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The Cryogenian nonglacial epoch (CNE) spans from the termination of the Sturtian snowball Earth (ca. 659 Ma) to the initiation of the Marinoan snowball Earth (ca. 649.2 Ma). The carbonate sequences formed in low latitudes record paleoclimatic and paleoceanographic changes during the CNE. Three negative carbon isotope (δ13C) excursions, named Rasthof, Tayshir and Trezona, are present at the bottom, middle, and top of the carbonate sequences, bracketing two intervals with highly positive δ13C values. Uranium isotope (δ238U) data from Mongolia reveal ocean redox changes linked to δ13C variations during the CNE, marked by the development of anoxic deep ocean to extensive oxygenation and subsequent deoxygenation. However, the timing and duration of these paleoceanographic events and δ13C excursions have not been adequately investigated. Here, we report new environmental magnetic results of the higher paleo-latitudinal, siliciclastic-dominated Datangpo Formation (Fm) in South China that may help constrain the age and correlation of the CNE geochemical events. We identified four segments of the Datangpo Fm based on the magnetic susceptibility (MS) profile and other environmental magnetic parameters, which are, in ascending order, the ascent segment (Da), lower stable-segment (Db), transition segment (Dc), and upper stable-segment (Dd). These segments are dated by the astronomical time scale as 659–655.6 Ma (Da), 655.6–653.3 Ma (Db), 653.3–652.3 Ma (Dc), and 652.3–649.2 Ma (Dd). Environmental magnetism analyses show that the highest magnetite concentration but lowest fine-grained magnetite contents are present in "Da", followed by "Dd" and "Db". These results suggest a sea-level fall and a potential decrease in oxygenation after the deposition of the transition segment (Dc), implying that a cooling climate started ∼4 Myr before the Nantuo glaciation (Marinoan snowball Earth). Ocean redox variations revealed by environmental magnetism in the Datangpo Fm are consistent with those reported from the low-latitudinal carbonate sequences. "Da" likely corresponds to the Rasthof δ13C excursion and "Dc" corresponds to the Tayshir δ 13C excursion; whereas "Db" and "Dd" probably correspond to the two intervals with positive δ 13C values. • Four segments of the Cryogenian nonglaciatial epoch in South China are identified and the time of each segment is constrained. • Environmental magnetism analyses show a climate cooling ∼4 Myr before the Nantuo glaciation (or Marinoan snowball Earth). • Siliciclastic depositions in South China are linked to carbonate depositions in low-latitude continents. [ABSTRACT FROM AUTHOR]

Recent studies of the upper Gaoyuzhuang Formation (Fm) (ca. 1600–1540 Ma) in north China have suggested that Earth underwent an oxygenation event associated with a negative δ13C carb excursion and this event may have led to the expansion of eukaryotic life. However, the duration of this negative δ13C carb excursion, which is crucial to understand its origin, remains uncertain. Here, we report a floating astronomical timescale based on Milankovitch cycles extracted from the carbonate-dominated strata of the Member 3 of the Gaoyuzhuang Fm in north China, in which the oxygenation event is recorded. High-resolution magnetic susceptibility, anhysteretic remnant magnetization and saturation isothermal remnant magnetization series were obtained from the stratigraphic sections in the Jixian and Yanqing regions. Rock magnetic experiments suggest that the magnetic parameters are dominated by the detrital materials whose flux was likely controlled by orbitally forced climatic changes. Our results for the first time reveal well-constrained eccentricity, obliquity, and precession cycles from the Gaoyuzhuang Fm and demonstrate that the ca. 1560 Ma negative δ13C carb excursion and associated transient oxygenation event indicated by I/(Ca + Mg) had durations of ~1.7 Myr and ~6.2 Myr, respectively. The ca. 1560 Ma δ13C carb excursion is comparable with the short-term Neoproterozoic excursions in respect of duration, rather than with the long-term ones such as the ca. 574–567 Ma Shuram excursion. The similarity may indicate a common mechanism in origin of the short-term excursions in the Mesoproterozoic and Neoproterozoic time, which deserve testing by more investigations. • Cyclostratigraphic analyses revealed Milankovitch cycles from the ca. 1.56 Ga Gaoyuzhuang Formation • Durations of the δ13C carb excursion and the oxygenation event in the ca. 1.56 Ga are 1.7 Myr and 6.2 Myr, respectively • The duration of this δ13C carb excursion are comparable to the short-term ones in the Neoproterozoic [ABSTRACT FROM AUTHOR]

The Shuram carbon isotope excursion (CIE) is the largest negative CIE in geological history that may have recorded dramatic changes in Earth's surface environments, yet its time, duration, and global synchroneity have been debated. In South China, the Shuram CIE has been correlated with the negative CIE of the upper Doushantuo Formation (named as EN3 or DOUNCE). It is previously suggested that the Shuram CIE in South China stratigraphically consists of the upper Member 3 and Member 4, with an ending age of ca. 551 Ma. Recent studies, however, demonstrated that the EN3 or DOUNCE shifts to near zero or positive carbon isotope (δ13C) values within carbonate rocks of the Doushantuo Member 3. To better understand the duration of this CIE and its spatial variability, we have conducted a high-resolution cyclostratigraphic study using magnetic susceptibility (MS) in two sections: the Zhengjiatang section that preserves a complete EN3 in carbonate rocks of the Doushantuo Member 3 and the Wuhe-Gaojiaxi (WG) drillcore in which the EN3 does not shift to positive δ13C values until the end of the Member 4 black shales. In both sections, power spectral analyses of the MS series of the carbonate rocks reveal periodicities that match well with those of the Milankovitch cycles at 570 Ma. The duration of the Shuram CIE is estimated to be 6.1 ± 0.2 Myr by counting the interpreted 405-kyr sedimentary cycles observed in the Zhengjiatang section. Taking the newly reported Re Os age of 567.3 ± 3.0 Ma as the approximate termination age, the Shuram CIE in the best-preserved section in South China is constrained between ca. 573.4 and 567.3 Ma. Regional correlation, however, shows a ≥ 1 Myr stratigraphic hiatus or unconformity at the top of the Doushantuo Member 3 that separates the Shuram CIE from overlying post-Shuram ẟ13C "excursions". Similar phenomena may exist in the Shuram CIE documented from stratigraphic successions in Oman, Australia, and the Death Valley region of western United States. The results invoke a reevaluation of the stratigraphic range of the Shuram CIE and suggest that the geochemical records documented from the black shales of the Doushantuo Member 4 and its globally correlative intervals may record paleoceanographic conditions millions of years after the Shuram CIE. Comparison of astrochronologically calibrated δ13C profiles reveals significant difference in the shape and amplitude of the Shuram CIE among the sections in South China and globally, which may have been caused by isotopic departure in local depositional environments and/or diagenetic overprints. • The Zhengjiatang section in South China preserves a complete Shuram excursion. • Astronomically estimated duration of 6.1 ± 0.2 Myr for the Shuram excursion. • Portion of the previously defined Shuram excursion may be post-Shuram. • The shape and amplitude of the Shuram excursion differ regionally and globally. [ABSTRACT FROM AUTHOR]