobina Group are sourced from Paleoarchean rocks, in accordance with previous studies, yielding a maximum depositional age of 3353 ± 22 Ma. These detrital zircons have ε Hf (t) = −5.40 to −0.84, Hf model ages between 3.66 Ga and 4.30 Ga, and δ18O = +4.8‰ to +6.4‰. The pyrite multiple sulfur isotope investigation of the 3.3 Ga supracrustal rocks from the N-MNGB enabled a further understanding of Paleoarchean sulfur cycling. The samples have diverse isotopic compositions that indicate sulfur sourced from distinct reservoirs. Significantly, they preserve the signal of the anoxic Archean atmosphere, expressed by MIF-S signatures (Δ33S between −1.3‰ to +1.4‰) and a Δ36S/Δ33S slope of −0.81 that is indistinguishable from the so-called Archean array. A BIF sample has a magmatic origin of sulfur, as indicated by the limited δ 34S range (0 to +2‰), Δ33S ~ 0‰, and Δ36S ~ 0‰. A carbonaceous schist shows positive δ 34S (2.1‰–3.5‰) and elevated Δ33S (1.2‰–1.4‰) values, with corresponding negative Δ36S between −1.2‰ to −0.2‰, which resemble the isotopic composition of Archean black shales and suggest a source from the photolytic reduction of elemental sulfur. The pillowed metabasalt displays heterogeneous δ 34S, Δ33S, and Δ36S signatures that reflect assimilation of both magmatic sulfur and photolytic sulfate during hydrothermal seafloor alteration. Lastly, pyrite in a massive sulfide lens is isotopically similar to barite of several Paleoarchean deposits worldwide, which might indicate mass dependent sulfur processing from a global and well-mixed sulfate reservoir at this time. [ABSTRACT FROM AUTHOR]

[Display omitted] • S-MIF preservation is affected by prokaryotic S, Fe and CH 4 cycling. • Methanotrophic derived biomass (δ 13C org < −30‰) is observed in BIF. • Dampened Δ33S in carbonate-rich BIF reflects AOM. • Oxygen fluctuations before the GOE attenuate S-MIF. • S-MIF dynamics throughout the Archean reflect local and global processes. Sulfur mass-independent fractionation (S-MIF) preserved in Archean sedimentary pyrite is interpreted to reflect atmospheric chemistry. Small ranges in Δ33S that expanded into larger fractionations leading up to the Great Oxygenation Event (GOE; 2.45–2.2 Ga) are disproportionately represented by sequences from the Kaapvaal and Pilbara Cratons. These patterns of S-MIF attenuation and enhancement may differ from the timing and magnitude of minor sulfur isotope fractionations reported from other cratons, thus obscuring local for global sulfur cycling dynamics. By expanding the Δ33S record to include the relatively underrepresented São Francisco Craton in Brazil, we suggest that marine biogeochemistry affected S-MIF preservation prior to the GOE. In an early Neoarchean sequence (2763–2730 Ma) from the Rio das Velhas Greenstone Belt, we propose that low δ 13C org (<−30‰) and dampened Δ33S (0.4‰ to −0.7‰) in banded iron formation reflect the marine diagenetic process of anaerobic methane oxidation. The overlying black shale (TOC up to 7.8%) with higher δ 13C org (−33.4‰ to −19.2‰) and expanded Δ33S (2.3‰ ± 0.8‰), recorded oxidative sulfur cycling that resulted in enhance preservation of S-MIF input from atmospheric sources of elemental sulfur. The sequence culminates in a metasandstone, where concomitant changes to more uniform δ 13C org (−30‰ to −25‰), potentially associated with the RuBisCO I enzyme, and near-zero Δ33S (−0.04‰ to 0.38‰) is mainly interpreted as evidence for local oxygen production. When placed in the context of other sequences worldwide, the Rio das Velhas helps differentiate the influences of global atmospheric chemistry and local marine diagenesis in Archean biogeochemical processes. Our data suggest that prokaryotic sulfur, iron, and methane cycles might have an underestimated role in pre-GOE sulfur minor isotope records. [ABSTRACT FROM AUTHOR]